Copyright © 2007 Elsevier B.V. All rights reserved.
Plasma analysis for the plasma immersion ion implantation processing by a PIC-MCC simulation
Available online 22 February 2007.
Abstract
In order to analyze the plasma behavior during PIII processing, a computer simulation has been carried out using the simulation software “PEGASUS”. The software uses a Particle-in-Cell (PIC) method for the movement of charged particles in the electromagnetic field and a Monte Carlo method for collisions of ions, electrons, and neutrals in the plasma and also a Monte Carlo method to analyze the background gas behavior for a low density gas system. This approach is based on the weighting collision simulation scheme allowing for disparate number densities of different species. The spatial distributions of potential and densities of ions, electrons and radicals in the coating system were calculated together with the flux of ions and electrons on the surface of the object. The gas pressure was 0.01 to 50 Pa and a negative and/or a positive pulse voltage (Vmax=0.1 to 20 kV) was applied to the object. The calculation is fully self-consistent. A two-dimensional Cartesian and a cylindrical coordinate system were used. The effects of gas pressure, applied voltage, and secondary electron emission coefficient by ion impact (γ) on the sheath thickness, the spatial distribution of densities of electron, ion, and neutral atoms, the ion flux and its spatial distribution, etc. were studied for PIII processing of a trench shaped object, inner wall of a pipe and a PET bottle.
Keywords: PIC-MCC simulation; PIII; Plasma Immersed Ion Implantation; PIC-MCC coupling simulation






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2–3 eV) atomic oxygen (FAO) beam have been used as aggressive environments for testing the implanted polymers. The modified materials successfully survived these test environments, including FAO, which is the main danger for carbon-based materials in space, in low Earth orbit. The retained doses of implanted and recoil implanted elements were controlled by RBS. The content, structure and morphology of the modified protective surface layers were examined by XPS and scanning electron microscopy (SEM). It was shown that protective oxide(s)-based surface structures were formed. Implantation and conversion conditions were found for which the appearance and important thermo-optical properties of treated polymer films, such as solar absorptance and thermal emittance, were practically unchanged.




Discharge starts outside of the pipe under low pressure and high voltage.
Plasma is not generated.
