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Fabrication of nitrogen-doped porous carbon nanofibers for heavy metal ions removal

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Abstract

In this article, nitrogen (N) doped porous carbon nanofibers (N-PCNF) were prepared by carbonization of polymer-silica nanocomposite precursor, and its application for heavy metal ion removal was demonstrated. Carbon–silica composite nanofibers were obtained by carbonization of electrospun polyacrylonitrile (PAN)-silica nanofiber composites. Subsequent selective etching of silica porogen produced porous carbon nanofibers (PCNF). It was revealed by surface characterization with X-ray photoelectron spectroscopy (XPS) that the surface of the PCNF was nitrogen-doped because N atom from cyanide group in PAN chains remained in the hexagonal carbon structure. The use of the obtained N-PCNF for heavy metal ion (Hg2+) removal was demonstrated using a simple adsorption test apparatus and 5, 10, 15, 20-tetraphenylporphine tetrasulfonic acid (TPPS) as an indicator. The N-PCNF showed a removal efficiency of 96 and 99% in 10 and 120 min, respectively, indicating a maximum heavy metal ion adsorption capacity at pH 7.0. In addition, heavy metal ion adsorption behavior was also analyzed using common adsorption isotherms. This article provides important information for future research activities regarding control over hazardous substances.

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References

  1. Hou H, Shao G, Yang W, Wong WY (2020) One-dimensional mesoporous inorganic nanostructures and their applications in energy, sensor, catalysis and adsorption. Prog Mater Sci 113:100671

    Article  CAS  Google Scholar 

  2. Diercks CS, Yaghi OM (2017) The atom, the molecule, and the covalent organic framework. Science 355:eaal1585

    Article  Google Scholar 

  3. Sun MH, Huang SZ, Chen LH, Li Y, Yang XY, Yuan ZY, Su BL (2016) Applications of hierarchically structured porous materials from energy storage and conversion, catalysis, photocatalysis, adsorption, separation, and sensing to biomedicine. Chem Soc Rev 45:3479–3563

    Article  CAS  Google Scholar 

  4. Muñoz-Bonilla A, Fernández-García M, Rodríguez-Hernández J (2014) Towards hierarchically ordered functional porous polymeric surfaces prepared by the breath figures approach. Prog Polym Sci 39:510–554

    Article  Google Scholar 

  5. Septevani AA, Evans DAC, Hosseinmardi A, Martin DJ, Simonsen J, Conley JF, Annamalai PK (2018) Atomic layer deposition of metal oxide on nanocellulose for enabling microscopic characterization of polymer nanocomposites. Small 14:1803439

    Article  Google Scholar 

  6. Yang XY, L’eonardLemaireTianSu AAGBL (2011) Self-formation phenomenon to hierarchically structured porous materials: design, synthesis, formation mechanism and applications. Chem Commun 47:2763–2786

    Article  CAS  Google Scholar 

  7. Triantafillidis C, Elsaesser MS, Hüsing N (2013) Chemical phase separation strategies towards silica monoliths with hierarchical porosity. Chem Soc Rev 42:3833–3846

    Article  CAS  Google Scholar 

  8. Kanamori K, Nakanishi K (2011) Controlled pore formation in organotrialkoxysilane-derived hybrids: from aerogels to hierarchically porous monoliths. Chem Soc Rev 40:754–770

    Article  CAS  Google Scholar 

  9. Hong JY, Oh WK, Shin KY, Kwon OS, Son S, Jang J (2012) Spatially controlled carbon sponge for targeting internalized radioactive materials in human body. Biomaterials 33(20):5056–5066

    Article  CAS  Google Scholar 

  10. Hong JY, Bak BM, Wie JJ, Kong J, Park HS (2014) Reversibly compressible, highly elastic, and durable graphene aerogels for energy storage devices under limiting conditions. Adv Funct Mater 25:1053–1062

    Article  Google Scholar 

  11. Hong JY, Yu X, Bak BM, Pang C, Park HS (2015) Bio-inspired functionalization and redox charge transfer of graphene oxide sponges for pseudocapacitive electrodes. Carbon 83:71–78

    Article  CAS  Google Scholar 

  12. Hong JY, Sohn EH, Park S, Park HS (2015) Highly-efficient and recyclable oil absorbing performance of functionalized graphene aerogel. Chem Eng J 269:229–235

    Article  CAS  Google Scholar 

  13. Hong JY, Wie JJ, Xu Y, Park HS (2015) Chemical modification of graphene aerogels for electrochemical capacitor applications. Phys Chem Chem Phys 17:30946–30962

