Elsevier

Lithos

Volume 127, Issues 1–2, November 2011, Pages 86-100
Lithos

Timing of subduction and exhumation in a subduction channel: Evidence from slab melts from La Corea Mélange (eastern Cuba)

https://doi.org/10.1016/j.lithos.2011.08.009Get rights and content

Abstract

High pressure igneous rocks (tonalites), generated by partial melting of subducted basaltic rocks accreted to the mantle wedge, are present in the La Corea serpentinite-matrix mélange (eastern Cuba) as centimeter- to meter-sized blocks and as concordant to crosscutting veins within high-pressure parent amphibolite blocks. The slab melts have adakitic signatures, in agreement with formation after partial melting of metabasite. Thermobarometric calculations indicate 620–680 °C and 13–15 kbar during crystallization of tonalites and down to 250–300 °C, 6 kbar during retrogression, indicating counter-clockwise P–T paths (hot subduction-cool exhumation). Free water required for melting of amphibolite at moderate temperature (700–750 °C) and moderate pressure (13–16 kbar) close to the wet basaltic solidus is inferred to have been provided after dehydration of sediments, altered basaltic crust and serpentinite of the subducting Proto-Caribbean lithosphere. Single zircon (SHRIMP) and phengite 40Ar/39Ar age data constrain the P–T–t evolution of the mélange from the timing of crystallization of melts at ~ 110–105 Ma to cooling at ~ 87–84 Ma, ca. 350 °C, ca. 9 kbar. These figures are consistent with subduction of an oblique ridge, shortly before 115 Ma. Furthermore, our data indicate very slow exhumation (ca. 1 mm/yr) in the subduction channel during the oceanic convergence stage (120–70 Ma) until final fast exhumation to the surface occurred at 70–65 Ma during a regional arc-platform collision event.

Highlights

► We study tonalite rocks formed by partial melting of the slab. ► Thermobarometric calculations indicate counter-clockwise P–T paths. ► Zircon (SHRIMP) data give the timing of crystallization of melts at ~ 110–105 Ma. ► Phengite 40Ar/39Ar ages provide the cooling at ~ 87–84 Ma. ► These data indicate very slow syn-subduction/exhumation (1 mm/a).

Introduction

The evolution of a subduction zone can be broadly divided into three main phases: (1) onset of subduction, (2) mature stage and (3) cessation of subduction. Exhumation of ancient and recent rock complexes allow a good characterization and recognition of the mature (i.e., volcanic arc development, formation of eclogites and blueschists) and demise (by means of arc-continent, arc-arc, or arc-ocean collision, with termination of volcanic arc activity and emplacement of ophiolites) phases. However, the onset of the subduction phase is less well-known because of the intrinsic complexities of this transient period. It is unclear how subduction zones are initiated (cf. Stern, 2002, Stern, 2004) and, in addition, rocks formed during the earliest phases of subduction will normally disappear in the mantle and are therefore not commonly observed on the surface.

According to Stern (2004) subduction is initiated either by convergence of lithospheric plates and blocking of a subduction zone by incoming buoyant continental or oceanic crust (induced onset of subduction) or by gravitational collapse of oceanic lithosphere (spontaneous onset of subduction). Transference or polarity reversal of subduction characterizes the induced type, whereas the spontaneous type occurs at a passive margin or at a transform/fracture zone, normally if the downgoing plate is old (i.e., cold and dense). Both types of onset of subduction are characterized by warm-hot geothermal gradients (relative to mature subduction) along the subduction interface, but spontaneous initiation of subduction of old lithosphere should be characterized by relatively colder conditions (relative to young lithosphere; e.g., Peacock, 2003, Peacock and Wang, 1999). In both types, however, subducted rocks accreted to the upper plate during the early stages of subduction show counter-clockwise P–T (pressure–temperature) paths during exhumation due to the effects of continued refrigeration of the subduction system during the mature stage (Gerya et al., 2002), whereas subducted rocks accreted during the mature stage follow hairpin P–T paths (Ernst, 1988, Wakabayashi, 2004). In addition, convective circulation of the subducted and accreted materials in the subduction channel can be produced (Blanco-Quintero et al., 2011a).

