Original contributionAre dioxetanes chemiluminescent intermediates in lipoperoxidation?
References (46)
- et al.
Iron toxicity and oxygen radicals
Ballière's Clin. Haematol.
(1989) - et al.
Visible chemiluminescence from rat brain homogenates undergoing autoxidation. II. Kinetics of the luminescence decay
Free Rad. Biol. Med.
(1988) - et al.
Ascorbate- and hemoglogin-dependent brain chemiluminescence
Free Rad. Biol. Med.
(1990) - et al.
Reactions of the triplet state of ketones woth molecular oxygen
Comm. Eur. Communities, [REP] EUR Phys.-Chem. Behav. Atmos. Pollut.
(1982) - et al.
Liposomes as membrane model for study of lipid peroxidation
Free Rad. Biol. Med.
(1988) - et al.
Lipid peoxidation and lipid peroxide detected by chemiluminescence
Free Rad. Biol. Med.
(1987) Determination of chemiexcitation yields in the thermal generation of electronic excitation from 1,2-dioxetanes
- et al.
Chemically initiated electron exchange luminescence. A new chemiluminescent reaction path for organic peroxides
J. Am. Chem. Soc.
(1977) - et al.
Determination of activation parameters and the thermal stability of 1,2-dioxetanes
- et al.
Singlet excited states from dioxetane decomposition
J. Chem. Soc. Chem. Commun.
(1977)
Ultraweak chemiluminescence: A sensitive assay for oxidative radical reactions
Deuterio-isotope effects in the autoxidation of aralkyl hydrocarbons. Mechanism of the interaction of peroxy radicals
J. Am. Chem. Soc.
Energy transfer from chemiluminescent species in polymers
Nature
Biochemistry of oxygen toxicity
Ann. Rev. Biochem.
The singlet oxygen “ene” reaction
Dioxyge NIR FT0-emission () and Raman spectra of 1,4-dimethylnaphthalene endoperoxide, a source of singlet molecular oxygen
Appl. Spectro.
Formation of 1,4-endoperoxides from the dye-sensitized photo-oxygenation of alkylnaphthalenes
J. Chem. Soc. Chem. Commun.
Preparation and thermolysis of some 1,2-dioxetanes
Can. J. Chem.
Effects of emthylation on the thermal stability and chemiluminescence properties of 1,2-dioxetanes
J. Am. Chem. Soc.
Thermolysis of dioxetanes: Activation parameters for cis-/trans-3,4-dialkyl-1,2-dioxetanes
J. Org. Chem.
Tetraethyldioxetane and 3,4,-dimethyl-3,4-di-n-butyl-1,2-dioxetane. High ration of triplet to singlet excited products from the thermolysis of both dioxetanes
J. Am. Chem. Soc.
“Solvent effects” on the chemiluminescent decomposition of tetramethyl-1,2-dioxetane. Competitive dark pathways
J. Am. Chem. Soc.
The chemiluminescence from cis-diethoxy-1,2-dioxetane. An unexpected effect of oxygen
J. Am. Chem. Soc.
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Mining reactive triplet carbonyls in biological systems
2023, Journal of Photochemistry and Photobiology B: BiologyOxidative degradation of surfactants: mechanisms
2023, Surfactants in Biopharmaceutical DevelopmentRole of reactive oxygen species in ultra-weak photon emission in biological systems
2014, Journal of Photochemistry and Photobiology B: BiologyCitation Excerpt :Apart to 3(RO)*, the decomposition of ROOOOR directly to 1O2 occurs via Russell mechanisms [60,65]. The photon emission of 3(RO)* is at near UVA and blue–green regions of the spectrum (350–550 nm) [64,66]. The photon emission of singlet and triplet excited pigments is in the green–red (550–750 nm) and red-near IR (750–1000 nm) regions of the spectrum, respectively [66,67], whereas the dimol and the monomol photon emissions of 1O2 are in the red (634 and 703 nm) and near IR (1270 nm) regions of the spectrum, respectively [68].
Electronically Excited State Formation
2013, In Vitro Toxicity IndicatorsSmall reactive carbonyl compounds as tissue lipid oxidation products; And the mechanisms of their formation thereby
2012, Chemistry and Physics of LipidsCitation Excerpt :The immediate product of such addition of oxygen across a double bond is a dioxetane, whose formation normally requires singlet oxygen. However, Di Mascio et al. (1992) found that the addition of singlet oxygen to lipids mainly produces hydroperoxides, with negligible dioxetane formation. Schieberle and Grosch (1981) proposed an alternative mechanism, in which a peroxyl radical adds to 2,4-decadienal at the α-carbon, resulting in the formation of a dimeric peroxy-peroxyl radical.
In situ and real time muscle chemiluminescence determines singlet oxygen involvement in oxidative damage during endotoxemia
2010, Chemico-Biological InteractionsCitation Excerpt :For this reason, we used D2O that specifically enhances 1O2 signal by extending its lifetime [26] and biacetyl that specifically enhances excited carbonyls signal by an energy transfer mechanism [27]. The probes were found effective in enhancing 1O2 dimol emission an carbonyl emission respectively, indicating the occurrence of the Russel reaction in vivo, as it was also recognized for in vitro lipid peroxidation by Di Mascio et al. [28]. The obtained results strengthen the conclusion that 1O2 is the main chemical species involved in the oxidative stress mechanism with a secondary participation of CO*.