Doubly excited states play important roles in the low-energy region of the optical spectra of polyenes and their investigation has been subject of theoretical and experimental studies for more than 30 years now and still is in the focus of ongoing research. In this work, we address the question why doubly excited states play a role in the low-energy region of the optical spectrum of molecular systems at all, since from a naive point of view one would expect their excitation energy approximately twice as large as the one of the corresponding single excitation. Furthermore, we show that extended-ADC(2) is well suited for the balanced calculation of the low-lying excited 21Ag-, and states of long all-trans polyenes, which are known to possess substantial double excitation character. A careful re-investigation of the performance of TDDFT calculations for these states reveals that the previously reported good performance for the state relies heavily on fortuitous cancellation of errors. Finally, the title question is answered such that for short polyenes the lowest excited and states can clearly be classified as doubly excited, whereas the ground state is essentially represented by the (ground-state) HF determinant. For longer polyenes, in addition to increasing double excitation contributions in the and states, the ground state itself aquires substantial double excitation character (45% in C₂₂H₂₄), so that the transition from the ground state to these excited states should not be addressed as the excitation of two electrons relative to the ground state.