Skip to main content
SpringerLink
Log in

Phase Equilibria in the System CuO-Fe2O3-Sb2O4-O2

  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Results of X-ray phase analysis were used to construct the phase diagram of the system CuO-Fe2O3-Sb2O4-O2 at 1000°C in air. Two Cu2x Fe4-3x Sb x O6 solid solutions (0 ≤ x ≤ 0.154 and 0.923 ≤ x ≤ 1) of, respectively, hematite and bixbyite structure were identified.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Hutchings, G.J., Bowker, M., Crossley, A., et al., Catal. Today, 1991, vol. 10, no. 3, pp. 413–418.

    Google Scholar 

  2. Boreskov, G.K., Ven'yaminov, S.A., and Shchukin, V.V., Dokl. Akad Nauk SSSR, 1970, vol. 192, no. 4, p. 831.

    Google Scholar 

  3. Zinovik, M.A., and Davidovich, A.G., Zh. Neorg. Khim., 1981, vol. 26, no. 6, p. 1586.

    Google Scholar 

  4. Sapozhnikova, E.Ya., Davidovich, A.G., Roizenblat, E.M., et al., Zh. Neorg. Khim., 1981, vol. 26, no. 7, p. 1751.

    Google Scholar 

  5. Zinovik, M.A., Zh. Neorg. Khim., 1988, vol. 33, no. 10, p. 2689.

    Google Scholar 

  6. Shchepetkin, A.A., Fiziko-khimicheskii analiz oksidov na osnove metallov peremennoi valentnosti (Physicochemical Analysis of Oxides of Variable Valence Metals), Moscow: Nauka, 1987.

    Google Scholar 

  7. Diagrammy sostoyaniya system tugoplavkikh oksidov (Phase Diagrams of Systems Based on Refractory Oxides), Galakhov, F.Ya., Ed., Leningrad: Nauka 1986, issue 5, part 2.

    Google Scholar 

  8. Walczak, J., Filpek, E., and Bosacka, M., Solid State Ionics, 1997, vols. 101–103, p. 1363.

    Google Scholar 

  9. Nakua, A., Yun, H., Reimers, J.N., et al., J. Solid State Chem., 1991, vol. 91, no. 1, p. 105.

    Google Scholar 

  10. Shimada, S., and Mackenzie, K.J.D., Thermochim. Acta, 1982, vol. 56, p. 73.

    Google Scholar 

  11. Zenkovets, G.A., Olen'kova, I.P., and Tarasova, D.V., Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk, 1986, vol. 11, no. 4, p. 53.

    Google Scholar 

  12. Varfolomeev, M.B., Shostak, I.S., Sotnikova, M.N., et al., Izv. Akad Nauk SSSR, Ser. Neorg. Mater., 1975, vol. 11, no. 5, p. 962.

    Google Scholar 

  13. Pletnev, R.N., Ivakin, A.A., Kleshchev, D.G., et al., Gidratirovannye oksidy elementov IV and V grupp (Hydrated Oxides of Group-IV and-V Elements), Moscow: Nauka, 1986.

    Google Scholar 

  14. Rumpel, Y., Berndt, W., Adam, K., et al., Z. Naturforsch., 1978, vol. 33, no. 1, p. 39.

    Google Scholar 

  15. Bazuev, G.V., and Golovkin, B.G., Dokl. Ross. Akad. Nauk, 1993, vol. 330, no. 1, p. 57.

    Google Scholar 

  16. Bazuev, G.V., Colovkin, B.G., Zubkov, V.G.,et al., J. Solid State Chem., 1994, vol. 113, no. 1, p. 132.

    Google Scholar 

  17. Colovkin, B.G., Dokl. Akad. Nauk SSSR, 1992, vol. 322, no. 3, p. 549.

    Google Scholar 

  18. Ben-Dor, L., Fischbein, E., Felner, S., et al., J. Electrochem. Soc., 1977, vol. 124, no. 3, p. 451.

    Google Scholar 

  19. Geller, S., Acta Cryst., Ser. B., 1971, vol. 27, no. 4, p. 821.

    Google Scholar 

  20. Bazuev, G.V., Colovkin, B.G., Kadyrova, N.I., et al., Dokl. Ross. Akad. Nauk, 1997, vol. 353, no. 5, p. 622.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, Yekaterinburg, Russia

    B. G. Golovkin & G. V. Bazuev

Authors
  1. B. G. Golovkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. V. Bazuev
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Golovkin, B.G., Bazuev, G.V. Phase Equilibria in the System CuO-Fe2O3-Sb2O4-O2 . Russian Journal of Applied Chemistry 76, 1696–1698 (2003). https://doi.org/10.1023/B:RJAC.0000015742.30194.cb

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:RJAC.0000015742.30194.cb

Keywords

Search

Navigation