Comparison of palm oil, Jatropha curcas and Calophyllum inophyllum for biodiesel: A review

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Abstract

The world today is faced with serious global warming and environmental pollution. Besides, fossil fuel will become rare and faces serious shortage in the near future. This has triggered the awareness to find alternative energy as their sustainable energy sources. Biodiesel as a cleaner renewable fuel has been considered as the best substitution for diesel fuel due to it being used in any compression ignition engine without any modification. The main advantages of using biodiesel are its renewability and better quality of exhaust gas emissions. This paper reviews the production, performance and emission of palm oil, Jatropha curcas and Calophyllum inophyllum biodiesel. Palm oil is one of the most efficient oil bearing crops in terms of oil yield, land utilization, efficiency and productivity. However, competition between edible oil sources as food with fuel makes edible oil not an ideal feedstock for biodiesel production. Therefore, attention is shifted to non-edible oil like Jatropha curcas and Calophyllum inophyllum. Calophyllum inophyllum oil can be transesterified and being considered as a potential biodiesel fuel. Compared to Palm oil and Jatropha biodiesel industry, biodiesel from Calophyllum inophyllum is still in a nascent state. Therefore, long term endurance research and tribological studies need to be carried out before Calophyllum inophyllum oil base biodiesel can become an alternative fuel in future.

Introduction

The increasing industrialization, modernization and development have led to high demand of petroleum worldwide. Global energy consumption in 2008 was growing from 6630 million tonnes of oil equivalent (Mtoe) in 1980 to almost double of the energy consumption which had reached 11,295 Mtoe in 2008 [1]. However, the world reserve for fossil fuel such as petroleum has been depleting and causing the price to hit new highest record of US$ 136 per barrel in July 2008 [2]. In Malaysia, the final energy consumption has risen at an annual growth rate of 7.2% from 1990 to 2008 and reached 44.9 Mtoe in 2008 [3]. The crucial challenge faced by power sector in Malaysia currently is the issue of sustainability. Besides, the world today is faced with a serious global warming and environmental pollution. The major sources of greenhouse gas (GHG) emissions are gasoline and diesel fuel from transportation sector. The world is confronted with the twin crises of fossil fuel depletion and environmental degradation [4]. Thus, there is an urgent need to find an alternative renewable energy resource that is renewable, clean, reliable and yet economically feasible. Biodiesel, a cleaner renewable fuel has been considered as the best candidate for diesel fuel substitution due to it can be used in any compression ignition engine without any modification on the engine.

Biodiesel is gradually gaining acceptance in the market as an environmentally friendly fuel and the demand is expected to increase sharply as an alternative renewable energy source in the near future. Biodiesel fuel is mono alkyl ester derived from vegetable or animal and it can be blended with diesel fuel which has characteristics similar to diesel fuel and has lower exhaust emissions [5], [6], [7]. On the other hand, the main drawbacks of vegetable oil have to overcome due to the high viscosity and low volatility which will cause a poor combustion in diesel engines. Transesterification is the process successfully employed to reduce the viscosity of biodiesel and improve the other characteristics [8]. Currently, more than 95% of the world biodiesel is produced from edible oil which is easily available on a large scale from the agricultural industry. However, competition of edible oil sources as food with fuel makes edible oil not an ideal feedstock for biodiesel production [9], [10]. Therefore, much effort is required to focus in this area to produce biodiesel from non-edible seeds like Jatropha curcas, Pongamia pinnata, Calophyllum inophyllum, etc. to become feasible feedstock for biodiesel.

Biodiesel seems to be a realistic alternative renewable fuel in the near future and this review is focus on the possibilities of using palm oil, Jatropha curcas, Calophyllum inophyllum and biodiesel in diesel engine. Besides, the fuel characteristics, processes available, production, performance and emission analysis of biodiesel are discussed by making a comparison on these three different types of biodiesel fuel.

Section snippets

Biodiesel

The concept of using biofuel in diesel engines is not a radically new idea, an inventor named Rudolph Diesel demonstrated his first developed compression ignition (CI) diesel engine using peanut oil as a fuel at the World Exhibition at Paris in 1900 [11], [12]. However due to abundant supply of diesel and vegetable oil fuel were more expensive than diesel, research and development activities on vegetable oil were not seriously pursued [13]. There is a renewed interest in vegetable oil in this

Palm oil

Oil palm is botanical classification as Elaeis guineensis and native to the West Africa where it was growing wild and later developed into an agricultural crop [52]. Elaeis guineensis Jacq is the most productive oil palm variety which can produce 10–35 tonnes/ha of fresh fruit bunch (FFB) oil palm annually [53]. The oil palm is a tropical perennial plant and grows well in lowland with humid places and therefore it can be cultivated easily in Malaysia [54]. The tree which is unbranched and

Jatropha curcas

Jatropha curcas is a large shrub that belongs to the genus Euphorbiaceae native in tropical American but widely distributed in tropical and subtropical regions throughout Africa, India and South East Asia [63]. It is a tropical plant that can be grown in low to high rainfall areas either in the farms as a commercial crop or on the boundaries of fields as a hedge [64]. It requires very little irrigation and grows in all types of soils. Jatropha is well adapted to semi-arid conditions, although

Calophyllum inophyllum

Calophyllum inophyllum, commonly known as Penaga Laut in Malaysia, is an non-edible oilseed ornamental evergreen tree belonging to the Clusiaceae family as shown in Fig. 7 [70], [71]. The scientific name of “Calophyllum” comes from the Greek word for “beautiful leaf”. It grows along coastal areas and adjacent lowland forests, although it occasionally occurs inland at higher elevations. It is native of eastern Africa, southern coastal India, Southeast Asia, Australia and the South Pacific.

Production of biodiesel

Researchers have developed many different methods for biodiesel production from different feedstocks. A review of these methods from palm oil, Jatropha curcas and Calophyllum inophyllum have discussed here.

Performance of biodiesel

The findings and outputs for performance of biodiesel fuel in diesel engine are reviewed. The performance parameter such as brake thermal efficiency, specific fuel consumption and power output for palm oil, Jatropha curcas and Calophyllum inophyllum are discussed below.

Emissions of biodiesel

Biodiesel mainly emits carbon monoxide, carbon dioxide, nitrogen oxides, sulphur oxides and smoke. The ignition timing, fuel contents and fuel viscosity will affect emission exhaust from engine. Apart from using additives fuel properties by preheating or oxidizing, many aftertreatment devices such as particulate matter filter, exhaust gas recirculation (EGR) are used. A brief review of the most prominent engine emissions from biodiesel is discussed in this section.

Conclusions

Biodiesel fuel is gaining more interest as an attractive alternative fuel due to the environmental pollution and diminishing supply of fossil fuel. Biodiesel has similar combustion characteristics as diesel and biodiesel blend can reduce hydrocarbons, smoke opacity, particulate matters, carbon dioxide and carbon monoxide emissions but NOx emissions have slightly increased. However, exhaust emissions of NOx can be controlled by adopting certain strategies such as changing the composition of

Acknowledgements

The author would like to express his acknowledgement to University of Malaya, Kuala Lumpur, Malaysia for the financial support under PPP research fund with Grant No: PS092-2009B and the Fellowship Scheme University Malaya.

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