Abstract
In this work, the relationship between the thermodynamic properties of metal–ceramic interfaces and their electrical contact properties was explored for semiconducting BaTiO3 ceramics. The role of chemical reactivity at the interface was quantified through sessile drop measurements of the work of adhesion (W ad). The interfacial properties were characterized with impedance spectroscopy to quantify contact resistance and capacitance. It was observed that interfaces with a strong chemical interaction between the metal and the oxygen anion in the ceramic showed large W ad and correspondingly low contact resistances. It is believed that an oxygen depleted region near the surface of the BaTiO3 was formed as a result of the strong metal-oxygen interactions and led to a large W ad and an Ohmic contact.
Similar content being viewed by others
References
M. RÜhle and A. G. Evans, Mat.Sci.Eng. A107 (1987) 187.
Ju. V. Naidich, Prog.Surf.and Memb.Sci. 14 (1981) 353.
D. Chatain, L. Coudurier and N. Eustathopoulous, Rev.Phys.Appl. 23 (1988) 1055.
J. G. Li, Mater.Chem.and Phys. 47 (1997) 126.
L. J. Brillson, Phys.Rev.Lett. 40 (1978) 260.
Idem., Surf.Sci. 229/230 (1994) 909.
Idem., Comments Cond.Matt.Phys. 14(6) (1989) 311.
S. Kurtin, T. C. McGill and C. A. Mead, Phys.Rev. Lett.22 (1969) 1433.
D. Kahng and S. H. Wemple, J.Appl.Phys. 36(7) (1965) 2925.
S. H. Wemple, D. Kahng, C. N. Berglund and L. G. Van Uitert, ibid. 38(2) (1967) 799.
S. H. Wemple, D. Kahng and H. J. Braun, ibid. 38(1) (1967) 353.
S. H. Wemple, in “Ohmic Contacts to Semiconductors,” edited by B. Schwartz (The Electrochemical Society, Princeton, NY, 1969) P. 128.
R. C. Neville and C. A. Mead, J.Appl.Phys. 43(11) (1972) 4657.
N. Szydlo and R. Poirier, ibid. 43(11) (1972) 4657.
E. H. Rhoderick and R. M. Williams, “Metal-Semiconductor Contacts” (Clarendon Press, Oxford, 1988).
N. Eustathopolous, D. Chatain and L. Coudurier, Mat.Sci.Eng. A135 (1991) 83.
D. Chatain, I. Rivollet and N. Eustathopolous, J.de Chim.Phys. 83 (1986) 561.
Idem. ibid. 84 (1987) 201.
W. Heywang and H. Thomann, in “Electronic Ceramics,” edited By B. C. H. Steele (Elsevier Applied Science, New York, 1991).
D. Chatain, F. Chabert, V. Ghetta and J. Fouletier, J.Amer.Ceram.Soc. 77(1) (1994) 197.
D. P. Cann and C. A. Randall, J.Appl.Phys. 80(3) (1996) 1628.
A. J. Moulson and J. G. Herbert, “Electroceramics” (Chapman and Hall, New York, 1990).
J. E. McDonald and J. G. Eberhart, Trans.Met.Soc. of AIME 233 (1965) 512.
P. Kritsalis, B. Drevet, N. Valignat and N. Eustaopolous, Scritpa Met.et Mat. 30(9) (1994) 1127.
V. Ganin and M. A. Kvantov, Izv.Akad.Nauk SSSR.Ser. Fiz. 54(6) (1990) 1192.
D. J. Wang and S. T. Wu, Acta Met et Mat. 43(8) (1995) 2917.
M. G. Nicolas, T. M. Valentine and M. J. Waite, J.Mater.Sci. 15 (1980) 2197.
R. Standing and M. Nicolas, ibid. 13 (1978) 1509.
JU. V. Naidich and Ju. N. Chuvasov, ibid. 18 (1983) 2071.
A. R. Miedema, Z.Metall. 69 (1978) 455.
L. EspiÉ, B. Drevet and N. Eustathopolous, Met. et Mat.Trans.A 25A (1994) 599.
F. R. De Boer, R. Boom, W. C. M. Mattens, A. R. Miedema and A. K. Niessen, “Cohesion in Metals” (North Holland, New York, 1989).
F. A. KrÖger and H. J. Vink, in “Solid State Phys.,” Vol. 3, edited by F. Seitz and D. Turnbull (1956) p. 307.
M. S. Maiti and R. N. Basu, Mat.Res.Bull. 21 (1986) 1107.
H. B. Michaelson, J.Appl.Phys. 48(11) (1977) 4729.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Cann, D.P., Maria, JP. & Randall, C.A. Relationship between wetting and electrical contact properties of pure metals and alloys on semiconducting barium titanate ceramics. Journal of Materials Science 36, 4969–4976 (2001). https://doi.org/10.1023/A:1011817128242
Issue Date:
DOI: https://doi.org/10.1023/A:1011817128242