The effect of polymer—filler interaction energy on the T′g of filled polymers
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2019, Materials Science and Engineering CCitation Excerpt :Such disparate results can be explained by taking into account the nature of the interfacial interactions between the polymer and particles [44,45]. In a study by Yim et al. [46], the increase in Tg of different composites compared to the unfilled polymer was correlated with the polymer—filler interaction energies measured by the heats of adsorption of the model compounds of the polymers on the filler surfaces. Torres et al. found that while lower TiO2 content in PLGA-TiO2 composite foams shifts the Tg toward higher temperatures, higher contents causes reduction in Tg [47].
Concepts and conflicts in nanoparticles reinforcement to polymers beyond hydrodynamics
2016, Progress in Materials ScienceCitation Excerpt :Rather than modifying the hydrodynamic equations, the reinforcement exhibits some simple scaling behaviors and is related to the filler connectivity highly depending on nanoparticle geometry [233]. The CCA [56,293–297], “jamming” [67,68], percolation mechanisms [69–78] are frequently quoted for discussing the network reinforcement effect of NPFPs [79–85]. Nanoparticles interact through hydrodynamic and non-hydrodynamic forces.
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