Skip to main content
SpringerLink
Log in

Modeling the Interactionof F-gases on Ruthenium-Doped Boron Nitridenanotube

  • Original Article
  • Published:
Chemistry Africa Aims and scope Submit manuscript

Abstract

Fluorinated gases (F-gases) emission is one of the primaries, toxic, and largest pollutants released into the environment. In this work, first-principles computation was used to investigate the adsorbing performance of F-gases: CFC-11, CFC-12, E-HFO-1234, HCFC-22, HFC-23, HFC-134, and PFC-14 onto the surface of ruthenium-doped boron nitride nanotube (Ru@BN). Density functional theory (DFT) at PBE0/GenECP/LanL2DZ/6-311 + + G(d,p) level of theory has been adopted in this investigation to arrive at various conclusions. Comparative adsorption studies have been carried out using three adsorption models of hybrid functionals: M062X-D3, PBE0-D3, and ωB97XD at the 6-311 + + G(d,p)/LanL2DZ basis set, for better insights into the adsorbing behavior of the studied gases.The energy of interactions, nature of bonding, and the global reactivity descriptors indicate weak interactions in all cases. To ascertain these results, the QTAIM analysis has been utilized and then confirmed with the RDG analysis which is a visual extension of the AIM analysis. The color region where red color sweep majorly on the isosurface indicate weak interaction. All these analyses provided the opportunity to arrive at a conclusive scientific result that the interaction between F-gases and the ruthenium-doped boron nitride is weak and best described as physisorption phenomena.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

Data Availability

All data are contained within the manuscript.

References

  1. Vadikkeettil Y, Subramaniam Y, Murugan R, Ananthapadmanabhan PV, Mostaghimi J, Pershin L, Kobayashi Y (2022) Plasma assisted decomposition and reforming of greenhouse gases: a review of current status and emerging trends. Renew Sustain Energy Rev 161:112343

    Article  CAS  Google Scholar 

  2. Sheldon DJ, Crimmin MR (2022) Repurposing of F-gases: challenges and opportunities in fluorine chemistry. Chem Soc Rev 20(3):734–744

    Google Scholar 

  3. El Diwani G, Amin SK, Attia NK, Hawash SI (2022) Fluoride pollutants removal from industrial wastewater. Bull Natl Res Centre 46(1):1–9

    Article  Google Scholar 

  4. Kharraz JA, Khanzada NK, Farid MU, Kim J, Jeong S, An AK (2022) Membrane distillation bioreactor (MDBR) for wastewater treatment, water reuse, and resource recovery: a review. J Water Process Eng 47:102687

    Article  Google Scholar 

  5. Fu WC, MacQueen PM, Jamison TF (2021) Continuous flow strategies for using fluorinated greenhouse gases in fluoroalkylations. Chem Soc Rev 50(13):7378–7394

    Article  CAS  PubMed  Google Scholar 

  6. Znidar D, Dallinger D, Kappe CO (2022) Practical guidelines for the safe use of Fluorine Gas employing continuous Flow Technology. ACS Chem Health Safety 29(2):165–174

    Article  CAS  Google Scholar 

  7. Gaines LG Historical and current usage of per-and polyfluoroalkyl substances (PFAS): a literature review. American Journal of Industrial Medicine

  8. Cole JC, Taylor R (2022) Intermolecular interactions of organic fluorine seen in perspective. Cryst Growth Des 22:1352

    Article  CAS  Google Scholar 

  9. Rocha M, Echeverría GA, Piro OE, Jios JL, Ulic SE, Gil DM (2021) Role of fluorine-fluorine and weak intermolecular interactions in the supramolecular network of a new trifluoromethyl-1, 5-benzodiazepine: crystal structure, Hirshfeld surface analysis and theoretical study. J Fluorine Chem 242:109697

    Article  CAS  Google Scholar 

  10. Ma J, Zheng Z, Hoque MJ, Li L, Rabbi KF, Ho JY, Miljkovic N (2022) A lipid-inspired highly adhesive interface for durable superhydrophobicity in Wet environments and stable jumping droplet condensation. ACS Nano 16(3):4251–4262

    Article  CAS  PubMed  Google Scholar 

  11. Narayanan VR, Gnybida M, Rümpler C (2022) Transport and radiation properties of C4F7N-CO2 gas mixtures with added oxygen. J Phys D 55(29):295502

