Timing of subduction and exhumation in a subduction channel: Evidence from slab melts from La Corea Mélange (eastern Cuba)
Highlights
► We study tonalite rocks formed by partial melting of the slab. ► Thermobarometric calculations indicate counter-clockwise P–T paths. ► Zircon (SHRIMP) data give the timing of crystallization of melts at ~ 110–105 Ma. ► Phengite 40Ar/39Ar ages provide the cooling at ~ 87–84 Ma. ► These data indicate very slow syn-subduction/exhumation (1 mm/a).
Introduction
The evolution of a subduction zone can be broadly divided into three main phases: (1) onset of subduction, (2) mature stage and (3) cessation of subduction. Exhumation of ancient and recent rock complexes allow a good characterization and recognition of the mature (i.e., volcanic arc development, formation of eclogites and blueschists) and demise (by means of arc-continent, arc-arc, or arc-ocean collision, with termination of volcanic arc activity and emplacement of ophiolites) phases. However, the onset of the subduction phase is less well-known because of the intrinsic complexities of this transient period. It is unclear how subduction zones are initiated (cf. Stern, 2002, Stern, 2004) and, in addition, rocks formed during the earliest phases of subduction will normally disappear in the mantle and are therefore not commonly observed on the surface.
According to Stern (2004) subduction is initiated either by convergence of lithospheric plates and blocking of a subduction zone by incoming buoyant continental or oceanic crust (induced onset of subduction) or by gravitational collapse of oceanic lithosphere (spontaneous onset of subduction). Transference or polarity reversal of subduction characterizes the induced type, whereas the spontaneous type occurs at a passive margin or at a transform/fracture zone, normally if the downgoing plate is old (i.e., cold and dense). Both types of onset of subduction are characterized by warm-hot geothermal gradients (relative to mature subduction) along the subduction interface, but spontaneous initiation of subduction of old lithosphere should be characterized by relatively colder conditions (relative to young lithosphere; e.g., Peacock, 2003, Peacock and Wang, 1999). In both types, however, subducted rocks accreted to the upper plate during the early stages of subduction show counter-clockwise P–T (pressure–temperature) paths during exhumation due to the effects of continued refrigeration of the subduction system during the mature stage (Gerya et al., 2002), whereas subducted rocks accreted during the mature stage follow hairpin P–T paths (Ernst, 1988, Wakabayashi, 2004). In addition, convective circulation of the subducted and accreted materials in the subduction channel can be produced (Blanco-Quintero et al., 2011a).
During the onset of subduction, the fluids released from subducted sediments, altered basaltic crust and serpentinitic abyssal peridotite begin fluxing the upper plate. Much of the upper plate lithospheric mantle is characterized at this stage by hydrous peridotite, because the temperature at relatively shallow depth is above the stability field of antigorite (> 650 °C; Ulmer and Trommsdorff, 1995). During the mature stage antigorite serpentinite forms in the upper plate mantle down to ca. 100 km depth, because continued subduction produces the refrigeration of the interface (Gerya et al., 2002). This process triggers the formation of a buoyant serpentinitic subduction channel at the plate interface which provides the medium for syn-subduction exhumation of accreted high-pressure rocks (Gerya et al., 2002, Guillot et al., 2000, Guillot et al., 2001). Hence, exhumation of high-pressure rocks accreted to the upper mantle during the onset of subduction is delayed until the mature phase when the subduction channel is formed. This has important consequences for early accreted rocks, which undergo near-isobaric cooling at the upper plate before exhumation in the channel begins (i.e., counter-clockwise PT paths; Gerya et al., 2002).
