doi:10.1016/j.physd.2005.06.010
Copyright © 2005 Elsevier B.V. All rights reserved.
Collision versus collapse of droplets in coarsening of dewetting thin films
aDepartment of Mathematics, University of Arizona, Tucson, AZ 85721, USA
bDepartment of Mathematics and Center for Nonlinear and Complex Systems, Duke University, Durham, NC 27708-0320, USA
Available online 12 July 2005.
References and further reading may be available for this article. To view references and further reading you must
purchase this article.
Abstract
Thin films of viscous fluids coating solid surfaces can become unstable due to intermolecular forces, leading to break-up of the film into arrays of droplets. The long-time dynamics of the system can be represented in terms of coupled equations for the masses and positions of the droplets. Analysis of the decrease of energy of the system shows that coarsening, decreasing the number of droplets with increasing time, is favored. Here we describe the two coarsening mechanisms present in dewetting films: (i) mass exchange leading to collapse of individual drops, and (ii) spatial motion leading to droplet collisions and merging events. Regimes where each of mechanisms are dominant are identified, and the statistics of the coarsening process are explained.
Keywords: Dewetting; Coarsening; Thin films; van der Waals forces; Fluid dynamics; Lubrication models
Fig. 1. Numerical simulations of the lubrication model for a dewetting thin film: (left) the evolution of a film at successive times showing droplet collision and collapse events (both circled), (right) the long-time scaling behavior for coarsening of the number of drops N(t)in a large system as a function of time.
Fig. 2. A stable steady-state droplet solution
showing the three regions in the asymptotic structure of the solution for
→0: (i) droplet core, (ii) contact line, (iii) outer ultra-thin film. The dashed curve shows the leading order asymptotic solution for the droplet core, the parabola (2.7), with width
.
Fig. 3. Dynamics of two typical adjacent droplets in a dewetting film. The interaction of the droplets generally yields mass exchange and spatial motion.
Fig. 4. Fundamental modes of evolution for a single droplet: (left) translation and (right) change of mass.
Fig. 5. The CX(P)drift coefficient function (2.13) and its asymptotic behaviors for large drops (P→0)(2.22) and small drops (P→pmax).
Fig. 6. Numerical simulation of two interacting drops in the lubrication PDE (2.1). As predicted by the ODE model (3.4), collision cannot occur.
Fig. 7. A schematic figure of a system of four drops used to study collision interactions.
Fig. 8. Contour lines of the asymptotic collision distance ratio, r=D2,3/D1,2(3.12), as a function of P1,P3for a fixed value of P2. This structure of the solution is generic for all values of P2.
Fig. 9. Plots of droplet histories in the xtplane for two different versions of the collision events suggested by (3.6): (a) a nearly symmetric 3-drop interaction, and (b) a more asymmetric quasi-2-drop collision. The solid stripes indicate the positions of droplet cores, with supports given on
for k=1,2,3,4.
Fig. 10. Droplet histories in the xt plane (corresponding to Fig. 1) from numerical simulations of the full PDE, notice that the collision event (left) resembles the asymmetric “quasi-2-drop” collision in Fig. 9 b, while the collapse event (right) is more symmetric.
Fig. 11. Details of the collision and merging process: (a) two near-equilibrium droplet evolving toward collision, (b) the formation of the collided “two-drop complex” and its rapid convexification, (c) symmetrization and contraction to yield a single merged near-equilibrium droplet.
Fig. 12. Evolution of the energy for the numerical solution of the PDE, corresponding to the dynamics shown in Fig. 1 and Fig. 10 including a collision and a collapse event.
Fig. 13. Schematic of the fastest growing global instability modes: (a) the primary instability, connected to coarsening by collapse (4.10), and (b) the dominant secondary instability, connected to coarsening by collision (4.13).
Fig. 16. (Left) Plot of N(t)from simulations of (2.15) at several values of
, for j=0,1,2,…,5, and (right) the same data rescaled according to (4.19).
Fig. 17. N(t) for the three simulations shown in Fig. 14 for
values in the collision, collapse and mixed coarsening regimes (solid dots) compared with the scaling law predicted by (4.22) (dotted lines).
Fig. 18. The phase plane for Eq. (2.6) at a value of
in the range
. The droplet solution is given by the homoclinic orbit to
(solid curve).