    Article  Google Scholar 

  12. Nielsen MM, Pedersen CM (2022) Vessel effects in organic chemical reactions; a century-old, overlooked phenomenon. Chem Sci 13:6181

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  13. Tack O (2020) Novel radiochemistry for positron emission tomography imaging (Doctoral dissertation, University of Oxford)

  14. Ferreira ML, Vieira NS, Castro PJ, Vega LF, Araújo JM, Pereiro AB (2022) Understanding the phase and solvation behavior of fluorinated ionic liquids. J Mol Liq 359:119285

    Article  CAS  Google Scholar 

  15. Haqq-Misra J, Kopparapu R, Fauchez TJ, Frank A, Wright JT, Lingam M (2022) Detectability of chlorofluorocarbons in the atmospheres of habitable M-dwarf planets. Planet Sci J 3(3):60

    Article  Google Scholar 

  16. Manderfeld E, Kleinberg MN, Thamaraiselvan C, Koschitzki F, Gnutt P, Plumere N, Rosenhahn A (2021) Electrochemically activated laser-induced graphene coatings against marine biofouling. Appl Surf Sci 569:150853

    Article  CAS  Google Scholar 

  17. Shaik MH, Kolla S, Prasad Katuru B (2022) Exergy and energy analysis of low GWP refrigerants in the perspective of replacement of HFC-134a in a home refrigerator. Int J Ambient Energy 43(1):2339–2350

    Article  CAS  Google Scholar 

  18. Jiang J, Hu B, Wang RZ, Deng N, Cao F, Wang CC (2022) A review and perspective on industry high-temperature heat pumps. Renew Sustain Energy Rev 161:112106

    Article  CAS  Google Scholar 

  19. Peyrton J, Avérous L (2021) Structure-properties relationships of cellular materials from biobased polyurethane foams. Mater Sci Eng 145:100608

    Article  Google Scholar 

  20. Tomlin AS (2021) Air quality and climate impacts of biomass use as an energy source: a review. Energy Fuels 35(18):14213–14240

    Article  CAS  Google Scholar 

  21. Dai C, Han Y, Duan Y, Lai X, Fu R, Liu S, Zhou L (2022) Review on the contamination and remediation of polycyclic aromatic hydrocarbons (PAHs) in coastal soil and sediments. Environ Res 205:112423

    Article  CAS  PubMed  Google Scholar 

  22. Louis H, Ikenyirimba OJ, Unimuke TO, Mathias GE, Gber TE, Adeyinka AS (2022) Electrocatalytic activity of metal encapsulated, doped, and engineered fullerene-based nanostructured materials towards hydrogen evolution reaction. Sci Rep 12(1):15608

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  23. Derakhshi M, Daemi S, Shahini P, Habibzadeh A, Mostafavi E, Ashkarran AA (2022) Two-dimensional nanomaterials beyond graphene for biomedical applications. J Funct Biomater 13(1):27

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  24. Hasan M, Bithe SA, Neher B, Ahmed F (2022) Polythiophene as a sensor model for chlorofluorocarbon, fluorine, and oxygen gas using DFT calculations. J Mol Model 28(3):1–13

    Article  Google Scholar 

  25. Ogunwale GJ, Louis H, Gber TE, Adeyinka AS (2022) Modeling of pristine, Ir-and Au-decorated C60 fullerenes as sensors for detection of hydroxyurea and nitrosourea drugs. J Environ Chem Eng 10(6):108802

    Article  CAS  Google Scholar 

  26. Mohammadi MD, Abdullah HY (2021) The adsorption of bromochlorodifluoromethane on pristine, Al, Ga, P, and As-doped boron nitride nanotubes: a study involving PBC-DFT, NBO analysis, and QTAIM. Comput Theor Chem 1193:113047

    Article  Google Scholar 

  27. Louis H, Etiese D, Unimuke TO, Owen AE, Rajee AO, Gber TE, Nfor EN (2022) Computational design and molecular modeling of the interaction of nicotinic acid hydrazide nickel-based complexes with H 2 S gas. RSC Adv 12(47):30365–30380

