Estimation of the state-of-charge of gel lead-acid batteries and application to the control of a stand-alone wind-solar test-bed with hydrogen support

https://doi.org/10.1016/j.ijhydene.2012.05.001Get rights and content

Abstract

In hybrid renewable energy systems, batteries act as a DC bus to provide constant voltage and to smooth out commutations between the generating devices. These batteries are usually of a lead-acid type and operate under harsh variable conditions due to fluctuations of both solar radiation and wind speed. Precise knowledge of the state-of-charge of the batteries, and hence of their available energy, play a key role in effecting efficient control and energy management of the installation. The present study had a twofold aim. One objective was to adjust and validate a method based on coulomb counting to estimate the state-of-charge (SOC) of a gelled lead-acid battery which is the DC bus of a hybrid wind-solar system with hydrogen storage. Other works evaluate SOC models based on several parameters, however, the present proposal based on experimental measurements involves only a few parameters. The second objective was to modify the installation's control algorithm to use the battery's calculated SOC as control parameter instead of its voltage. The results of a test-bed system, showing how the system evolved under real operating conditions, constitute a proof-of-concept of the validity of the method.

Highlights

► We use a lead-acid gelled battery as the DC bus of a test-bed wind-solar system. ► The test-bed is a stand-alone hybrid wind-solar system with hydrogen support. ► A coulomb counting method is proposed for estimating the battery state-of-charge, SOC. ► An SOC-based control algorithm is implemented for the electrolyzer's operation. ► Experimental results validated the applied method and algorithm.

Introduction

In recent years, the combination of renewable energy sources has contributed to minimize atmospheric degradation and climate change by substituting fossil fuel energy. The major advantage of combining these energy sources in a hybrid system is that it enhances the reliability of the system [1]. Renewable energy (RE) based power systems offer off-grid energy supply for various applications, such as the electrification of rural and remote areas with problematic grid connections, the powering of telecommunication stations, and others. These systems usually combine photovoltaic (PV) systems, wind generators, and diesel generators [2].

Storage and transport are among the problems which need to be solved when using renewable energies, since they are diluted and diffuse forms of energy, and so their supply can be extremely intermittent and unreliable [3]. There is therefore a need for storage systems that can accumulate the energy produced in periods of low demand to be utilized when the demand is high, ensuring full utilization of the intermittent sources that are available. Hydrogen is an attractive energy carrier since it is one of the cleanest, lightest, and most efficient fuels. However, it is not found naturally and, like electricity, must be produced from primary energy sources. Unlike electricity however, after production it can be stored. For short-term applications, batteries, compressed air, flywheels, and capacitors appear to be the most feasible and attractive, but for long-term application the use of certain chemicals is preferred [4].

Batteries currently constitute the main solution to energy storage needs in a wide variety of autonomous applications, from vehicles and portable devices to isolated renewable energy systems, including many industrial uses mainly related to ensuring energy supply in case of mains failure (for example, UPS or telecommunications) [5].

Batteries are not appropriate for long-term storage because of their low energy density and self-discharge. The combination of a battery bank with long-term energy storage in the form of H2 can significantly improve the performance of stand-alone RE systems. In such an RE system, the electrolyzer generates H2 during times when excess solar and wind energy is available, and the fuel cell utilizes this H2 to produce electricity when there is insufficient solar and wind energy [6], [7], [8], [9], [10], [11], [12]. The battery bank smooths out the electrical power flow between the components and provides electricity for the daily operation of the control unit and auxiliary devices [13], [14].

In practice, two different immobile electrolyte battery technologies have commonly been used. One is the valve-regulated lead-acid (VRLA) battery with an AGM (absorptive glass mat) separator and starved electrolyte [15], [16], [17], [18]. The other is the VRLA battery with gelled electrolyte [19], [20]. Tang et al. [21] enumerate the advantages of gel VRLA batteries in comparison with conventional flooded or AGM batteries: (i) they have a long service life and high reliability under deep discharge cycles; (ii) there is no acid stratification and they can be installed in any orientation; (iii) there is no leakage of acid mist, charge stability is good, and operation is maintenance-free. The most commonly used gelled electrolyte consists of fumed silica, although colloidal silica gelled electrolytes (CSGE) are receiving increasing attention because of their good stability and low cost.

With gelled electrolyte, the corrosion rate of the positive grids is lower than with AGM technology, and the evolution of the hydrogen overpotential on the negative plate is also higher. For these reasons VRLA batteries have a considerably improved performance [20].

