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International Journal of Solids and Structures
Volume 41, Issues 24-25, December 2004, Pages 6895-6903
 
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doi:10.1016/j.ijsolstr.2004.06.014    How to Cite or Link Using DOI (Opens New Window)
Copyright © 2004 Elsevier Ltd. All rights reserved.

Molecular assembly on cylindrical surfaces

W. Hong and Z. SuoCorresponding Author Contact Information, E-mail The Corresponding Author

Division of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138, USA

Received 22 December 2003; 
Revised 8 June 2004. 
Available online 15 July 2004.

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Abstract

A molecule adsorbed on a metal surface carries an electric dipole moment, and diffuses on the surface. When a collection of identical molecules partially covers the surface, the dipole–dipole interactions, along with other thermodynamic forces, drive the molecules to aggregate into monolayer islands, in the shape of dots or stripes. The dipole–dipole interactions mediate through the electrostatic field in the space. If the space is shaped, the electrostatic field will be affected, and so will the molecular pattern. To illustrate this idea, we develop a model to evolve molecular pattern on the surface of a wire, or the inner surface of a tube. Molecules assemble into parallel rings on the wire, and parallel stripes on the internal surface of a tube. When the tube radius is comparable to, or smaller than, the island size, the stripes switch to the rings; occasionally, the stripes form spirals.

Author Keywords: Self-assembly; Cylindrical surface; Phase pattern; Adsorbate

Article Outline

1. Introduction
2. The model
3. Electrostatic field in the Fourier space
4. Numerical method
5. Simulation results
6. Concluding remarks
Acknowledgements
References






 
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