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Initiating and Cross-Linking Ability of Organic Peroxides: Chemical Kinetic Methods for the Determination

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Abstract

This review surveys chemical kinetic methods for the quantitative determination of the initiating and cross-linking ability of organic peroxides ROOR" (peroxides, hydroperoxides, peroxyesters, diacyl peroxides, and peroxycarbonates). The conditions and limitations of the use of autoxidation, inhibitor, radical polymerization, and model cross-linking methods are analyzed. The results of the determination of the initiating and cross-linking ability of the most important organic peroxides are cited.

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  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    V. L. Antonovskii

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Antonovskii, V.L. Initiating and Cross-Linking Ability of Organic Peroxides: Chemical Kinetic Methods for the Determination. Kinetics and Catalysis 44, 54–73 (2003). https://doi.org/10.1023/A:1022568601041

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