The higher cost of VRLA batteries as compared to flooded ones has restricted their use in installations such as automotive or PV systems, despite their excellent performance, which has been patent for decades, in deep cycling applications [22]. In hybrid systems with hydrogen support, a battery bank is used for short-term energy storage due to its high charging-discharging efficiency, and also because of its ability to deal with the effects caused by instantaneous load, electrolyzer transients, and wind energy peaks.

A complete analysis of the battery's charge and discharge requirements is required in order to size the battery bank in this kind of application. Two properties of the battery are usually related to the hybrid system's performance: state-of-charge (SOC) and open-circuit voltage (VOC) [23].

The present work proposes a method for determining the SOC of a gel VRLA battery installed in a test-bed hybrid wind-solar system with hydrogen storage support. The resulting value is used to control the test-bed system. Prior to this work, hydrogen generation and consumption devices were controlled using as control variable the DC bus voltage, i.e., the voltage across the battery terminals. However, this voltage is not representative of the energy in the battery because it depends on the current intensity being supplied or withdrawn, the ripple introduced by the electrolyzer and the fuel cell, variations in load demand, and the intrinsic intermittent nature of RES. As indicated by Agbossou [24], the DC bus voltage alone cannot be considered an appropriate variable with which to control the operation of an RE plant.

The contribution of this work to estimating the SOC of a gel battery is the adaptation and validation of an Ah counting method based on current integration using the actual values of the variables involved. The battery is the DC bus of a hybrid wind-solar installation with hydrogen storage. The estimated SOC value will be used as the system's control parameter. Unlike other work on hybrid power systems which use a computer to estimate the battery's SOC [25], [26], [27], in our case the calculation procedure is implemented in the PLC that controls and monitors the system. This procedure for estimating the battery's SOC is particularly innovative, and endows the system with robustness, reliability, and dependability. The paper is organized as follows. Section 2 describes the hybrid system, and Sec. 3 defines the SOC level of a battery. Different methods for estimating the SOC are discussed in Sec. 4, followed by the presentation of the proposed procedure. Section 5 describes the experimental hardware used and the tests carried out, and presents the results of these tests with the SOC-based control algorithm and their analysis. Finally, Sec. 6 presents the conclusions and the lines of future work.

Section snippets

Hybrid system description

A wind-solar test-bed with hydrogen support has been developed and installed in the Industrial Engineering School of the University of Extremadura in Badajoz. It is a laboratory scale system for testing the integration and control of a stand-alone hybrid installation. Its components are two PV modules, a wind-turbine generator, a lead-acid gel battery, an electrolyzer, a fuel cell, a metal-hydride system for hydrogen storage, and a supervisory control and data acquisition system. This system is

The state-of-charge (SOC) level of an accumulator

The SOC of an accumulator is the fraction of the accumulator's current capacity at any given instant relative to its nominal capacity [2]:SOC=CCnomwhere C is the (available) current capacity of the accumulator and Cnom its nominal capacity.

Damages to the battery's internal structure due to over-charging and over-discharging and unforeseen system interruptions can be avoided when SOC value is available; consequently SOC estimation is one of the most important issues in battery applications [25].

Methods for determining the state-of charge

Given the importance of knowing the SOC of a battery, the question arises as to how to measure it. In recent years, there have been many studies aimed at improving SOC determination [25], [57], [58], [59], [60], [61]. Piller et al. [62] present a wide variety of SOC determination methods – chemistry-dependent techniques, open-circuit voltage (VOC) measurements, electrochemical modeling, impedance spectroscopy, and circuit models. These methods usually rely on system-specific models which differ

Measurement and data acquisition system

To perform the trials, we used devices for the measurement and acquisition of data which allow the variables involved to be monitored, and equipment for charging and discharging the battery (Fig. 4).

The test-bed monitoring and control system includes the data measurement and recording devices needed for the calculation of the SOC estimate. The PLC has electronic modules, Siemens SM331 and SM334 model, for connecting analogue sensors with voltage and current outputs. The variables monitored

Conclusions and future work

An enhanced SOC estimation method based on coulomb counting has been implemented for gelled VRLA batteries. The accuracy of the method was verified in various experiments involving a number of charging and discharging cycles under real operating conditions. The method was applied to a battery installed in a test-bed wind-solar system with hydrogen storage. To this end, we implemented a control algorithm by means of a programmable controller that governs the installation's operation using the

Acknowledgements

The authors are grateful to the Ministerio de Educación y Ciencia of Spain and the Gobierno de Extremadura for their financial support through the Projects ENE2007/66668/ALT, PRI07A088, and PDT07A047, the grant PRE09048 and the European Social Fund, ESF.

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