Difference in α-thiocyanation of malonates, β-oxo esters and β-diketones with sodium thiocyanate and cerium(IV) ammonium nitrate
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Cerium(IV) ammonium nitrate: Reagent for the versatile oxidative functionalization of styrenes using N-hydroxyphthalimide
2019, TetrahedronCitation Excerpt :Large number of papers is devoted to CAN-catalyzed processes [10,11]. CAN is known to generate radicals from 1,3-dicarbonyl compounds [12,13], azide anions [14,15], thiocyano-anions [6,15] and sulfinates [16]. Under the action of CAN, N-hydroxyphthalimide (NHPI) is oxidized to the phthalimide-N-oxyl (PINO) radical [17], which is the effective mediator of aerobic oxygenation and various processes of CH functionalization [18–22].
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