Abstract
Yttria-doped zirconia and pure zirconia membranes were prepared with sol-gel method using zirconium oxychloride octahydrate (ZrOCl2 · 8H2O) as starting material. Characterization for membranes was performed by means of BET, TG-DTA, SEM, XRD, FT-IR and Raman spectroscopy. Stable tetragonal phase and pore structure in yttria-doped zirconia membranes were observed at 400–700°C. And, phase transformation temperature can be retarded to 300°C. As a result, yttria doping can be developed as a method to secure the membrane from cracking in preparation process and high temperature applications.
Similar content being viewed by others
References
R. R. Bhave, "Inorganic Membranes, Synthesis, Characterization and Properties" (Van Rostrnd Reinhold, New York, 1991).
H. P. Hsieh, Inorganic Membranes, A. I. Ch.E. Symp. Ser. 84(261) (1998) 1.
L. Yang and J. Cheng, J. Non-Cryst. Solids 112(1989).
K. Izumi, M. Murakami, T. Deguchi and A. Morita, J. Amer. Ceram. Soc. 72(1989) 1465.
P. De Lima Neto, M. Atik, L. A. Auaca and M. A. Aegerter, J. Sol-Gel Sci. Technol. 2(1994) 529.
R. M. Shane and M. L. Mecartney, J. Mater. Sci. 25(1990) 1537.
P. Peshev and V. Slavova, Mater. Res. Bull. 27(1992) 1269.
K. Miyazawa, K. Suzuki and M. Y. Wey, J. Amer. Ceram. Soc. 78(1995) 347.
M. Yashima, Y. Matsuo and M. Yoshimura, J. Mater. Res. 12(1997) 2575.
C. H. Chang, R. Gopalan and Y. S. Lin, J. Membr. Sci. 91(1994) 27.
R. Gopalan, C. H. Chang and Y. S. Lin, J. Mater. Sci. 30(1995) 3075.
T. L. Wen, V. Herbert and S. Vilminot, ibid. 26(1991) 3787.
P. Peshev and V. Slavova, Mater. Res. Bull. 27(1992) 1269.
T. W. Kueper, S. J. Visco and L. C. De Jonghe, Solid State Ionics 52(1992) 251.
C. Sakurai, T. Fuzuki and M. Okuyama, J. Amer. Ceram. Soc. 76(1993) 1061.
W. D. Kingery, H. K. Bowen and D. R. Uhlmann, "Introduction to Ceramics" (Wiley, New York, 1976).
C. J. Brinker and G. W. Scherer, "Sol-Gel Science" (Academic Press, Boston, 1990).
S. Ramanathan, R. V. Muraleedharan, S. K. Roy and P. K. Nayar. J. Amer. Ceram. Soc. 78(1995) 429.
R. C. Garvie, J. Phys. Chem. 69(1965) 1238.
R. P. Ingel and D. Lewis I I I, J. Amer. Ceram. Soc. 69(1986) 325.
C. H. Perry, F. Lu and B. Alzyab, J. Raman Spectroscopy 21(1990) 577.
T. Hirata, J. Phys. Chem. Solids 7(1995) 951.
C. J. Howard, R. J. Hill and B. E. Reichert, Acta Crystallogr. B44(1988) 116.
J. M. Leges, P. E. Tomaszewski and A. S. Pereira, Phys. Rev. B47(1993) 14075.
D. R. Clarke and E. Adar, J. Amer. Ceram. Soc. 65(1982) 284.
K. Tsukuma and M. Shimada, J. Mater. Sci. 20(1985) 1178.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Shi, L., Tin, KC. & Wong, NB. Thermal stability of zirconia membranes. Journal of Materials Science 34, 3367–3374 (1999). https://doi.org/10.1023/A:1004681015331
Issue Date:
DOI: https://doi.org/10.1023/A:1004681015331