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  28. Subhashree S, Kumar PS (2022) New analytical strategies amplified with carbon-based nanomaterial for sensing food pollutants. Chemosphere 295:133847

    Article  Google Scholar 

  29. Ansari AA, Malhotra BD (2022) Current progress in organic–inorganic hetero-nano-interfaces based electrochemical biosensors for healthcare monitoring. Coord Chem Rev 452:214282

    Article  CAS  Google Scholar 

  30. Apebende CG, Idante PS, Louis H, Ameuru US, Unimuke TO, Gber TE, …, Asogwa FC (2022) Integrated spectroscopic, bio-active prediction and analytics of isoquinoline derivative for breast cancer mitigation. Chem Afr 5(6):1979–1995

    Article  CAS  Google Scholar 

  31. Gharaati A, Abed Y, Mostaghni F (2022) Nonlinear optical characteristics of N, N’-bis (salicylidene)-p-phenylenediamine: Z-scan technique and quantum mechanical calculations. Bull Chem Soc Ethiop 36(2):465–477

    Article  CAS  Google Scholar 

  32. Apebende CG, Louis H, Owen AE, Benjamin I, Amodu IO, Gber TE, Asogwa FC (2022) Adsorption properties of metal functionalized fullerene (C59Au, C59Hf, C59Ag, and C59Ir) nanoclusters for application as a biosensor for hydroxyurea (HXU): insight from theoretical computation. Z für Phys Chemie 236(11–12):1515–1546

    Article  CAS  Google Scholar 

  33. Rushiti A, Hättig C (2021) Activation of molecular O2 on CoFe2O4 (001) Surfaces: an embedded cluster study. Chem A Eur J 27(68):17115–17126

    Article  CAS  Google Scholar 

  34. Pierri G, Corno M, Macedi E, Voccia M, Tedesco C (2021) Solid-state conformational flexibility at work: energetic Landscape of a single crystal-to-single crystal transformation in a cyclic hexapeptoid. Cryst Growth Des 21(2):897–907

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  35. Pinter B, Broeckaert L, Turek J, Růžička A, De Proft F (2014) Dimers of N-heterocyclic carbene copper, silver, and gold halides: probing metallophilic interactions through electron density based concepts. Chem A Eur J 20(3):734–744

    Article  CAS  Google Scholar 

  36. Owens RG (2022) The separation angle of the free surface of a viscous fluid at a straight edge. J Fluid Mech 942:A50

    Article  CAS  Google Scholar 

  37. Sohail U, Ullah F, Mahmood T, Muhammad S, Ayub K (2022) Adsorption of industrial gases (CH4, CO2, and CO) on olympicene: a DFT and CCSD (T) investigation. ACS Omega 7:18852

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  38. Edet HO, Louis H, Gber TE, Idante PS, Egemonye TC, Ashishie PB, Adeyinka AS (2023) Heteroatoms (B, N, S) doped quantum dots as potential drug delivery system for isoniazid: insight from DFT, NCI, and QTAIM. Heliyon 9(1):e12599

    Article  CAS  PubMed  Google Scholar 

  39. Mohammadi MD, Abdullah HY, Louis H, Mathias GE (2022) 2D boron nitride material as a sensor for H2SiCl2. Comput Theor Chem 1213:113742

    Article  Google Scholar 

  40. Zhang C, Wang M, Jiang C, Zhu P, Sun B, Gao Q, Liu R (2022) Highly adhesive and self-healing γ-PGA/PEDOT: PSS conductive hydrogels enabled by multiple hydrogen bonding for wearable electronics. Nano Energy 95:106991

    Article  CAS  Google Scholar 

  41. Abbas F, Mohammadi MD, Louis H, Amodu IO, Charlie DE, Gber TE (2023) Design of new bithieno thiophene (BTTI) central core-based small molecules as efficient hole transport materials for perovskite solar cells and donor materials for organic solar cells. Mater Sci Eng 291:116392

    Article  CAS  Google Scholar 

  42. Unimuke TO, Louis H, Eno EA, Agwamba EC, Adeyinka AS (2022) Meta-hybrid density functional theory prediction of the Reactivity, Stability, and IGM of Azepane, Oxepane, Thiepane, and Halogenated Cycloheptane. ACS Omega 7(16):13704–13720

