Elsevier

Tribology Series

Volume 7, 1981, Pages 19-30
Tribology Series

Universal Binding Energy Relations in Metallic Adhesion

https://doi.org/10.1016/S0167-8922(08)70869-1Get rights and content

Abstract

Rose, Ferrante, and Smith (ref. 7) have discovered scaling relations which map the adhesive binding energy of Ferrante and Smith (ref. 6) onto a single universal binding energy curve. The energies in ref. 6 are calculated for all combinations of Al(111), Zn(0001), Mg(0001), and Na(110) in contact. The scaling involves normalizing the energy to the maximum binding energy and normalizing distances by a suitable combination of Thomas-Fermi screening lengths. A simple mathematical expression is found to accurately represent the universal curve, E* (a*) = – (1 + βa*) exp (−βa*) where E* is the normalized binding energy, a* is the normalized separation, and β is the fitting parameter. Rose et al. (ref. 7) have also found that the calculated cohesive energies of K, Ba, Cu, Mo, and Sm scale by similar simple relations suggesting the universal relation may be more general than for the simple free electron metals for which it was derived. In this paper we outline these results and discuss them in relation to topics of interest in adhesion, friction, and wear.

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Cited by (11)

  • Analysis of Ti-6Al-4V adhesion to AISI 52100 steel and TiN during unlubricated sliding contact

    2015, Tribology International
    Citation Excerpt :

    Adhesive wear is the fundamental cause of failure of most metal sliding contacts and therefore its effective prevention is essential to proper functioning of engineering [1]. Ferrante and Smith [2] first pointed out that the adhesion between metals took place when the distance between two surfaces is lower than 0.2 nm, which is proved to be a critical separation distance to avoid adhesive wear between metals. Bowden and Tabor [3] first noticed that the real contact area is at least one order magnitude smaller the nominal contact area due to the surface roughness.

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