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Electrical and Magnetic Properties of Rare Earth Doped Pb0.8R0.2Fe0.1Cr0.1Ti0.8O3 Ceramics

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Abstract

Rare earth doped Pb0.8R0.2Fe0.1Cr0.1Ti0.8O3 (R = La, Nd, Sm) ceramics were prepared by solid state reaction method. The formation of the materials was confirmed using X-ray diffraction. A meticulous investigation of dielectric properties was carried out in order to evaluate the macroscopic effect and ensuing incorporation of rare earth ions over a wide range of frequency and temperature. The phase transition temperatures of these ceramics were in the range of 75–115 °C and 325–365 °C. The ac conductivity of the samples was found to be frequency and temperature dependent. Charge transport through short as well as long range conduction contributions were indicated in different temperature regions of conductivity studies. The ferroelectric, magnetic hysteresis and magnetoelectric measurements were conducted to affirm the multiferroic properties in these materials.

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Acknowledgements

Authors are grateful to Dr. D. Pradhan, Materials Science Center, IIT, Kharagpur for providing FESEM facility and Dr. M. Shahid Anwar, Colloids and Materials Chemistry Department, IMMT, Bhubaneswar for M-E coefficient measurement. One of the authors (Amrita Nayak) would like to thank Govt. of Odisha, Science & Technology Department for providing financial assistance to carry out research work.

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Nayak, A., Patri, S.K. & Behera, B. Electrical and Magnetic Properties of Rare Earth Doped Pb0.8R0.2Fe0.1Cr0.1Ti0.8O3 Ceramics. Trans. Electr. Electron. Mater. 23, 441–456 (2022). https://doi.org/10.1007/s42341-021-00380-7

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