Serpentinite mélanges bearing high-pressure blocks are commonly considered to represent exhumed fragments of subduction channels (Agard et al., 2009, Guillot et al., 2000, Guillot et al., 2001). In these mélanges, the timing of exhumation of subducted mafic oceanic crust relative to the onset of subduction is highly variable, though it appears that in most cases exhumation is episodic (Agard et al., 2009). In the northern Caribbean (Fig. 1a), high-pressure blocks in serpentinite mélanges record a protracted history of subduction and continued exhumation lasting for ca. 60 Ma, from onset of subduction until final exhumation to the Earth's surface (Krebs et al., 2008, Lázaro et al., 2009). Early subducted rocks record hot geothermal gradients along the plate interface during the onset of subduction (García-Casco et al., 2008a, Lázaro et al., 2009). In eastern Cuba, the Sierra del Convento and the La Corea mélanges (Fig. 1b) record the rare case of partial melting of subducted basaltic crust at relatively shallow depth (ca. 50 km), documenting hot conditions related to subduction of very young lithosphere or even a ridge (Blanco-Quintero et al., 2010, Blanco-Quintero et al., 2011b, García-Casco et al., 2008a, Lázaro and García-Casco, 2008). Such a young age for the subducting lithosphere would indicate induced rather than spontaneous onset of subduction. Lázaro et al. (2009) dated blocks of high-pressure amphibolite and associated tonalitic–trondhjemitic rocks formed after partial melting of the former and provided a comprehensive P–T–t path for the Sierra del Convento mélange. The data presented by Lázaro et al. (2009) indicate that onset of exhumation was delayed by < ca. 10 Ma since accretion of subducted crust occurred and that syn-subduction exhumation in the channel continued for ca. 40 Ma at very slow rates (0.7 mm/yr). We report new petrological, geochemical and geochronological (SHRIMP zircon and phengite 40Ar/39Ar) data for tonalite rocks of the La Corea mélange, eastern Cuba, in order to provide clues for deciphering the nature and age of hot, deep-seated processes that occurred during subduction of young oceanic lithosphere in the Caribbean realm.
Section snippets
Geological setting
The Greater Antilles belt accreted to the southern margin of the North American plate in the Tertiary (Iturralde-Vinent et al., 2008, Pindell and Kennan, 2009, Pindell et al., 2006; Fig. 1a). It evolved during the Mesozoic–Tertiary along the northern edge of the Caribbean plate margin where Proto-Caribbean (i.e., Atlantic) lithosphere was consumed and a complex intra-oceanic volcanic arc (or arcs) developed (Pindell and Kennan, 2009, Pindell et al., 2006 and references therein). Onset of
Microprobe analyses
Mineral compositions were obtained by Wavelength Dispersive Spectroscopy (WDS) with a CAMECA SX-100 microprobe (Centro de Instrumentación Científica – CIC – from University of Granada), operated at 15 kV and 15 nA, with a beam size of 5 μm and standards used for element calibrations were: albite (Na), quartz (Si), periclase (Mg), sanidine (K), rutile (Ti), hematite (Fe), diopside (Ca), vanadinite (Cl), barite (Ba), fluorite (F), chromite (Cr), Al2O3 (Al), MnTiO3 (Mn) and NiO (Ni). Detection limit
Petrography
The studied samples are tonalitic in composition, composed of primary medium-grained plagioclase and quartz (Fig. 2e, f). These minerals make up more than 75% of the modal mineralogy. In general, the rocks are not deformed, except for sample LCG-2 which has a strong foliation. Subordinate idiomorphic clinozoisite, phengite and amphibole are present (Fig. 2e, f), and apatite, titanite and rutile are present in small amounts. Clinozoisite is idiomorphic and prismatic with faint zonation. The
Whole-rock chemistry
The rocks exhibit a great range of SiO2 contents from 58.82 to 75.66 wt.%. The high-silica samples have the lower Al2O3 (14.17 wt.%), CaO (4.29 wt.%) and Na2O (3.3 wt.%), in correspondence to high proportion of quartz and low plagioclase. Similarly, the low-silica samples are rich in CaO (7.42 wt.%), in agreement with the abundance of epidote. The K2O (0.22–0.63 wt.%) contents are low in all samples. The FeO and MgO contents are low, and the Mg # is relatively homogenous, ranging from 0.42 to 0.45.