During the onset of subduction, the fluids released from subducted sediments, altered basaltic crust and serpentinitic abyssal peridotite begin fluxing the upper plate. Much of the upper plate lithospheric mantle is characterized at this stage by hydrous peridotite, because the temperature at relatively shallow depth is above the stability field of antigorite (> 650 °C; Ulmer and Trommsdorff, 1995). During the mature stage antigorite serpentinite forms in the upper plate mantle down to ca. 100 km depth, because continued subduction produces the refrigeration of the interface (Gerya et al., 2002). This process triggers the formation of a buoyant serpentinitic subduction channel at the plate interface which provides the medium for syn-subduction exhumation of accreted high-pressure rocks (Gerya et al., 2002, Guillot et al., 2000, Guillot et al., 2001). Hence, exhumation of high-pressure rocks accreted to the upper mantle during the onset of subduction is delayed until the mature phase when the subduction channel is formed. This has important consequences for early accreted rocks, which undergo near-isobaric cooling at the upper plate before exhumation in the channel begins (i.e., counter-clockwise PT paths; Gerya et al., 2002).

Serpentinite mélanges bearing high-pressure blocks are commonly considered to represent exhumed fragments of subduction channels (Agard et al., 2009, Guillot et al., 2000, Guillot et al., 2001). In these mélanges, the timing of exhumation of subducted mafic oceanic crust relative to the onset of subduction is highly variable, though it appears that in most cases exhumation is episodic (Agard et al., 2009). In the northern Caribbean (Fig. 1a), high-pressure blocks in serpentinite mélanges record a protracted history of subduction and continued exhumation lasting for ca. 60 Ma, from onset of subduction until final exhumation to the Earth's surface (Krebs et al., 2008, Lázaro et al., 2009). Early subducted rocks record hot geothermal gradients along the plate interface during the onset of subduction (García-Casco et al., 2008a, Lázaro et al., 2009). In eastern Cuba, the Sierra del Convento and the La Corea mélanges (Fig. 1b) record the rare case of partial melting of subducted basaltic crust at relatively shallow depth (ca. 50 km), documenting hot conditions related to subduction of very young lithosphere or even a ridge (Blanco-Quintero et al., 2010, Blanco-Quintero et al., 2011b, García-Casco et al., 2008a, Lázaro and García-Casco, 2008). Such a young age for the subducting lithosphere would indicate induced rather than spontaneous onset of subduction. Lázaro et al. (2009) dated blocks of high-pressure amphibolite and associated tonalitic–trondhjemitic rocks formed after partial melting of the former and provided a comprehensive P–T–t path for the Sierra del Convento mélange. The data presented by Lázaro et al. (2009) indicate that onset of exhumation was delayed by < ca. 10 Ma since accretion of subducted crust occurred and that syn-subduction exhumation in the channel continued for ca. 40 Ma at very slow rates (0.7 mm/yr). We report new petrological, geochemical and geochronological (SHRIMP zircon and phengite 40Ar/39Ar) data for tonalite rocks of the La Corea mélange, eastern Cuba, in order to provide clues for deciphering the nature and age of hot, deep-seated processes that occurred during subduction of young oceanic lithosphere in the Caribbean realm.

