The homogeneous gas phase oxidation of methane and the retarding effect of basic/inert surfaces
References (11)
- et al.
The Fifth Symposium on Combustion, N.Y.
(1955)et al.The Fifth Symposium on Combustion, N.Y.
(1955) - et al.
Ind. Eng. Chem.
(1977) - et al.
Proc. Roy. Soc., A
(1936) Combustion Science and Technology
(1986)
Cited by (52)
Comparison of mechanisms for the direct, gas phase, partial oxidation of methane to methanol
2021, Chemical Engineering ScienceCitation Excerpt :From this appendix over 100 data points were randomly selected, and the simulations were run to compare the conversion of methane and methanol selectivity predicted to these experimental points. The data used are from the following authors: NNewitt and Haffnerewitt and Haffner (1932); NNewitt and Schmidtewitt and Schmidt (1937); Boomer and Thomas (1937); Furman and Shestakova (1956); Oberdorfer and Winch (1961); Lott and Sliepcevich (1967); Tripathy (1975); LLuckett and Mileuckett and Mile (1976); BBrockhaus and Frankerockhaus and Franke (1981); Gesser et al. (1985); Burch et al. (1989); Onsager et al. (1989); Hunter et al. (1990); Rytz and Baiker (1991); Walsh et al. (1992); Yarlagadda et al. (1988). A separate selection of data (over 100 data points) was compiled from literature using only results from quartz reactors.
Study of the oxidative methane coupling over SrO-La<inf>2</inf>O<inf>3</inf> catalyst: Experiment and kinetic modeling
2021, Fuel Processing TechnologyDirect Methane to Methanol: Reaction Products and Effect of Gas Composition
2018, Methanol: Science and EngineeringDirect Methane to Methanol: Historical and Kinetics Aspects
2018, Methanol: Science and EngineeringThe interplay of catalytic and gas-phase stages at oxidative conversion of methane: A review
2017, Journal of Molecular Catalysis A: ChemicalCitation Excerpt :As ethylene accumulates, the reaction transforms into the gas-phase process of oxidation of methane and ethylene to CO and CH3OH. The influence of a number of heterogeneous catalysts (SrCO3, BaCO3, and 7% Li/MgO), active in the oxidative condensation of methane at low pressures, on the process at 500–750 °C was studied in [49]. However, at pressures above 3 atm, no contribution from heterogeneous activation was detected, in agreement with the estimates of the pressure range of transition to chain-branched oxidation obtained in [50].
An EPR and NMR study on Mo/HZSM-5 catalysts for the aromatization of methane: Investigation of the location of the pentavalent molybdenum
2013, Journal of Molecular Catalysis A: ChemicalCitation Excerpt :Several routes have been explored over the previous two decades. In addition to methane conversion into syn gas which is of real industrial significance, more ambitious routes such as direct conversion into oxygenates [1–4], methanation of olefins, although this is a barely effective route to methane insertion in view of the unfavorable thermodynamics at the temperatures needed to activate methane and to reach measurable reaction rates [5], oxidative coupling of methane [6–9] and conversion of methane into benzene and hydrogen [10–29] were explored. The latest developments were concerned with the latter reaction carried out in the presence of various transition metal oxide-loaded inorganic carriers.