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Advances in Environmental Research
Volume 8, Issue 2, January 2004, Pages 151-171
Pollution Prevention in Process and Product Design
 
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doi:10.1016/S1093-0191(02)00130-2    
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Copyright © 2002 Elsevier Ltd. All rights reserved.

On zero water discharge solutions in the process industry*1

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Anantha P. R. Koppola, Miguel J. BagajewiczCorresponding Author Contact Information, E-mail The Corresponding Author, a, Brian J. Dericksb and Mariano J. Savelskib

a University of Oklahoma, Chemical Engineering and Materials Science, 100 E. Boyd Street, Norman, OK, USA

b Rowan University, Chemical Engineering, 201 Mullica Hill Road, Glassboro, NJ 08028, USA


Available online 6 March 2003.

Abstract

This paper presents a mathematical programming approach to analyze the feasibility of zero liquid discharge option in different industries. Mathematical programming methodologies are applied to four industrial cases—a tricresyl phosphate plant, an ethyl chloride plant, a paper mill and a refinery. In each case study various end of pipe and regeneration configurations using different treatment technologies are explored to determine the possibility of zero liquid discharge and its economical feasibility. The results show that the relationship between the cost of regeneration and the cost of freshwater as well as the discharge concentration of the treatment is the determining factor for the feasibility of zero liquid discharge.

Author Keywords: Water management; Zero liquid discharge

Article Outline

1. Introduction
2. Problem statement and mathematical models
2.1. Problem statement
2.2. Solution procedure
2.3. Procedure for single contaminant systems
2.4. Procedure for multiple contaminant systems
3. Case studies
3.1. Case #1: tricresyl phosphate plant
3.2. Case #2: ethyl chloride process
3.3. Case #3: paper mill
3.4. Case #4: petroleum refinery
4. Conclusion
Acknowledgements
Appendix A. Nomenclature
References























Corresponding Author Contact InformationCorresponding author. Tel.: +1-405-325-5458; fax: +1-405-325-5813

*1 Parts were first presented at Press 2001, Florence, Italy, May 2001. Other parts were presented at Empromer 2001, Santa Fe, Argentina.


Advances in Environmental Research
Volume 8, Issue 2, January 2004, Pages 151-171
Pollution Prevention in Process and Product Design
 
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