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Tetrahedron Letters

Volume 42, Issue 2, 8 January 2001, Pages 187-189
Tetrahedron Letters

Samarium-mediated Barbier reaction of carbonyl compounds

https://doi.org/10.1016/S0040-4039(00)01961-4Get rights and content

Abstract

Samarium metal in the presence of catalytic amounts of iodine was found to be effective for the Barbier reaction of carbonyl compounds.

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Acknowledgements

This work was supported in part by a grant received from the Robert J. Kleberg Jr. and Helen C. Kleberg Foundation and an NIH Cancer Center Support Grant, 5-P30-CA16672-25, in particular the shared resources of the Pharmacology and Analytic Center Facility.

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