Photoionization of S3+ using the Breit-Pauli R-matrix method

https://doi.org/10.1016/j.jqsrt.2017.09.027Get rights and content
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Highlights

  • Brief description of the electron scattering S V and photoionization of S IV within the R-matrix method.

  • Bound target states description, level energies, and the radiative transition probabilities between them.

  • Photoionization of SIV ground state using LS- coupling within the R-matrix approach.

  • Statistically weighted, level resolved ground photoionization cross sections for the S IV ion.

  • Cross sections are evaluated at photon energy ranging from the SV 3s2 threshold up to the SV 4s threshold.

Abstract

Sulphur is one of the most abundant chemical elements in the universe and a large number of lines have been observed in the spectra of astrophysical object. The S IV and SV ions considered in this work have received much interest in the last decade. The main objective of the present work is to report on photoionization cross-sections of S IV using the Breit-Pauli R-matrix (BPRM) method. We have carried out extensive non-relativistic and relativistic calculations of the photoionization cross sections to focus on relativistic effects. The reliability of the atomic data presented here has been carefully tested. We have exploited the BPRM code to describe the atomic wavefunctions and generate the energy levels for the SV 81 fine-structure bound target states and the corresponding A-values for transitions between these levels. The partial and total cross sections for the photoionization of the Al-like S3+ ground and excited states are determined for photon energy ranging from the S4+ 3s2 threshold up to the S4+ 4s threshold. We present statistically weighted, level resolved ground photoionization cross sections for the S IV ion. Both resonance positions and the oscillator strengths are presented. Extensive comparison of the present calculated values with those obtained from direct theoretical scattering calculation is also presented. To the best of our knowledge, the work reported herein describes for the first time a detailed relativistic photoionization calculation for this system, and the results are relevant to the laboratory and astrophysical plasmas.

Keywords

R-matrix
Photoionization
Electron-impact excitation
Cross sections

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