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  43. Unimuke TO, Louis H, Emori W, Idante PS, Agwamba EC, Nwobodo IC, Anyama CA (2022) Spectroscopic and molecular electronic property investigation of 2-phenylpyrimidine-4, 6-diamine via 1H NMR, UV–vis, FT-Raman, FT-IR, and DFT approach. J Mol Struct 1263:133195

    Article  CAS  Google Scholar 

  44. Afahanam LE, Louis H, Benjamin I, Gber TE, Ikot IJ, Manicum ALE (2023) Heteroatom (B, N, P, and S)-doped cyclodextrin as a hydroxyurea (HU) drug nanocarrier: a computational approach. ACS Omega 278:125518

    Google Scholar 

  45. Louis H, Charlie DE, Amodu IO, Benjamin I, Gber TE, Agwamba EC, Adeyinka AS (2022) Probing the reactions of thiourea (CH4N2S) with metals (X = au, hf, hg, ir, Os, W, Pt, and re) anchored on fullerene surfaces (C59X). ACS Omega 7(39):35118–35135

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  46. Kaur J, Kumar R, Vohra R, Sawhney RS (2020) A pursuit to design highly sensitive fullerene-based sensors: adsorption and dissociation phenomenon of toxic sulfur gases on B40 fullerene. J Mol Model 26(1):1–13

    Article  Google Scholar 

  47. Cortés-Arriagada D (2018) Phosphorene as a template material for physisorption of DNA/RNA nucleobases and resembling of base pairs: a cluster DFT study and comparisons with graphene. J Phys Chem C 122(9):4870–4880

    Article  Google Scholar 

  48. Paularokiadoss F, Sekara A, Jeyakumarc TC (2019) DFT studies on the adsorption of CFC over the copper embedded nitrogen doped graphene. J Emerg Technol Innov Res 6:276–88

    Google Scholar 

  49. Parlak C, Alver Ö, Şenyel M (2017) Computational study on favipiravir adsorption onto undoped-and silicon-decorated C60 fullerenes. J Theoretical Comput Chem 16(02):1750011

    Article  CAS  Google Scholar 

  50. Louis H, Gber TE, Asogwa FC, Eno EA, Unimuke TO, Bassey VM, Ita BI (2022) Understanding the lithiation mechanisms of pyrenetetrone-based carbonyl compound as cathode material for lithium-ion battery: insight from first principle density functional theory. Mater Chem Phys 278:125518

    Article  CAS  Google Scholar 

  51. Agwupuye JA, Louis H, Unimuke TO, David P, Ubana EI, Moshood YL (2021) Electronic structure investigation of the stability, reactivity, NBO analysis, thermodynamics, and the nature of the interactions in methyl-substituted imidazolium-based ionic liquids. J Mol Liq 337:116458

    Article  CAS  Google Scholar 

  52. Gber TE, Louis H, Owen AE, Etinwa BE, Benjamin I, Asogwa FC, …, Eno EA (2022) Heteroatoms (Si, B, N, and P) doped 2D monolayer MoS 2 for NH 3 gas detection. RSC Adv 12(40):25992–26010

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  53. Pandya JB, Shinde SM, Jha PK (2022) Theoretical study on the interaction of flutamide anticancer drug with cucurbit [n] uril (n = 5–8) as a drug delivery system. Int J Quantum Chem 122:e26899

    Article  CAS  Google Scholar 

  54. Mérillet L, Robert M, Hernvann PY, Pecuchet L, Pavoine S, Mouchet M, Kopp D (2022) Effects of life-history traits and network topological characteristics on the robustness of marine food webs. Global Ecol Conserv 34:e02048

    Article  Google Scholar 

  55. Skardal PS, Arola-Fernández L, Taylor D, Arenas A (2021) Higher-order interactions can better optimize network synchronization. Phys Rev Res 3(4):043193

    Article  CAS  Google Scholar 

  56. Liu Z, Gui Y, Xu L, Chen X (2022) Adsorption and gas-sensing properties of Aun (n = 1–3) cluster doped MoTe2 for NH3, NO2, and SO2 gas molecules. Surf Interfaces 30:101883

    Article  CAS  Google Scholar 

  57. Louis H, Gber TE, Charlie DE, Egemonye TC, Orosun MM (2022) Detection of hydroxymethanesulfonate (HMS) by transition metal-anchored fullerene nanoclusters. J Iran Chem Soc 20:1–17