Zircon ages
Zircon grains of tonalite sample LCG-1 are clear, long-prismatic and display well developed oscillatory magmatic zoning under cathodoluminenscence (Fig. 9a) with no older cores. Six grains were analyzed on SHRIMP II, and the concordant data are well grouped, providing a mean 206Pb/238U age of 109.7 ± 1.7 Ma (Fig. 9a). Zircon grains of sample LCG-3 are also clear (Fig. 9b), mostly euhedral and long-prismatic with oscillatory magmatic zoning. Five grains provided consistent and concordant results
Petrogenesis of leucocratic rocks
The leucocratic rocks in La Corea mélange have distinct REE patterns with a negative slope and positive Eu anomalies (Fig. 8), high Sr/Y > 80, SiO2 > 58 wt.%, Al2O3 > 14 wt.%, but very low Yb < 0.35 ppm, Y < 6 ppm (Fig. 11) and (La/Yb)n < 6, indicating an adakitic affinity (e.g., Defant and Drummond, 1990, Martin, 1999). The Y and HREE depletion, typical of adakites, is explained by the presence of residual garnet in the source, whereas the Sr enrichment and negative Nb anomaly are thought to be due to the
Conclusions
Field, petrologic and whole-rock chemical data indicate that tonalitic rocks from the La Corea mélange in eastern Cuba represent melts formed during partial melting of subducted and accreted amphibolites. SHRIMP zircon ages of the tonalites provide crystallization ages from 105 to 110 Ma, and are interpreted to date partial melting processes in the subduction channel. This implies accretion of subducting amphibolites to the upper plate and ensuing infiltration of fluids released from downgoing
Acknowledgments
We appreciate constructive comments of Esteban Gazel and an anonymous reviewer that substantially improved this paper, and thanks editor A. Kerr for editorial suggestions. We appreciate financial support from Spanish MICINN projects CGL2006-08527/BTE and CGL2009-08527/BTE. We thank Bert De Waele and Neal McNaughton from the University of Western Australia for help with CL imaging and for assistance during sample preparation, respectively. Mike Wingate of the Geological Survey of Western
References (90)
- et al.
Exhumation of oceanic blueschists and eclogites in subduction zones: timing and mechanisms
Earth Science Reviews
(2009) Trondhjemite: definition, environment and hypotheses of origin
- et al.
TEMORA 1: a quality zircon standard for Phanerozoic U-Pb geochronology
Chemical Geology
(2003) - et al.
Metamorphic reworking of a high pressure–low temperature mélange along the Motagua fault, Guatemala: a record of Neocomian and Maastrichtian transpressional tectonics
Earth and Planetary Science Letters
(2009) - et al.
A double focusing mass spectrometer for geochronology
International Journal of Mass Spectrometry
(1998) - et al.
Interpretation of discordant 40Ar/39Ar spectra of Mesozoic tholeiites from Antarctica
Geochimica et Cosmochimica Acta
(1977) - et al.
Arc-plume interaction in Central America: influx of Galapagos asthenosphere and slab melting
Lithos
(2011) - et al.
Evidence of hydration of the mantle wedge and its role in the exhumation of eclogites
Earth and Planet Science Letters
(2001) - et al.
Mantle plume or slab window?: physical and geochemical constraints on the origin of the Caribbean oceanic plateau
Earth Science Reviews
(2010) - et al.
Geochronology, geochemistry and petrogenesis of rhyodacite lavas in eastern Jamaica: a new adakite subgroup analogous to early Archaean continental crust?
Chemical Geology
(2010)
The dynamics of intra-oceanic subduction zones: a direct comparison between fossil petrological evidence (Rio San Juan Complex, Dominican Republic) and numerical simulation
Lithos
Mass flow in serpentinite-hosted subduction channels: P-T-t path patterns of metamorphic blocks in the Rio San Juan mélange (Dominican Republic)
Journal of Asian Earth Sciences
Geochemical and Sr–Nd isotope signatures of pristine slab melts and their residues (Sierra del Convento mélange, eastern Cuba)
Chemical Geology
The imprint of subduction fluids on subducted MORB-derived melts (Sierra del Convento mélange, Cuba)
Lithos
The adakitic magmas: modern analogues of Archaean granitoids
Lithos
The composition of the earth
Chemical Geology
Application of deuteron–deuteron (D–D) fusion neutrons to 40Ar/39Ar geochronology
Applied Radiation and Isotopes
Cl-derived argon isotope production in the CLICIT facility of OSTR reactor and the effects of the Cl-correction in 40Ar/39Ar geochronology
Chemical Geology
Joint determination of 40 K decay constants and 40Ar*/40 K for the Fish Canyon sanidine standard, and improved accuracy for 40Ar/39Ar geochronology
Geochimica et Cosmochimica Acta
The isotopic composition of atmospheric argon and 40Ar/39Ar geochronology: time for a change?
