Abstract
Coarsening of M23C6 precipitates in an Fe-12. 4Cr-0. 13C ternary alloy has been investigated ageing at 780 “C up to 200 h. Evolution of M23C6 carbides at different ageing times was determined experimentally using transmission electron microscopy. Particle size distribution was obtained with different measuring methods. Simulations of coarsening of M23 C6 precipitates were carried out using computational thermodynamics and kinetics. Results showed low coarsening rates for M23C6 precipitates in the Fe-Cr-C ternary alloy. Interfacial energy of M23 C6/ferrite interface is between 0. 1 and 0. 3 J • m 2 for the coarsening of M23C6 ageing at 780 °C.
Similar content being viewed by others
References
Mohsen Asadi Asadabad. Shahram Kheirandish, Abdul Javad Novinrooz. Microstructual and Mechanical Behavior of 4. 5Cr-2W-0. 25V-0. IC Steel [J]. Materials Science and Engineering, 2010, 527A(6): 1612.
Anders Bjärbo, Mats Hättestrand. Complex Carbide Growth, Dissolution, and Coarsening in a Modified 12 pet Chromium Steel An Experimental and Theoretical Study [J]. Metallurgical and Materials Transactions, 2001, 32A: 19.
Shtansky D V, Nakai K, Ohmori Y. Decomposition of Martensite by Discontinuous-Like Precipitation Reaction in an Fe-1700. 5C Alloy [J]. Acta Materialia, 2000, 48: 969.
Chen Qing, Jeppsson Johan, Agren John. Analytical Treatment of Diffusion During Precipitate Growth in Multicomponent Systems [J]. Acta Materialia, 2008, 56(8): 1890.
Jayaram R, Klueh R L. Microstructural Characterization of 5 to 9 pet Cr-2 pet W-V-Ta Martensitic Steels [J]. Metallurgical and Materials Transactions, 1998, 29A: 1551.
Myeong Yong Wey, Taketo Sakuma, Taiji Nishizawa. Growth of Alloy Carbide Particles in Austenite [J]. Transactions of the Japan Institute of Metals, 1981, 22(10): 773.
Asa Gustafson, Mats Hättestrand. Coarsening of Precipitates in an Advanced Creep Resistant 9% Chromium Steel—Quantitative Microscopy and Simulations [J]. Materials Science and Engineering, 2002, 333A(1/2): 279.
HU Xin-bin, LI Lin, WU Xiao-chun, et al. Coarsening Behavior of M23C6 Carbides After Ageing or Thermal Fatigue in AISI H13 Steel With Niobium [J]. International Journal of Fatigue, 2006, 28: 175.
Prat O, Garcia J, Rojas D, et al. Investigations on Coarsening of MX and M23C6 Precipitates in 12%Cr Creep Resistant Steels Assisted by Computational Thermodynamics [J]. Materials Science and Engineering, 2010, 527A: 5976.
Cao W, Chen S-L, Zhang F, et al. PANDAT Software With PanEngine, PanOptimizer and PanPrecipitation for MultiComponent Phase Diagram Calculation and Materials Property Simulation [J]. Calphad, 2009, 33(2): 328.
Agren John. Computer Simulation of Diffusional Reactions in Complex Steels [J]. ISIJ International, 1992, 32(2): 291.
Qin Y, Götz G, Blum W, et al. Determination of Size Distribution of Precipitates in the Cast Martensitic Steel GX12CrMoWVNbN 10–1–1 by Direct and Indirect Method [J]. Journal of Alloys and Compounds, 2003, 352: 260.
Walton W H. Feret’s Statistical Diameter as a Measure of Particle Size [J]. Nature, 1948, 162(4113): 329.
Andersson J-O, Thomas Heiander, Lars Höglund, et al. Thermo-Calc and DICTRA, Computational Tools for Materials Science [J]. Calphad, 2002, 26(2): 273.
Borgenstam Annika, Höglund Lars, Agren John, et al, DICTRA, a Tool for Simulation of Diffusional Transformations in Alloys [J]. Journal of Phase Equilibria, 2000, 21(3): 269.
Author information
Authors and Affiliations
Corresponding author
Additional information
Foundation Item: Item Sponsored by National Natural Science Foundation of China (50971137, 50934011); National Basic Research Program of China (2010CB630802)
Rights and permissions
About this article
Cite this article
Zhu, Nq., Lu, L., He, Yl. et al. Coarsening of M23C6 Precipitates in an Fe-Cr-C Ternary Alloy. J. Iron Steel Res. Int. 19, 62–67 (2012). https://doi.org/10.1016/S1006-706X(13)60009-6
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1016/S1006-706X(13)60009-6