    Article  CAS  Google Scholar 

  14. Hong JY, Yun S, Wie JJ, Zhang X, Dresselhaus MS, Kong J, Park HS (2016) Cartilage-inspired superelastic ultradurable graphene aerogels prepared by the selective gluing of intersheet joints. Nanoscale 8:12900–12909

    Article  CAS  Google Scholar 

  15. Yang B, Zhang D, He J, Wang Y, Wang K, Li H, Wang Y, Miao L, Ren R, Xie M (2020) Simple and green fabrication of a biomass-derived N and O self-doped hierarchical porous carbon via a self-activation route for supercapacitor application. Carbon Lett 30:709–719

    Article  Google Scholar 

  16. Li Y, Zhang D, Zhang M, He J, Wang Y, Wang Y (2020) Biomass-derived microporous carbon with large micropore size for high-performance supercapacitors. J Power Sources 448:227396

    Article  CAS  Google Scholar 

  17. Bi Z, Kong Q, Cao Y, Sun G, Su F, Wei X, Li X, Ahmad A, Xie L, Chen CM (2019) Biomass-derived porous carbon materials with different dimensions for supercapacitor electrodes: a review. J Mater Chem A 7:16028

    Article  CAS  Google Scholar 

  18. He J, Zhang D, Han M, Liu X, Wang Y, Li Y, Zhang X, Wang K, Feng H, Wang Y (2019) One-step large-scale fabrication of nitrogen doped microporous carbon by self-activation of biomass for supercapacitors application. J Energy Storage 21:94

    Article  Google Scholar 

  19. Zhang Q, Han K, Li S, Li M, Li J, Ren K (2018) Synthesis of garlic skin-derived 3D hierarchical porous carbon for high-performance supercapacitors. Nanoscale 10:2427

    Article  CAS  Google Scholar 

  20. Wang Y, Tang X, Han M, Li Y, Zhang Y, He J, Liu X, Wang K, Wang Y, Zhang D (2019) One-step synthesis of the N and P co-doped nest-like mesoporous carbon by a microwave-assisted ultra-high temperature solvothermal method for supercapacitor application. Chem Sel 4:1108

    CAS  Google Scholar 

  21. Cao B, Liu H, Xu B, Lei Y, Chen X, Song H (2016) Mesoporous soft carbon as an anode material for sodium ion batteries with superior rate and cycling performance. J Mater Chem A 4:6472

    Article  CAS  Google Scholar 

  22. Oda H, Yamashita A, Minoura S, Okamoto M, Morimoto T (2006) Modification of the oxygen-containing functional group on activated carbon fiber in electrodes of an electric double-layer capacitor. J Power Sources 158:1510

    Article  CAS  Google Scholar 

  23. Lee HM, Lee BH, Kim JH, An KH, Park SJ, Kim BJ (2019) Determination of the optimum porosity for 2-CEES adsorption by activated carbon fiber from various precursors. Carbon Lett 29:649–654

    Article  Google Scholar 

  24. Giannakoudakis DA, Barczak M, Florent M, Bandosz TJ (2019) Analysis of interactions of mustard gas surrogate vapors with porous carbon textiles. Chem Eng J 362:758–766

    Article  CAS  Google Scholar 

  25. Im JS, Park SJ, Lee YS (2009) Superior prospect of chemically activated electrospun carbon fibers for hydrogen storage. Mater Res Bull 44(9):1871–1878

    Article  CAS  Google Scholar 

  26. Zhi M, Liu S, Hong Z, Wu N (2014) Electrospun activated carbon nanofibers for supercapacitor electrodes. RSC Adv 4(82):43619–43623

    Article  CAS  Google Scholar 

  27. Bae K, Gwak N, Park MK, Lee B, Lee KJ (2019) Synthesis of multi-functionalized N-Cl hydantoin polyurethane for chemical warfare agent decomposition with High N–Cl stability. Macromol Chem Phys 220:1900213

    Article  Google Scholar 

  28. Moon S, Yun J, Lee JY, Park G, Kim SS, Lee KJ (2019) Mass-production of electrospun carbon nanofiber containing SiOx for lithium-ion batteries with enhanced capacity. Macromol Mater Eng 304:1800564

    Article  Google Scholar 

  29. Choi J, Moon DS, Ryu SG, Lee B, Lee KJ (2018) Highly functionalized thermoplastic polyurethane from surface click reactions. J Appl Polym Sci 135:46519

    Article  Google Scholar 

  30. Ghimire PP, Jaroniec M (2021) Renaissance of Stöber method for synthesis of colloidal particles: new developments and opportunities. J Colloid Interface Sci 584:838–865

    Article  CAS  Google Scholar 

  31. Greasley SL, Page SJ, Sirovica S, Chen S, Martin RA, Riveiro A, Hanna JV, Porter AE, Jones JR (2016) Controlling particle size in the Stöber process and incorporation of calcium. J Colloid Interface Sci 469:213–223

