Avoiding cross-linking in iron-polyphosphazene metallo-polymers
Graphical abstract
Cross-linking in metallo-polyphosphazenes can be prevented by attaching two bidentate donors in a geminal fashion to the phosphorus atoms in the polymer chain.
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Acknowledgements
We thank the Massey University Research Fund for financial support and a PhD Scholarship (to R.J.D.). We also thank Associate Professor S.G. Telfer and the MacDiarmid Institute for Advanced Materials and Nanotechnology for the use of the Spider Diffractometer, Professor K.C. Gordon and Dr R. Horvath (The University of Otago) for Resonance Raman data and G. Weal (The University of Otago) for help in collecting Mössbauer data.
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