Research paperA chronological framework for the Clyde Foreland Formation, Eastern Canadian Arctic, derived from amino acid racemization and cosmogenic radionuclides
Highlights
► We provide absolute age constraints for previously undateable Quaternary glaciomarine deposits. ► Establish a minimum age of 1.15 ± 0.20 Ma for a buried paleosol. ► Develop the first amino acid racemization calibration for Arctic Canada. ► The 7 glacial advances recorded by these sediments span the Pleistocene. ► The oldest deposits record Late Pliocene/Early Pleistocene ice advances across Baffin Island.
Introduction
The most extensive outcrops of superposed glacial and glaciomarine deposits in the Eastern Canadian Arctic are found along the northeastern coast of Baffin Island on the Clyde Foreland and Qivitu Peninsula (Fig. 1A). Exposed in wave-eroded cliffs are cyclical sedimentary facies deposited on coastal lowlands during successive glaciations (Miller et al., 1977; Nelson, 1981) collectively comprising the Clyde Foreland Formation (CFF; Feyling-Hanssen, 1976a; Andrews et al., 1985; Miller, 1985). During an individual sedimentation cycle, the growth of the Foxe Sector of the Laurentide Ice Sheet (LIS; Fig. 1A) isostatically depressed Baffin Island, and the resulting marine transgression inundated these lowlands. The deposition of silts and sublittoral sand continued until ice advances deposited distal- to proximal glaciomarine sediment, followed by till. As ice retreated, this sequence reversed, and pedogenesis began following a marine regression and reemergence of the coastal lowlands.
Exposures of Plio-Pleistocene sedimentary deposits are found throughout the North American Arctic and at locations around Greenland (Feyling-Hanssen et al., 1983; Funder et al., 2001; Bennike et al., 2002, 2010), northern Alaska (Brigham-Grette and Carter, 1992), and scattered sites across the Arctic Archipelago (Brigham-Grette et al., 1987; Matthews, 1989; Vincent, 1990; Devaney, 1991; Fyles et al., 1998). However, the majority of previously studied marine sediment deposited during eustatic marine transgressions and provides only limited information about past glacial advances and marine conditions during glaciations. Additionally, most of these deposits span only brief intervals of time and interpretations are hampered by ambiguous chronologies. In contrast, the CFF contains a sedimentological succession of seven distinct major Quaternary continental glaciations, as well as a paleontological record of conditions during each of these intervals.
Since Goldthwait (1964) first described these deposits, the CFF has been the subject of investigations of micropaleontology (Feyling-Hanssen, 1976b, 1980, 1985; Feyling-Hanssen et al., 1983), aminostratigraphy (Miller et al., 1977; Mode, 1980; Nelson, 1982; Miller, 1985), sedimentology and stratigraphy (Løken, 1966; Mode, 1980; Nelson, 1981), facies changes (Nelson, 1981), and palynology (Miller, 1976; Mode, 1980). These studies were all limited by the inability to reliably apply any absolute dating tools to the CFF. Absolute dating efforts, some of which were ineffective (Kaufman et al., 1993), have only succeeded in placing minimum-limiting age estimates on some of the deposits using radiocarbon and U-series methods, the results of which suggest the oldest deposits are >300 ka (Szabo et al., 1981). Using amino acid racemization (AAR) measurements and a range of probable effective diagenetic temperatures (EDTs), Miller (1985) suggested that the oldest aminozone is likely 1.6 to 7.9 Ma, and Feyling-Hanssen (1985) inferred a latest Pliocene or Early Pleistocene age for the oldest CFF sediments from tentative biostratigraphic correlations to dated Plio-Pleistocene deposits elsewhere in the Arctic.
Despite the prodigious body of prior CFF research, the resulting detailed micropaleontological record, and the presence of some of the oldest deposits from major LIS advances, we still lack a reliable chronological framework for these sediments. In an effort to make headway into this problem, we apply a cosmogenic radionuclide (CRN) isochron burial dating technique (Balco and Rovey, 2008) to a newly identified paleosol preserved within one of the oldest aminozones of the CFF (Fig. 1B). By using the resulting minimum age to calibrate AAR, we present a refined chronology for the CFF. We also analyzed the palynomorphs within the paleosol, which provide a glimpse into the climate during an Early Pleistocene interglaciation and coastal sediment recycling during preceding glaciations.
Section snippets
Cosmogenic radionuclide geochronology
The paleosol we dated was developed in a 5-m-thick deposit of marine sand that was subsequently buried by glaciomarine deposits. The upper 2 m of the sand is horizontally bedded, and the lower 3 m have 1-m-tall planar crossbeds. The paleosol is exposed at a height of 28.5 m a.s.l. in 32-m-tall cliffs 2.8 km northwest of the mouth of the Kuvinilk River (Fig. 1B). A dark reddish-brown band of oxidized sand, interpreted as a preserved A horizon, gradually fades to the pale yellow color of the
CRN measurements
The 10Be and 26Al concentrations in samples from the depth profile through the paleosol decrease exponentially with depth as expected (Table 1; Fig. 3), and the concentrations in the paleosol are relatively low at 0.9 and 3.2 × 105 for 10Be and 26Al in the A horizon, respectively. The 26Al/10Be ratio of 3.8 is consistent with burial for a minimum of 1.3 Ma, assuming that the ratio was at the surface production ratio upon burial.
AAR measurement and compilation
Results from AAR measurements on 284 individual
Theory
As described above, the isochron burial dating approach is based upon the common post-burial history of a set of samples that contained a range of pre-burial CRN inventories. In our application, we collected samples from a vertical profile through a buried paleosol. If the parent material in which this soil developed was homogenous with respect to the CRN inventory inherited from prior to soil formation, the CRN concentrations in the soil should have decreased exponentially with depth prior to
Conclusions
After nearly half a century of scientific interest in the sedimentary deposits of the CFF, we combined CRN and AAR techniques to construct the first absolute chronologic framework for the formation. Applying CRN burial dating to a paleosol, we present a minimum age for the paleosol burial of 1.15 ± 0.20 Ma. After compiling and adding to the existing isoleucine AAR data from the CFF, we redefined seven aminozones, and using a piecewise linear-logarithmic model for isoleucine epimerization in H.
Acknowledgments
This research was funded by NSF award ARC-0903024 (GHM) and grants from the Geological Society of America, Shell Oil, and the University of Colorado Beverly Sears Graduate Student Grant program (KAR). We thank the Nunavut Research Institute, Jamesee Qillaq, Allen Kooneeliusie, and Mina Kunilusie for logistical support, the Inuit of Nunavut for permission to work on their land, Devin Girtin, Margaret Barnes, Keith Brugger, and Alexis Ault for assistance in the field, and Sam Cantor and Charles
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