Copyright © 1984 Published by Elsevier Inc.
Note
Influence of adsorbed vapors on the photoacoustic spectra of liquids*1
Received 26 September 1983.
Available online 12 July 2004.
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Q−3.37 due to the scattering of a surface fractal structure of dimension DS = 2.63. This fractal structure is the internal surface between regions of highly densified amorphous material and agglomerates of free volumes, forming a system of interconnected channels across the whole sample. Filling the pore system with a contrast liquid leads to a strong change of the scattering intensity, while the exponent α = 3.37 of the low Q power law remained unchanged. The results verify the fractal nature of the internal surface, as well as the microstructural concept of dense nanometer-sized amorphous grains embedded in a less dense “matrix” formed by grain boundaries and free volumes. Using C6D12, CS2 and D20, a molecule-size effect of different access to smaller pores was observed.


