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Science of The Total Environment
Volume 355, Issues 1-3, 15 February 2006, Pages 118-126
 
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doi:10.1016/j.scitotenv.2005.02.021    How to Cite or Link Using DOI (Opens New Window)
Copyright © 2005 Elsevier B.V. All rights reserved.

Scavenging of gaseous mercury by acidic snow at Kuujjuarapik, Northern Québec

Nazafarin Lahoutifarda, Laurier Poissantb and Susannah L. Scottc, Corresponding Author Contact Information, E-mail The Corresponding Author

aDepartment of Chemistry, University of Ottawa, Ottawa, Ontario, Canada bMeteorological Service of Canada, Environment Canada, Montréal, Québec, Canada cDepartment of Chemical Engineering, University of California, Santa Barbara, CA 93106-5080, USA

Received 17 October 2004; 
accepted 18 February 2005. 
Available online 10 May 2005.

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Abstract

One fate of gaseous elemental mercury (GEM) in the Arctic has been identified as gas phase oxidation by halogen-containing radicals, leading to abrupt atmospheric mercury depletion concurrent with ozone depletion. Rapid deposition of oxidized mercury leads to snow enrichment in mercury. In this report, we describe experiments that demonstrate the ability of snow to directly scavenge atmospheric mercury. The study was conducted at Kuujjuarapik, Québec, Canada (latitude 55°17′N). A mercury depletion event (MDE) caused the mercury concentration in the surface snow of the coastal snowpack to double, from (9.4 ± 2.0) to (19.2 ± 1.7) ng/L. Independent of the MDE, mercury concentrations increased five-fold, from (10.0 ± 0.1) to (51.4 ± 6.0) ng/L, upon spiking the snow with 500 μM hydrogen peroxide under solar irradiation. Total organic carbon in the spiked irradiated snow samples also decreased, consistent with the formation of strongly oxidizing species. The role of the snowpack in releasing GEM to the atmosphere has been reported; these findings suggest that snow may also play a role in enhancing deposition of mercury.

Keywords: Mercury; Arctic; Atmospheric chemistry; Snow chemistry; Scavenging; Hydrogen peroxide

Article Outline

1. Introduction
2. Experimental methods
2.1. Sampling location and snow collection
2.2. Chemical analysis
3. Results
4. Discussion
5. Conclusion
Acknowledgements
References




 
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