    Article  CAS  Google Scholar 

  32. Marcuzzo JS, Otani C, Polidoro HA, Otani S (2013) Influence of thermal treatment on porosity formation on carbon fiber from textile PAN. Mater Res 16(1):137–144

    Article  CAS  Google Scholar 

  33. Nomura S, Arima T (2001) The effect of volume change of coal during carbonization in the direction of coke oven width on the internal gas pressure in the plastic layer. Fuel 80(9):1307–1315

    Article  CAS  Google Scholar 

  34. Gbewonyo S, Xiu S, Shahbazi A, Zhang L (2020) Low thermal conductivity carbon material from electrospinning and subsequent chemical activation. Carbon Lett 30:289–296

    Article  Google Scholar 

  35. Maddah B, Soltaninezhad M, Adib K, Hasanzadeh M (2017) Activated carbon nanofiber produced from electrospun PAN nanofiber as a solid phase extraction sorbent for the preconcentration of organophosphorus pesticides. Sep Sci Technol 52(4):700–711

    Article  CAS  Google Scholar 

  36. Zhang D, Zhang C, Wang Q, Li S, Zhao X, Luo H (2020) Preparation and electrochemical properties of self-doped nitrogen porous carbon derived from Zn-MOFs. Carbon Lett 30:315–324

    Article  Google Scholar 

  37. Chen X, Chen C, Zhang Z, Xie D (2013) Gelatin-derived nitrogen-doped porous carbon via a dual-template carbonization method for high performance supercapacitors. J Mater Chem A 1:10903

    Article  CAS  Google Scholar 

  38. Wang H, Zhang C, Liu Z, Wang L, Han P, Xu H, Zhang K, Dong S, Yao J, Cui G (2011) Nitrogen-doped graphene nanosheets with excellent lithium storage properties. J Mater Chem 21:5430

    Article  CAS  Google Scholar 

  39. Lin G, Ma R, Zhou Y, Liu Q, Dong X, Wang J (2018) KOH activation of biomass-derived nitrogen-doped carbons for supercapacitor and electrocatalytic oxygen reduction. Electrochim Acta 261:49

    Article  CAS  Google Scholar 

  40. Kim MA, Jang D, Tejima S, Cruz-Silva R, Joh HI, Kim HC, Lee S, Endo M (2016) Strengthened PAN-based carbon fibers obtained by slow heating rate carbonization. Sci Rep 6:22988

    Article  CAS  Google Scholar 

  41. Liu L, Xie ZH, Deng QF, Hou XX, Yuan ZY (2017) One-pot carbonization enrichment of nitrogen in microporous carbon spheres for efficient CO2 capture. J Mater Chem A 5:418–425

    Article  CAS  Google Scholar 

  42. Shin KY, Hong JY, Jang J (2011) Heavy metal ion adsorption behavior in nitrogen-doped magnetic carbon nanoparticles: isotherms and kinetic study. J Hazard Mater 190:36–44

    Article  CAS  Google Scholar 

  43. Gu GE, Bae J, Park HS, Hong JY (2021) Development of the functionalized nanocomposite materials for adsorption/decontamination of radioactive pollutants. Materials 14:2896

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the Industrial Strategic Technology Development Program (20012763, development of petroleum residue-based porous adsorbent for industrial wastewater treatment) and funded by the Ministry of Trade, Industry & Energy (MOTIE, Korea) and by National Research Foundation of Korea, Grant numbers NRF-2021R1F1A1061939.

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Authors and Affiliations

  1. Department of Applied Chemistry, Dongduk Women’s University, Seoul, 02748, Republic of Korea

    Joonwon Bae

  2. Center for C1 Gas & Carbon Convergent Research, Korea Research Institute of Chemical Technology (KRICT), 141 Gajeong-ro, Yuseong-gu, Daejeon, 34114, Republic of Korea

    Jin-Yong Hong

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  1. Joonwon Bae
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Contributions

JB: design and perform the experiments, investigation, data analysis, visualization, writing original draft, and funding acquisition. JYH: conceptualization, developed the research plan and experimental strategy, performed part of the experiments, investigation, visualization, writing–review & editing, and funding acquisition. All authors discussed the results, reviewed and edited the manuscript.

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Correspondence to Jin-Yong Hong.

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Bae, J., Hong, JY. Fabrication of nitrogen-doped porous carbon nanofibers for heavy metal ions removal. Carbon Lett. 31, 1339–1347 (2021). https://doi.org/10.1007/s42823-021-00291-w

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  • DOI: https://doi.org/10.1007/s42823-021-00291-w

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