Quaternary Geochronology
Subcommission on geochronology: convention on the use of decay constants in geo- and cosmochronology
Earth and Planetary Science Letters
Subduction initiation: spontaneous and induced
Earth and Planetary Science Letters
CSpace: an integrated workplace for the graphical and algebraic analysis of phase assemblages on 32-bit Wintel platforms
Computers and Geosciences
Tectonic mechanisms associated with P–T paths of regional metamorphism: alternatives to single-cycle thrusting and heating
Tectonophysics
Principales características de la geología y de los minerales útiles de la región nordeste de la Provincia de Oriente
Revista Tecnológica
Upper Triassic to Cretaceous radiolaria from Nicaragua and northern Costa Rica — the Mesquito composite oceanic terrane
Ofioliti
Metamorphic evolution of subducted hot oceanic crust, La Corea mélange, Cuba
American Journal of Science
Tectonic blocks in serpentinite melange (eastern cuba) reveal large-scale convective flow of the subduction channel
Geology
Barium-rich fluids and melts in the subduction environment (La Corea and Sierra del Convento mélanges, eastern Cuba)
Contributions to Mineralogy and Petrology
Serpentinites and serpentinites within a fossil subdution channel: La Corea mélange, eastern Cuba
Geologica Acta
Tectonic evolution of the Caribbean
Annual Reviews of Earth and Planetary Sciences
Geología del flanco sur de la Sierra del Purial
Revista La Minería de Cuba
Geología de la Región Central y Suroriental de la Provincia de Guantánamo
Mixing properties of phengitic micas and revised garnet-phengite thermobarometers
Journal of Metamorphic Geology
Zircon U–Pb ages for the Early Cambrian time scale
Journal Geological Society London
Derivation of some modern arc magmas by melting of young subducted lithosphere
Nature
The geochemistry of young volcanism throughout Western Panama and Southeastern Costa-Rica — an overview
Journal of the Geological Society
A new thermo-dynamic model for clino- and orthoamphiboles in Na2O–CaO–FeO–MgO–Al2O3–SiO2–H2O–O
Journal of Metamorphic Geology
Plate tectonic evolution of the Caribbean region in the mantle reference frame
Tectonic history of subduction zones inferred from retrograde blueschist P–T paths
Geology
High pressure metamorphism of ophiolites in Cuba
Geologica Acta
Partial melting and counterclockwise P–T path of subducted oceanic crust (Sierra del Convento mélange, Cuba)
Journal of Petrology
Latest Cretaceous collision/accretion between the Caribbean Plate and Caribeana: origin of metamorphic terranes in the Greater Antilles
International Geology Review
Exhumation of high-pressure metamorphic rocks in a subduction channel — a numerical simulation
Tectonics
Asthenospheric upwelling, oceanic slab retreat and exhumation of UHP mantle rocks: insights from Greater Antilles
Geophysical Research Letters
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2020, Journal of Asian Earth SciencesCitation Excerpt :These differences in trace elements might be explained by the presence of garnet in the source of the 112 Ma leucogranitic dike (Martin, 1999; Yu et al., 2019). The presence of amphibole or rutile in the melt residue might also be indicated by the negative Nb-Ta anomalies (Blanco-Quintero et al., 2011; Hastie et al.,2010). Moreover, the high concentration of Sr (269 ppm), and high Sr/Y (=61) and La(N)/Yb(N) (=20.7) ratios indicate that this leucogranite dike was sourced from an adakite-type magma (Defant and Drummond, 1990; Martin, 1999; Fig. 14).