The existence of two H-bonds of different strengths in ice and the possible implications☆
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Raman spectroscopic and theoretical study of liquid and solid water within the spectral region 1600–2300 cm<sup>−1</sup>
2018, Spectrochimica Acta - Part A: Molecular and Biomolecular SpectroscopyCitation Excerpt :The authors of [35] note that molecules with one broken bond can rotate as well. A study from the early 1990s [36], where different modifications of ice were investigated by inelastic neutron scattering, has shown the possibility of two types of hydrogen bonding — strong and weak, which are determined by the positions of the two nearest molecules. There are four such configurations in ice Ih, with two related to strong and two to weak hydrogen bonds.
Water trapped in silica microspheres
2012, Microporous and Mesoporous MaterialsCitation Excerpt :At 250 K the librational edge of ice is already shifted to 550 cm−1 but the band is still very broad. At 10 K the band shows sharper features and the spectrum confirms the formation of hexagonal ice [16]. The water in the silica microspheres shows a very complicated pattern of librational modes at 300 and 250 K. Although at 250 K we are well below the freezing point of water, the water in the cavities is still liquid: The spectrum at 250 K looks identical to the one at 300 K.
Compton scattering evidence for covalency of the hydrogen bond in ice
2000, Journal of Physics and Chemistry of SolidsChapter 12 Interpretation of inelastic neutron scattering spectra for water ice by lattice and molecular dynamic simulations
1999, Theoretical and Computational ChemistryInelastic neutron scattering study of high density amorphous water ice
1997, Planetary and Space ScienceSolution thermodynamics and its application to aqueous solutions: A differential approach
2017, Solution Thermodynamics and Its Application to Aqueous Solutions: A Differential Approach
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Presented at the Xth Workshop “Horizons in Hydrogen Bond Research”, Autrans, France, 12–17 September 1993.