Effect of high temperature and cooling regimes on the compressive strength and pore properties of high performance concrete

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Abstract

This paper describes the behavior of high performance concrete (HPC), compared with normal strength concrete (NSC), after subject to different high temperatures (800 and 1100°C) and cooling regimes (gradual and rapid cooling). Deterioration of compressive strength of the concrete was measured. The results obtained showed that the strength of both the HPC and NSC reduced sharply after their exposure to high temperatures. Thermal shock due to rapid cooling caused a bit more deterioration in strength than in the case of gradual cooling without thermal shock. However, thermal shock did not significantly increase the spalling of HPC. Mercury intrusion porosimetry (MIP) tests were carried out to measure changes in the pore size distribution in the concrete. Test results showed that the pore volume in the HPC increased much more than that in the NSC. A significant change in the cumulative pore volume was observed and the difference in cumulative pore volume between the two cooling regimes was less after subject to the peak temperature of 1100°C when compared with that of 800°C peak temperature.

Introduction

Concrete has been the leading construction material for nearly a century. High performance concrete (HPC) with high strength or high durability is gradually replacing the normal strength concrete, especially in structures exposed to severe environment. The advantages of HPC result from the improvement of internal structure of the material as compared with that of the normal concrete [1]. The dense microstructure of HPC ensures a high strength and a very low permeability. The low permeability is probably essential to obtain good durability in severe exposure conditions where there are aggressive agents such as chloride, sulfate, etc. However, the dense microstructure of HPC seems to be a disadvantage in the situation where the HPC is exposed to fire. Recent fire test results show that there is a great difference between the properties of HPC and normal concrete after being subjected to high temperature [2], [3], [4]. It was observed that HPC, especially high strength concrete (HSC) is susceptible to spalling, or even explosive spalling when subject to rapid temperature rise such as in the case of a fire [5], [6]. Experimental studies have also shown that spalling of HPC is influenced by many complicated factors, such as rate of temperature elevation, mineral constituents of aggregates, thermally induced mechanical stress, density of concrete, moisture content, etc. Although the failure mechanisms of HPC spalling have not been sufficiently understood, there are two mechanisms which are considered as the direct causes of spalling of HPC. One is the thermal stress induced by the rapid temperature rise or thermal shock [7]; the other is the water vapor, which may cause high pore vapor pressure [8]. The properties of this binder are, therefore, critical to the HPC. In this study, three grades of HPC and one NSC were tested for their compressive strength after exposure to different high temperatures and cooling regimes. The variation in the microstructures of both the HPC and NSC were tested by means of mercury intrusion porosimetry (MIP).

Section snippets

Materials and test methods

Ordinary Portland cement conforming to BS12:1991, crushed granite with a maximum size of 20 and 10 mm, superplasticizer based on naphthalene sulfonates complying with BS5075 part3:1985, silica fume, pulverized fly ash (PFA) meeting the requirements of BS3892 part1:1982, as well as steel and polypropylene fibers were adopted in this study. The chemical compositions and physical properties of cement, silica fume and fly ash are given in Table 1.

The length and aspect ratio are 25 mm and 60,

Test results and discussion

As shown in Fig. 1, compressive strength of the HPC decreased more sharply than that of the NSC. Control sample referred to the standard cured specimen that was tested at 90 days and not subjected to high temperatures. When temperature was elevated to 800°C, the residual strength percentage of the HPC was 26–34% for the gradual cooling and 22–28% for the rapid cooling. When the peak temperature was 1100°C (Fig. 2), the residual strength percentage of HPC was 8–12% for gradual cooling and 8–10%

Conclusions

  • 1.

    When subjected to the peak temperature of 800°C, the residual compressive strength of HPC dropped to approximately 26–34% of the original after the gradual cooling process and 22–28% after the rapid cooling; when subjected to 1100°C, the residual strength of HPC reduced to approximately 8–12% for gradual cooling and 8–10% for rapid cooling.

  • 2.

    Steel fiber could reduce the deterioration of concrete to an extent. Polypropylene fiber used to prevent spalling of HPC did not lead to a marked degradation

Acknowledgements

The authors would like to thank the Hong Kong Polytechnic University for supporting the research work. This research was also part of a project financed by the Chinese National Nature Science Foundation. The support from the State Key Laboratory of Mineral Deposit Research, Nanjing University is also acknowledged.

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