Abstract
Supported platinum electrocatalysts are generally used in low temperature fuel cells to enhance the rates of the hydrogen oxidation and oxygen reduction reactions. In such catalysts, the high surface to volume ratios of the platinum particles maximize the area of the surfaces available for reaction. It is the structure and proper dispersal of these platinum particles that make low-loading catalysts feasible for fuel cell operation, lowering the cost of the system. If the platinum particles cannot maintain their structure over the lifetime of the fuel cell, change in the morphology of the catalyst layer from the initial state will result in a loss of electrochemical activity. This loss of activity in the platinum/carbon catalysts due to the agglomeration of platinum particles is considered to be a major cause of the decrease in cell performance, especially in the case of the cathode. In the light of the latest advances on this field, this paper reviews the preparation methods of these catalysts, their microstructural characteristic and their effect on both thermal and in cell conditions stability.
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References
E. Antolini, Mater. Chem. Phys. 78 (2003) 563.
S. Mukerjee, J. Appl. Electrochem. 20 (1990) 537.
F. Rodriguez-Reinoso, Carbon 36 (1998) 159.
E. Auer, A. Freund, J. Pietsch and T. Tacke, Appl. Catal. A 173 (1998) 259.
L. B. Okhlopkova, A. S. Lisitsyn, V. A. Likholobov, M. Gurrath and H. P. Boehm, ibid. 204 (2000) 229.
M. A. Fraga, E. Jordao, M. J. Mendes, M. M. A. Freitas, J. L. Faria and J. L. Figueredo, J. Catal. 209 (2002) 355.
E. Czaran, J. Finster and K. H. Schnabel, Z. Anorg. Allg. Chem. 443 (1978) 175.
H. E. van Dam and H. van Bekkum, J. Catal. 131 (1991) 335.
F. Coloma, A. Sepulveda-Escribano, J. L. Fierro and F. Rodriguez-Reinoso, Langmuir 10 (1994) 750.
S. R. De Miguel, O. A. Scelza, M. C. Roman-Martinez, C. Salinas-Martinez, D. Cazorla-Amoros and A. Linares-Solano, Appl. Catal. A 170 (1998) 93.
G. C. Torres, E. I. Iablonski, G. T. Baronetti, A. A. Castro, S. R. De Miguel, O. A. Scelza, M. D. Blanco, M. A. Pena Jimenez and J. L. G. Fierro, ibid. 161 (1997) 213.
A. Sepulveda-Escribano, F. Coloma and F. Rodriguez-Reinoso, ibid. 173 (1998) 247.
P. J. Carrott, M. M. Carrott, A. J. Candeias and J. P. Ramalo, J. Chem. Soc. Faraday Trans. 91 (1995) 2179.
A. Polania, E. Papirer, J. B. Donnett and G. Dagois, Carbon 31 (1993) 473.
H. P. Boehm, ibid. 32 (1994) 759.
M. V. Lopez-Ramon, F. Stoekli, C. Moreno-Castilla and F. Carrasco-Marin, ibid. 37 (1999) 1215.
S. S. Barton, M. J. B. Evans, E. Halliop and J. A. F. Macdonald, ibid. 35 (1997) 1361.
C. A. Leon, Y. Leon, J. M. Solar, V. Calemma and L. R. Radovic, ibid. 30 (1992) 797.
J. F. Lambert and M. Che, J. Mol. Catal. A 162 (2000) 5.
M. C. Roman-Martinez, D. Cazorla-Amoros, A. Linares-Solano and C. S. M. Lecea, Carbon 33 (1995) 3.
S. R. Miguel, O. A. Scelza, M. C. Roman-Martinez, C. S. M. Lecea, D. Cazorla-Amoros and A. Linares-Solano, Appl. Catal. A 170 (1998) 93.