    Google Scholar 

  58. Louis H, Chima CM, Amodu IO, Gber TE, Unimuke TO, Adeyinka AS (2023) Organochlorine detection on transition metals (X = zn, Ti, Ni, Fe, and cr) anchored fullerenes (C23X). ChemistrySelect 8(2):e202203843

    Article  CAS  Google Scholar 

  59. Patrick-Inezi FS, Emori W, Louis H, Apebende CG, Agwamba EC, Unimuke TO, Agwupuye JA (2022) Analeptic activity of 2-Hydroxyl-5-Nitrobenzaldehyde:Experimental, DFT studies, and in silico molecular docking approach. Healthcare Anal 2:100030

    Article  Google Scholar 

  60. Odey DO, Louis H, Ita DK, Edet HO, Ashishie PB, Gber TE, Effa AG (2023) Intermolecular interactions of cytosine DNA nucleoside base with gallic acid and its methylgallate and ethylgallate derivatives. ChemistrySelect 8(9):e202203832

    Article  CAS  Google Scholar 

  61. Mahmoudzadeh G, Kouchakzadeh G (2022) CRS J Chem Reactivity Synthesis 12(1):54–81

    Google Scholar 

  62. Bader RF (2007) Everyman’s derivation of the theory of atoms in molecules. J Phys Chem A 111(32):7966–7972

    Article  CAS  PubMed  Google Scholar 

  63. Eno EA, Louis H, Unimuke TO, Gber TE, Mbonu IJ, Ndubisi CJ, Adalikwu SA (2022) Reactivity, stability, and thermodynamics of para-methylpyridinium-based ionic liquids: insight from DFT, NCI, and QTAIM. J Ionic Liq 2(1):100030

    Article  Google Scholar 

  64. Mohammadi MD, Abbas F, Louis H, Afahanam LE, Gber TE (2022) Intermolecular interactions between nitrosourea and polyoxometalate compounds. ChemistrySelect 7(36):e202202535

    Article  CAS  Google Scholar 

  65. Gupta S, Nguyen NA, Muhich CL (2022) Surface water H-bonding network is key controller of selenate adsorption on [0 1 2] α-alumina: an Ab-initio study. J Colloid Interface Sci 617:136–146

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  66. Hossain MR, Hasan MM, Shamim SUD, Ferdous T, Hossain MA, Ahmed F (2021) First-principles study of the adsorption of chlormethine anticancer drug on C24, B12N12 and B12C6N6 nanocages. Comput Theor Chem 1197:113156

    Article  Google Scholar 

  67. Odey DO, Edet HO, Louis H, Gber TE, Nwagu AD, Adalikwu SA, Adeyinka AS (2023) Heteroatoms (B, N, and P) doped on nickel-doped graphene for phosgene (COCl2) adsorption: insight from theoretical calculations. Mater Today Sustain 21:100294

    Article  Google Scholar 

  68. Bassey VM, Apebende CG, Idante PS, Louis H, Emori W, Cheng C, R.,… Asogwa, F. C. (2022) Vibrational characterization and molecular electronic investigations of 2-acetyl-5-methylfuran using FT-IR, FT-Raman, UV–VIS, NMR, and DFT methods. J Fluoresc 32:1–13

    Article  Google Scholar 

  69. Louis H, Guo LJ, Zhu S, Hussain S, He T (2019) Computational study on interactions between CO2 and (TiO2) n clusters at specific sites. Chin J Chem Phys 32(6):674–686

    Article  CAS  Google Scholar 

  70. Wei K, Louis H, Emori W, Idante PS, Agwamba EC, Cheng CR, Unimuke TO (2022) Antispasmodic activity of carnosic acid extracted from rosmarinus officinalis: Isolation, spectroscopic characterization, DFT studies, and in silico molecular docking investigations. J Mol Struct 1260:132795

    Article  CAS  Google Scholar 

  71. Anyama CA, Louis H, Inah BE, Gber TE, Ogar JO (2023) Synthesis AYIA crystal structure, DFT studies, and molecular docking of Zn-BTC MOF as potential antiprotozoal agents. J Mol Struct 1277:134825

