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Marine Geology
Volume 174, Issues 1-4, 15 March 2001, Pages 341-354
 
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doi:10.1016/S0025-3227(00)00159-6    How to Cite or Link Using DOI (Opens New Window)
Copyright © 2001 Elsevier Science B.V. All rights reserved.

The behavior of redox-sensitive metals across a laminated–massive–laminated transition in Saanich Inlet, British Columbia

A. D. RussellCorresponding Author Contact Information, E-mail The Corresponding Author, a and J. L. MorfordE-mail The Corresponding Author, b, 1

a Department of Geology, University of California, Davis, CA 95616, USA b School of Oceanography, University of Washington, Box 357940, Seattle, WA 98195-7940, USA

Received 1 March 1999;
accepted 10 October 1999
Available online 30 April 2001.

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Abstract

Holocene laminated sediments in Saanich Inlet, British Columbia, are interrupted by frequent, non-laminated, massive layers. These layers may be debris flows released by earthquakes or bioturbated sediments deposited during periods of relatively high bottom water oxygen concentration and/or low surface productivity, or both. We determined the organic carbon content and the concentration of a suite of redox-sensitive metals in bulk sediments at approximately 1-cm resolution across a laminated–massive–laminated interval (ODP leg 169S Site 1033, Hole B, 4H4 54–74 cm), to determine the redox conditions under which the massive layer was deposited. Our results indicate that this massive interval was deposited under anoxic bottom waters. Manganese/Al ratios are consistently low throughout the massive section, while Mo/Al, Cd/Al, Re/Al, and U/Al ratios are enriched relative to their metal/Al ratios in detrital material (represented by Cowichan River suspended sediments). The concentration of organic carbon in the lower portion of the massive layer is higher than in the upper portion, which has a concentration similar to that in the overlying and underlying laminated sediments. Well-defined peaks in Mo/Al, Cd/Al, and Re/Al and a broad peak in U/Al occur in the lower portion of the massive layer. The positions of the Cd/Al, Re/Al, and Mo/Al peaks, as well as the increase in organic carbon content with depth in the massive layer, are best explained by a process of diagenetic redistribution of metals that occurred after the massive layer was emplaced.

Author Keywords: Marine sediments; Trace metals; Geochemistry; Fjords

Article Outline

1. Introduction
2. Background
2.1. Manganese (Mn)
2.2. Molybdenum (Mo), Uranium (U), Rhenium (Re) and Vanadium (V)
2.3. Cadmium (Cd)
2.4. Diagenesis
2.5. Summary
3. Sampling and analytical methods
3.1. Sample description and collection
3.2. Sediment digestion
3.3. Metal analyses
3.4. Standards, duplicates and blanks
3.5. Organic carbon
4. Results and discussion
4.1. Comparison of massive and laminated sediment composition
4.2. Me/Al variability down the section: evidence for diagenesis
5. Conclusions
Acknowledgements
References



Marine Geology
Volume 174, Issues 1-4, 15 March 2001, Pages 341-354
 
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