Organometallic intramolecular-coordination compounds containing a π-allyl donor ligand
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Cited by (36)
Applications of cyclometalation reaction five-membered ring products
2018, Journal of Organometallic ChemistryCitation Excerpt :There are two representative cyclometalation reactions [1–62] in which the first cyclometalation reactions are that a central metal atom is coordinated by a hetero atom ligand such as N [31,37,42,48], P [34,42,48], As [38,42], O [30,39,42,47,48] and S [32,42], and the other cyclometalation reactions are that the central metal atom is coordinated by a group ligand such as π-olefin [32,42], cyclopentadienyl [35,42], diolefin [40] and π-allyl [41,42] group ligand.
Applications of six-membered ring products from cyclometalation reactions
2017, Journal of Organometallic ChemistryApplication of the five-membered ring products of cyclometalation reactions for hydrogen production
2017, Journal of Organometallic ChemistryCitation Excerpt :This assumption is supported by their different coordination modes and photophysical and electrochemical properties. These systems maintained their activity for more than 72 h under visible-light irradiation, and a total turnover number of up to 3040 was reached, based on tris-cyclometalated iridium compound 3.18 [32]. The photocatalyzed reactions of five photosensitizer iridium compounds bearing carboxyl ester or phosphonate groups 3.23–3.27: with K2PtCl4 as the catalyst and TEA as sacrificial electron donor in acetonitrile/water solution were carried out for hydrogen production.
Application of the five-membered ring blue light-emitting iridium products of cyclometalation reactions as OLEDs
2016, Coordination Chemistry ReviewsCitation Excerpt :For example, in four deep-blue electrophosphorescent metal 1-cyanophenyl-3-methylimizoline-2-ylidene-C,C2⿲ type N-heterocyclic carbene compounds for three types of metal (i.e., Ir, Rh and Pt), the iridium compounds exhibit the highest PLQY at room temperature compared with those with platinum and rhodium (Fig. 2.1) [82]. In many other metal compounds, platinum and gold compounds have relatively high PLQYs [65,67,7072,74,78,80,81,88,93,98,101,120]. These compounds include carbene compounds [67,68,72], tridentate or tetradentate metal compounds [65,71,74,80,81,98], and compounds with boron, thiophene and heterocyclic amine ligands [70,78,88,93,101,120], as shown in Figs. 2.22.4, and in Tables 2.12.3, respectively.
Application of five-membered ring products of cyclometalation reactions as sensing materials in sensing devices
2016, Journal of Organometallic ChemistryCitation Excerpt :When cyclometalation reactions are performed using metal compounds with substrates that contain heteroatoms with a strong donor ability, such as amines, phosphines, alcohols and sulfur compounds, the reactions show a high reactivity of the substrate to the metal compounds because compounds with these heteroatoms are usually used as catalysts. Therefore, many articles, reviews [1–55] and books [56–61] on this subject have been published since the 1960s, and cyclometalation reactions are considered representative reactions in organic synthesis. Commonly, cyclometalation reactions with conventional substrates that have a γ-carbon atom as the heteroatom proceed very easily via agostic interactions with CH activation, as shown in Eq. (1.1) [49].
Agostic bonds in cyclometalation
2011, Journal of Organometallic ChemistryCitation Excerpt :The cyclometalation reactions proceed very easily, and an enormous amount of cyclic compounds have been synthesized not only with transition metal compounds, but also with main group metal compounds. The number of articles on the cyclometalation reactions has increased dramatically since 1970s, and also reviews [1–22] and a book [23] have been published. The number of the metal element in the organometallic intramolecular-coordination compounds, which are synthesized by these cyclometalation reactions was 57 in 2004 [21], 68 in 2007 [22], and 69 in 2010 [24].