doi:10.1016/S0921-4526(00)00650-5
Copyright © 2001 Elsevier Science B.V. All rights reserved.
Specific heat of Ce3Bi4Pt3 at 60 T
M. Jaime
,
, a, R. Movshovicha, G. R. Stewartb, W. P. Beyermannc, M. Gomez Berissod and P. C. Canfielde
a Los Alamos National Laboratory, Los Alamos, NM 87545, USA
b University of Florida, Gainesville, FL 32611-8440, USA
c University of California, Riverside, CA 980-8577, USA
d Centro Atómico Bariloche, Bariloche, 8400 RN, Argentina
e Iowa State University, Ames, IA 50011, USA
Available online 9 March 2001.
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Abstract
Kondo insulator materials such as CeRhAs, CeRhSb, YbB12, Ce3Bi4Pt3, and SmB6, are 3d, 4f and 5f intermetallic compounds. At high temperatures they behave like metals but a gap Δ in the conduction band opens at the Fermi energy as the temperature is reduced. It has been proposed that the formation of the low-temperature gap is a consequence of the hybridization between the conduction band and the f-electron levels. If this is true, Kondo metal physics should be recovered when the gap is closed at high magnetic fields. We report here specific heat results of Ce3Bi4Pt3 in DC and pulsed magnetic fields up to 60 T. We see evidence for the reduction of the gap in 18 T and a rapid increase of the Sommerfeld coefficient
in 30T>H>40T. Numerical results and the analysis of the data with the Coqblin–Schrieffer model prove a field-induced Kondo insulator-to-Kondo metal crossover.
Author Keywords: Specific heat; Kondo insulators; Pulsed magnetic fields
Fig. 1. The crystal structure of Ce3Bi4Pt3 is cubic (bcc, Y3Sb4Au3 structure), each unit cell is composed of four formula units.
Fig. 2. Specific heat measured in zero field (•) and 18 T (
) in a superconducting magnet. Top-left inset: band diagram described in the text. Bottom-right inset: field dependent contribution to the heat capacity in 18 T, versus temperature.
Fig. 3. (A) Temperature of the sample, magnetic field and heater voltage as a function of time during a specific heat measurement at 40 T. (B) Four temperature traces, corresponding to four magnetic field pulses required to measure at 60 T the same amount of specific heat data obtained at 40 T (A).
Fig. 4. Specific heat divided by the temperature versus T2 for magnetic different fields obtained in the 60 TLP magnet.
Fig. 5. Specific heat divided by the temperature versus T2 in a Si single crystal. No change is observed in 60 T.
Fig. 6. Sommerfeld coefficient γH versus magnetic field.