    Article  CAS  Google Scholar 

  72. Blasques F, van Brummelen J, Koopman SJ, Lucas A (2022) Maximum likelihood estimation for score-driven models. J Econ 227(2):325–346

    Article  Google Scholar 

  73. Arulsamy AD (2022) Second law of classical and quantum thermodynamics and its validity for any timescale and system size. Available at SSRN 4268662

  74. Louis H, Ekereke EE, Isang BB, Ikeuba AI, Amodu IO, Gber TE, Agwamba EC (2022) Assessing the performance of Al12N12 and Al12P12 nanostructured materials for alkali metal ion (Li, Na, K) batteries. ACS omega 210:112870

    Google Scholar 

  75. Sovacool BK, Griffiths S, Kim J, Bazilian M (2021) Climate change and industrial F-gases: a critical and systematic review of developments, sociotechnical systems and policy options for reducing synthetic greenhouse gas emissions. Renew Sustain Energy Rev 141:110759

    Article  CAS  Google Scholar 

  76. Shukla SK, Ebenso EE (2011) Corrosion inhibition, adsorption behavior and thermodynamic properties of streptomycin on mild steel in hydrochloric acid medium. Int J Electrochem Sci 6(8):3277–3291

    Article  CAS  Google Scholar 

  77. Tang J, Chen Y, Wang S, Kong D, Zhang L (2022) Highly efficient metal-organic frameworks adsorbent for pd (II) and au (III) recovery from solutions: experiment and mechanism. Environ Res 210:112870

    Article  CAS  PubMed  Google Scholar 

  78. Hossain MR, Hasan MM, Rahman H, Rahman MS, Ahmed F, Ferdous T, Hossain MA (2021) Adsorption behaviour of metronidazole drug molecule on the surface of hydrogenated graphene, boron nitride and boron carbide nanosheets in gaseous and aqueous medium: a comparative DFT and QTAIM insight. Physica E 126:114483

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors want to convey their gratitude to everyone who has helped them with this project and the Centre for high-performance computing (CHPC), South Africa for the computational resources.

Funding

This research was not funded by any Governmental or Non-governmental agency.

Author information

Authors and Affiliations

  1. Computational and Bio-Simulation Research Group, University of Calabar, Calabar, Nigeria

    Hitler Louis, Ismail O. Amodu, Ededet A. Eno, Innocent Benjamin, Terkumbur E. Gber, Tomsmith O. Unimuke & Bartholomew B. Isang

  2. Department of Pure and Applied Chemistry, Faculty of Physical Sciences, University of Calabar, Calabar, Nigeria

    Hitler Louis, Ededet A. Eno, Terkumbur E. Gber & Tomsmith O. Unimuke

  3. Department of Mathematics, Faculty of Physical Sciences, University of Calabar, Calabar, Nigeria

    Ismail O. Amodu & Bartholomew B. Isang

  4. Department of Chemical Sciences, University of Johannesburg, 2006, Johannesburg, South Africa

    Adedapo S. Adeyinka

Authors
  1. Hitler Louis
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ismail O. Amodu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ededet A. Eno
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Innocent Benjamin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Terkumbur E. Gber
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Tomsmith O. Unimuke
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Bartholomew B. Isang
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Adedapo S. Adeyinka
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

HL: Project conceptualization, design, and supervision. IOA and TOU: Writing, results extraction, analysis, and manuscript first draft. TEG and BBI: Manuscript revision, review, and proofreading. IB and EAE: Manuscript review and editing. AA: Resources, review, and editing.

Corresponding authors

Correspondence to Hitler Louis or Terkumbur E. Gber.

Ethics declarations

Conflict of Interest

All authors declare zero financial or inter-personal conflict of interest that could have influenced the research work or results reported in this research paper.

Ethical Approval

Not applicable.

Consent to Participate

Not applicable.

Consent for Publication

Not applicable.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic Supplementary Material

Below is the link to the electronic supplementary material.

Supplementary Material 1

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Louis, H., Amodu, I.O., Eno, E.A. et al. Modeling the Interactionof F-gases on Ruthenium-Doped Boron Nitridenanotube. Chemistry Africa 6, 1961–1979 (2023). https://doi.org/10.1007/s42250-023-00645-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s42250-023-00645-z

Keywords

Search

Navigation