doi:10.1016/j.cossms.2004.08.002
Copyright © 2004 Elsevier Ltd All rights reserved.
Manipulation of nanoparticles in supersonic beams for the production of nanostructured materials
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P. Piseria, c, H. Vahedi Tafreshib and P. Milania, c,
, 
aINFM-Dipartimento di Fisica, Universita’ di Milano, Via Celoria 16, I-20133 Milano, Italy
bNCRC, North Carolina State University, 2401 Research Dr., Raleigh, NC 27695-8301, USA
cCentro Interdisciplinare Materiali e Interfacce Nanostrutturati, Universita’ di Milano, Via Celoria 16, 20133 Milano, Italy
Available online 25 September 2004.
Abstract
Production and manipulation of nanoparticles in the gas phase is of primary importance for the synthesis of nanostructured materials and for the development of industrial processes based on nanotechnology. In this review we will present and discuss the approach based on the use of aerodynamic focusing methods coupled to supersonic expansions to obtain high intensity cluster beams with a control on nanoparticle mass and spatial distribution. The implication of this techniques for the synthesis of nanostructured materials will be also presented.
Keywords: Nanoparticles; Supersonic beams; Aerodynamic focusing; Nanostructured materials
Fig. 1. A sketch of the aerodynamic separation of particles in a gas flow according to their inertia. For large particles St
1 i.e. their inertia largely exceeds the drag action of the gas flow. At a point where the flow-lines curvature is sufficiently high, the particle trajectories separate from the flow-lines and the particles are eventually deposited on the walls. Very small particles closely follow the flow-lines because their inertia being negligible compared to drag (St
1). Particles of some intermediate size have trajectories only slightly decoupled from the flow-lines and this can be exploited to concentrate particles at given positions in the flow-field.
Fig. 2. A schematic view of the aerodynamic focusing device introduced by Piseri et al. [34]. The 3D picture represents a sectioned focuser-cylindrical nozzle assembly. The aerosol moves from the left (large cylindrical section) to the right, passing through the holes on the periphery of the cylinder; then it flows radially towards the entrance of the narrow cylindrical section, where a sudden turn of the flow-lines produces the separation.
Fig. 3. A typical SCBD apparatus set-up. The apparatus consists of two differentially pumped vacuum vessels separated by a skimmer for the molecular beam. In first chamber a PMCS cluster source is shown [62], equipped with a focusing nozzle. A cluster–buffer gas mixture expands through the nozzle forming a free jet and accelerating the nanoparticles to hyper-thermal kinetic energy. The skimmer selects only the central portion of the expanding jet and allows to keep the deposition chamber at high vacuum conditions. The use of a focusing nozzle allows to concentrate the particles within the angle of acceptance of the skimmer aperture.
Fig. 4. A thickness map showing the intensity distribution of particles inside a cluster beam generated by a PMCS. The characteristic shape is due to depletion from particles of the flow lines close to the cylindrical cathode surface.

Corresponding author. Address: INFM-Dipartimento di Fisica, Universita’ di Milano, Via Celoria 16, I-20133 Milano, Italy. Tel.: +39 02 503 17350; fax: +39 02 503 17482