Elsevier

Mendeleev Communications

Volume 27, Issue 6, November–December 2017, Pages 615-617
Mendeleev Communications

Diphenylacetylene hydrogenation on a PdAg /Al2O3 single-atom catalyst: an experimental and DFT study

https://doi.org/10.1016/j.mencom.2017.11.026Get rights and content

The hydrogenation of diphenylacetylene (DPA) on palladium–silver catalysts with a single-atom structure was investigated. It has been shown experimentally that the reaction rate of alkene to alkane hydrogenation is substantially lower than the rate of DPA semi-hydrogenation. The kinetic barriers of all stages of hydrogenation were calculated by the DFT method.

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