Elsevier

Tetrahedron

Volume 53, Issue 52, 29 December 1997, Pages 17761-17768
Tetrahedron

Halogen atom transfer radical addition of α-polychloroesters to olefins promoted by Fe0 filings

https://doi.org/10.1016/S0040-4020(97)10241-1Get rights and content

Abstract

The Kharasch addition of methyl 2,2-dichlorocarboxylates or trichloro acetic acid derivatives to alkenes, affording the corresponding 1:1 adducts, is promoted by the iron filings/N,N-dimethylformamide system.

The Kharasch addition of methyl 2,2-dichlorocarboxylates or trichloro acetic acid derivatives to alkenes, affording the corresponding 1:1 adducts, is promoted by the iron filings/N,N-dimethylformamide system.

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