Section snippets

Geological setting

The Greater Antilles belt accreted to the southern margin of the North American plate in the Tertiary (Iturralde-Vinent et al., 2008, Pindell and Kennan, 2009, Pindell et al., 2006; Fig. 1a). It evolved during the Mesozoic–Tertiary along the northern edge of the Caribbean plate margin where Proto-Caribbean (i.e., Atlantic) lithosphere was consumed and a complex intra-oceanic volcanic arc (or arcs) developed (Pindell and Kennan, 2009, Pindell et al., 2006 and references therein). Onset of

Microprobe analyses

Mineral compositions were obtained by Wavelength Dispersive Spectroscopy (WDS) with a CAMECA SX-100 microprobe (Centro de Instrumentación Científica – CIC – from University of Granada), operated at 15 kV and 15 nA, with a beam size of 5 μm and standards used for element calibrations were: albite (Na), quartz (Si), periclase (Mg), sanidine (K), rutile (Ti), hematite (Fe), diopside (Ca), vanadinite (Cl), barite (Ba), fluorite (F), chromite (Cr), Al2O3 (Al), MnTiO3 (Mn) and NiO (Ni). Detection limit

Petrography

The studied samples are tonalitic in composition, composed of primary medium-grained plagioclase and quartz (Fig. 2e, f). These minerals make up more than 75% of the modal mineralogy. In general, the rocks are not deformed, except for sample LCG-2 which has a strong foliation. Subordinate idiomorphic clinozoisite, phengite and amphibole are present (Fig. 2e, f), and apatite, titanite and rutile are present in small amounts. Clinozoisite is idiomorphic and prismatic with faint zonation. The

Whole-rock chemistry

The rocks exhibit a great range of SiO2 contents from 58.82 to 75.66 wt.%. The high-silica samples have the lower Al2O3 (14.17 wt.%), CaO (4.29 wt.%) and Na2O (3.3 wt.%), in correspondence to high proportion of quartz and low plagioclase. Similarly, the low-silica samples are rich in CaO (7.42 wt.%), in agreement with the abundance of epidote. The K2O (0.22–0.63 wt.%) contents are low in all samples. The FeO and MgO contents are low, and the Mg # is relatively homogenous, ranging from 0.42 to 0.45.

Zircon ages

Zircon grains of tonalite sample LCG-1 are clear, long-prismatic and display well developed oscillatory magmatic zoning under cathodoluminenscence (Fig. 9a) with no older cores. Six grains were analyzed on SHRIMP II, and the concordant data are well grouped, providing a mean 206Pb/238U age of 109.7 ± 1.7 Ma (Fig. 9a). Zircon grains of sample LCG-3 are also clear (Fig. 9b), mostly euhedral and long-prismatic with oscillatory magmatic zoning. Five grains provided consistent and concordant results

Petrogenesis of leucocratic rocks

The leucocratic rocks in La Corea mélange have distinct REE patterns with a negative slope and positive Eu anomalies (Fig. 8), high Sr/Y > 80, SiO2 > 58 wt.%, Al2O3 > 14 wt.%, but very low Yb < 0.35 ppm, Y < 6 ppm (Fig. 11) and (La/Yb)n < 6, indicating an adakitic affinity (e.g., Defant and Drummond, 1990, Martin, 1999). The Y and HREE depletion, typical of adakites, is explained by the presence of residual garnet in the source, whereas the Sr enrichment and negative Nb anomaly are thought to be due to the

Conclusions

Field, petrologic and whole-rock chemical data indicate that tonalitic rocks from the La Corea mélange in eastern Cuba represent melts formed during partial melting of subducted and accreted amphibolites. SHRIMP zircon ages of the tonalites provide crystallization ages from 105 to 110 Ma, and are interpreted to date partial melting processes in the subduction channel. This implies accretion of subducting amphibolites to the upper plate and ensuing infiltration of fluids released from downgoing

Acknowledgments

We appreciate constructive comments of Esteban Gazel and an anonymous reviewer that substantially improved this paper, and thanks editor A. Kerr for editorial suggestions. We appreciate financial support from Spanish MICINN projects CGL2006-08527/BTE and CGL2009-08527/BTE. We thank Bert De Waele and Neal McNaughton from the University of Western Australia for help with CL imaging and for assistance during sample preparation, respectively. Mike Wingate of the Geological Survey of Western

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