The thermal performance of two passive cooling systems under hot and humid climate condition is experimentally investigated. The experimental results were obtained from a test cell and a controlled cell with identical walls but different roof configurations. The passive cooling systems applied to the test cell are solar chimney and water spraying on roof. The experimental results obtained from the test cell are compared with the closed and no passive cooling controlled cell. In addition, the significant of solar-induced ventilation by using a solar chimney is realized by utilizing a wind shield to reduce the effect of wind-induced ventilation resulting in low measured air velocities to the solar chimney and low computed value of coefficient of discharge. The derived coefficient of discharge of 0.4 is used to compute Air Changes rates per Hour (ACH). The ACHs with application of solar chimney solely are found to be in the range of 0.16–1.98. The studies of air temperature differences between the room and the solar chimney suggest amount of air flow rates for different periods in a year. The derived relationships show that the air flow rate during February–March is higher than during June–October by 16.7–53.7%. The experimental results show that application of the solar chimney in the test cell could maintain the room temperature at 31.0–36.5 °C, accounting for 1.0–3.5 °C lower than the ambient air and 1.0–1.3 °C lower than the controlled cell. However, to make the test cell's room temperature much lower than the ambient temperature and increase the flow rate of air due to the buoyancy, the application of water spraying on roof is recommended together with solar chimney. The application of the two systems in the hot and humid climate are discovered to sustain the room temperature of the test cell to be lower than the ambient air by 2.0–6.2 °C and lower than the controlled cell by 1.4–3.0 °C.