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doi:10.1016/j.tetlet.2005.06.109 
Copyright © 2005 Elsevier Ltd All rights reserved.
Rhodium-catalyzed thiophosphinylation and phosphinylation reactions of disulfides and diselenides
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Received 20 May 2005;
revised 16 June 2005;
accepted 17 June 2005.
Available online 11 July 2005.
Abstract
Alkyl and aryl dithiophosphinates were synthesized by the reaction of disulfides with biphosphine disulfides in the presence of RhH(PPh3)4 and 1,2-diphenylphosphinoethane (dppe). The catalyst also promoted synthesis of thiophosphinates and selenothiophosphinates from disulfides and diselenides.