L. D. Ageeva, N. A. Kolpakova, T. V. Kovyrkyna, N. P. Potsyapun and A. S. Buinovskii, J. Anal. Chem. 56 (2001) 137.
D. S. Cameron, S. J. Cooper, I. L. Dodgson, B. Harrison and J. W. Jenkins, Catal. Today 7 (1990) 113.
C. Prado-Burguete, A. Linares-Solano, F. Rodriguez-Reinoso and C. S. M. Lecea, J. Catal. 115 (1989) 98.
D. J. Suh, T. J. Park and S. K. Ihm, Carbon 31 (1993) 427.
P. Ehrburger, O. P. Majahan and P. L. Jr. Walker, J. Catal. 43 (1976) 61.
A. Guerriero-Ruiz, P. Badenes and I. Rodriguez-Ramos, Appl. Catal. A 173 (1998) 313.
M. Watanabe, M. Uchida and S. Motoo, J. Electroanal. Chem. 229 (1987) 395.
H. G. Petrow and R. J. Allen, U.S. Patent no. 4,044,193 (1977).
E. Antolini, L. Giorgi, F. Cardellini and E. Passalacqua, J. Solid State Electrochem. 5 (2001) 131.
N. Giordano, E. Passalacqua, L. Pino, A. S. AricÒ, V. Antonucci, M. Vivaldi and K. Kinoshita, Electrochimica Acta 36 (1991) 1979.
Y. Nakao and K. Kaeriyama, J. Colloid Interface Sci. 110 (1986) 82.
D. Duff, T. Mallat, M. Schneider and A. Baiker, Appl. Catal. A 133 (1995) 133.
N. Toshima and K. Hirakawa, Polym. J. 31 (1999) 1127.
A. Honji, T. Mori, K. Tamura and Y. Hishinuma, J. Electrochem. Soc. 135 (1988) 355.
X. Wang and I.-M. Hsing, Electrochimica Acta 47 (2002) 2981.
J. Mcbreen, H. Olender, S. Srinivasan and K. Kordesch, J. Appl. Electrochem. 11 (1981) 787.
M. Uchida, Y. Aoyama, M. Tanabe, N. Yanagihara, N. Eda and A. Ohta, J. Electrochem. Soc. 142 (1995) 2572.
M. Watanabe, H. Sei and P. Stonehart, J. Electroanal. Chem. 261 (1989) 375.
M. Watanabe, S. Saegusa and P. Stonehart, Chem. Lett. 9 (1989) 1487.
A. Honji, T. Mori, K. Tamura and Y. Hishinuma, J. Electrochem. Soc. 137 (1990) 2084.
H. Bonnemann, G. Braun, W. Brijoux, R. Brinkmann, A. Tilling, K. Seevogel and K. Siepen, J. Organomet. Chem. 520 (1996) 143.
