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The bis(η-cyclopentadienyl)titanium(IV) – salicylate system revisited and the characterisation of two 3,5-di-t-butylsalicylate analogues. The molecular structure of [Cp2Ti(sal)], (sal = O2CC6H4O2−)

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Abstract

The Cp2TiIV – salicylate system has been re-examined and procedures for the syntheses of [Cp2Ti(salH)2] and [Cp2Ti(sal)] explored, [salH = (O2CC6H4OH-2)−; sal = (O2CC6H4O-2)2−]. The new 3,5-di-t-butylsalicylate analogues have been prepared and characterised. An X-ray structure determination of [Cp2Ti(sal)] confirms the chelating nature of the sal ligand which is bonded to the metal through the phenolic and one of the carboxylate oxygen atoms.

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  1. Department of Chemistry, University of Bath, Bath, BA2 7AY, UK

    Dennis A. Edwards, Mary F. Mahon, Timothy J. Paget & Nicholas W. Summerhill

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  1. Dennis A. Edwards
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  2. Mary F. Mahon
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  3. Timothy J. Paget
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  4. Nicholas W. Summerhill
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Edwards, D.A., Mahon, M.F., Paget, T.J. et al. The bis(η-cyclopentadienyl)titanium(IV) – salicylate system revisited and the characterisation of two 3,5-di-t-butylsalicylate analogues. The molecular structure of [Cp2Ti(sal)], (sal = O2CC6H4O2−). Transition Metal Chemistry 26, 116–119 (2001). https://doi.org/10.1023/A:1007184425487

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