Resonance Raman spectra of benzene adsorbed on Cu2+-montmorillonite. Formation of poly(p-phenylene) cations in the interlayer of the clay mineral

doi:10.1016/0009-2614(83)80549-1

Chemical Physics Letters

Volume 99, Issue 2, 29 July 1983, Pages 153-156

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Abstract

Resonance Raman spectra of benzene adsorbed on Cu²⁺- and Ru₃₊-montmorillonites have demonstrated the formation of poly(p-phenylene) cations in the interlayer of the clay mineral. The interlayer cation is reduced in a humid atmosphere to yield poly(p-phenylene). Biphenyl or p-terphenyl gives consistently the same product.

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Resonance Raman spectra of benzene adsorbed on Cu2+-montmorillonite. Formation of poly(p-phenylene) cations in the interlayer of the clay mineral

Abstract

J. Chem. Phys.

Nature

J. Phys. Chem.

J. Phys. Chem

J. Phys. Chem.

Resonance Raman spectra of benzene adsorbed on Cu²⁺-montmorillonite. Formation of poly(p-phenylene) cations in the interlayer of the clay mineral