An effective method for the preparation of chlorolactones
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Acknowledgment
Financial support from the Zhejiang Province Natural Science Foundation of China (No. Y4080068) is greatly appreciated.
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Synthesis of difluoroalkyl-γ-butyrolactones from iododifluoromethyl ketones and 4-pentenoic acids
2015, Chinese Chemical LettersCitation Excerpt :The γ-butyrolactone is a characteristic skeletal core present in a large amount of natural products and biological compounds including pharmaceuticals and agrochemicals, such as ascorbic acid [1], sex pheromones [2], plant growth regulator karrikin [3] and anti-HIV nucleoside β-FddA [4]. Development of efficient methods for the synthesis of various functionalized lactones has attracted extensive attention [5–9]. As we know, the introduction of fluorine-containing groups into organic molecules could alter their properties and bioactivities [10–14].
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Copyright © 2010 Min Zhu. Published by Elsevier B.V. All rights reserved.