A. Stoyanova, V. Naidenov, K. Petrov, I. Nikolov, T. Vitanov and E. Budevski, J. Appl. Electrochem. 29 (1999) 1197.
K. Tsurumi, T. Nakamura and A. Sato, U.S. Patent no. 4,956,331 (1990).
E. Antolini, F. Cardellini, E. Giacometti and G. Squadrito, J. Mater. Sci. 37 (2002) 133.
T. Torre, A. S. AricÒ, V. Alderucci, V. Antonucci and N. Giordano, Appl. Catal. A 114 (1994) 257.
V. M. Jalan and C. L. Bushnell, U.S. Patent no. 4,136,056 (1979).
V. M. Jalan, in “Extended Abstracts, Meeting Electrochemical Society” (Montreal, Canada, 1982).
M. Vaarkamp, J. T. Miller, F. S. Modica, G. S. Lane and D. C. Koningberger, J. Catal. 138 (1992) 675.
S. C. Roy, P. A. Christensen, A. Hamnett, K. M. Thomas and V. Trapp, J. Electrochem. Soc. 143 (1996) 3073.
S. Mukerjee, S. Srinivasan, M. P. Soriaga and J. Mcbreen, ibid. 142 (1995) 1409.
A. Pebler, ibid. 133 (1986) 9.
I. J. Hillenbrand and J. W. Lacksonen, ibid. 112 (1965) 249.
J. Escard, C. Leclerc and J. P. Contour, J. Catal. 29 (1973) 31.
J. C. Vedrine, M. Dufaux, C. Naccache and B. Imelik, J. Chem. Soc. Faraday Trans. 74 (1978) 440.
A. K. Shukla, M. K. Ravikumar, A. Roy, S. R. Barman, D. D. Sarma, A. S. AricÒ, V. Antonucci, L. Pino and N. Giordano, J. Electrochem. Soc. 141 (1994) 1517.
K. L. Mittal, J. Vac. Sci. Technol. 13 (1976) 19.
M. G. Mason, Phys. Rev. B 27 (1983) 748.
T. T. P. Cheung, Surf. Sci. 140 (1984) 151.
W. Eberhardt, P. Fayet, D. M. Cox, Z. Fu, A. Kaldor, R. Sherwood and D. Sondericker, Phys. Rev. Lett. 64 (1990) 780.
K. Kinoshita, J. Electrochem. Soc. 137 (1990) 845.
W. Romanowski, Surf. Sci. 18 (1969) 373.
V. M. Jalan, in “Extended Abstracts” (Meeting Electrochemical Society, Los Angeles, CA, 1979).
M. L. Sattler and P. N. Ross, Ultramicroscopy 20 (1986) 21.
M. Komiyama, J. Kobayashi and S. Morica, J. Vac. Sci. Tech. 8 (1990) 608.
R. van Hardeveld and A. van Montfoort, Surf. Sci. 4 (1966) 396.
R. van HARDEVELD and F. Hartog, ibid. 15 (1969) 189.
A. C. C. Tseung and S. C. Dhara, Electrochimica Acta 20 (1975) 681.
K. F. Blurton, H. R. Kunz and D. R. Rutt, ibid. 23 (1978) 183.
P. Bindra, S. Clouser and E. Yeager, J. Electrochem. Soc. 126 (1979) 1631.
G. A. Gluver, R. F. Pascoe and H. R. Kunz, ibid. 127 (1980) 1219.
B. C. Beard and P. N. Ross, ibid. 137 (1990) 3368.
M. Pourbaix, “Atlas of Electrochemical Equilibrium in Aqueous Solutions,” 1st ed. (Pergamon Press, Bristol, England, 1966).
P. J. Hyde, C. J. Maggiore and S. Srinivasan, J. Electroanal. Chem. 168 (1984) 383.
J. A. Bett, K. Kinoshita and P. Stonehart, J. Catal. 41 (1976) 124.
P. Stonehart and P. A. Zucks, Electrochimica Acta 17 (1972) 2333.
J. P. MEYERS and R. M. DARLING, in “Extended Abstracts” (Meeting Electrochemical Society, Salt clLake City, UT, 2002).
C. L. Bushnell and V. M. Jalan, U.S. Patent no. 4,137,372, (1979).
G. A. Gruver, J. Electrochem. Soc. 125 (1978) 1719.
P. Stonehart, Carbon 22 (1984) 423.
S. Mukerjee and S. Srinivasans J. Electroanal. Chem. 357 (1993) 201.
J. A. Bett, K. Kinoshita and P. Stonehart, J. Catal. 35 (1974) 307.
M. Min, J. Cho, K. Cho and H. Kim, Electrochimica Acta 45 (2000) 4211.
U. Bardi and P. N. Ross, J. Vac. Sci. Technol. A 2 (1984) 1461.
L. Giorgi, E. Antolini, A. Pozio and E. Passalacqua, Electrochimica Acta 43 (1998) 3675.
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Antolini, E. Formation, microstructural characteristics and stability of carbon supported platinum catalysts for low temperature fuel cells. Journal of Materials Science 38, 2995–3005 (2003). https://doi.org/10.1023/A:1024771618027
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DOI: https://doi.org/10.1023/A:1024771618027