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Mechanical properties and elastic moduli, as well as gamma-ray attenuation abilities: A wide-ranging investigation into calcium/sodium/phosphate glasses

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Abstract

Elastic moduli parameters and photon attenuation competence of phosphate (P2O5)/sodium (Na2O)/calcium (CaO) glasses with form 45P2O5–(55-x)Na2O–xCaO: x = 0–55 mol% (PNC-0:PNC-55) have been estimated and clarified. The development in Poisson’s ratio and elastic moduli parameters (bulk, Young’s, shear, and longitudinal) of the heavier CaO content of the PNC-glasses were proved through Makishima-Mackenzie (M-M) and bond compression (B-C) models. The B-C bulk elastic (KB-C) modulus was found to raise from 71.4 to 95.16 GPa, while the M-M bulk (KM-M) modulus was increased from 22.48 to 40.75 GPa for PNC-0 (glass sample free with CaO) and PNC-55 (glass sample rich with CaO), respectively. The highest mass attenuation coefficient (MAC) values were reported for PNC-55 sample, whereas the lowest were reported for PNC-0 sample. Half value layer (HVL) values were reported as 1.6526 cm, 1.6181 cm, 1.5734 cm, 1.5275 cm, 1.4847 cm, 1.441 cm, and 1.4172 cm for PNC-0, PNC-10, PNC-20, PNC-30, PNC-40, PNC-50, and PNC-55 samples at 0.1 MeV, respectively. The effective atomic numbers (Zeff) were reported as 10.2658, 10.4393, 10.6149, 10.7924, 10.9719, 11.1536, and 11.2451 for PNC-0, PNC-10, PNC-20, PNC-30, PNC-40, PNC-50, and PNC-55 samples at 0.1 MeV, respectively. The PNC-55 sample was reported with a maximum value of effective atomic weight for absorption (Aeff). The lowest exposure and energy absorption buildup factors (EBF and EABF) values were discovered for the PNC-55 sample, while the highest EBF values were found for the pure PNC-0 sample. Finally, one can conclude that the PNC-55 is a superior for gamma-ray attenuation competencies.

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References

  1. Siegel, J., Navarro, J.M.F., Navarro, A.G., Blanco, V.D., Sanz, O., Solis, J., Vega, F., Armengol, J.: Waveguide structures in heavy metal oxide glass written with femtosecond laser pulses above the critical self-focusing threshold. Appl. Phys. Lett. 86, 121109 (2005)

    Article  Google Scholar 

  2. Yang, W., Corbari, C., Kazansky, P.G., Sakaguchi, K., Carvalho, I.C.S.: Low loss photonic components in high index bismuth borate glass by femtosecond laser direct writing. Opt. Express. 16, 16215–16226 (2008)

    Article  CAS  Google Scholar 

  3. Ashok, J., Purnachand, N., Suresh Kumar, J., Reddy, M.S., Suresh, B., Graça, M.P.F., Veeraiah, N.: Studies on dielectric dispersion, relaxation kinetics and a.c. conductivity of Na2O-CuO-SiO2 glasses mixed with Bi2O3-influence of redox behavior of copper ions. J. Alloys Compd. 696, 1260–1268 (2017)

    Article  CAS  Google Scholar 

  4. Gancheva, V., Yordanov, N.D., Karakirov, Y.: EPR investigation of the gamma radiation response of different types of glasses. Spectrochim. Acta A. 63, 875–878 (2006)

    Article  Google Scholar 

  5. Caldas, L.V.E., Quezada, V.A.C.: Influence of thermal treatments on the response decay of glass radiation detectors. Radiat. Prot. Dosim. 100, 433–436 (2002)

    Article  CAS  Google Scholar 

  6. Marzouk, M.A., ElBatal, H.A., Abdel Ghany, A.M., Ezz Eldin, F.M.: Ultraviolet, visible, ESR, and infrared spectroscopic studies of CeO2-doped lithium phosphate glasses and effect of gamma irradiation. J. Mol. Struct. 997(1-3), 94–102 (2011)

    Article  CAS  Google Scholar 

  7. El-Batal, F.H., Khalil, E.M., Hamdy, Y.M., Zidan, H.M., Aziz, M.S., Abdelghany, A.M.: FTIR spectral analysis of corrosion mechanisms in soda lime silica glasses doped with transition metal oxides. Silicon. 2(1), 41–47 (2010)

    Article  CAS  Google Scholar 

  8. Mortada, W.I., Kenawy, I.M.M., Abdelghany, A.M., Ismail, A.M., Donia, A.F., Nabieh, K.A.: Determination of Cu2+, Zn2+ and Pb2+ in biological and food samples by FAAS after preconcentration with hydroxyapatite nanorods originated from eggshell. Mater. Sci. Eng. C. 52, 288–296 (2015)

    Article  CAS  Google Scholar 

  9. Hammad, A.H., Abdelghany, A.M.: Optical and structural investigations of zinc phosphate glasses containing vanadium ions. J. Non-Cryst. Solids. 433, 14–19 (2016)

    Article  CAS  Google Scholar 

  10. Abdelghany, A.M., Rammah, Y.S.: Transparent alumino lithium borate glass-ceramics: synthesis, structure and gamma-ray shielding attitude. J. Inorg. Organomet. Polym. Mater. 31, 2560–2568 (2021)

    Article  CAS  Google Scholar 

  11. Misbah, M.H., Abdelghany, A.M., El-Agawany, F.I., Rammah, Y.S., El-Mallawany, R.: On Y2O3·Li2O·Al2O3·B2O3 glasses: synthesis, structure, physical, optical characteristics and gamma-ray shielding behavior. J. Mater. Sci. Mater. Electron. (2021). https://doi.org/10.1007/s10854-021-06172-2

  12. Sglavo, V.M., Mura, E., Milanese, D., Lousteau, J.: Mechanical properties of phosphate glass optical fibers. Int. J. Appl. Glas. Sci. 5(1), 57–64 (2014)

    Article  CAS  Google Scholar 

  13. Brow, R.K.: Review: the structure of simple phosphate glasses. J. Non-Cryst. Solids. 263 & 264, 1–28 (2000)

    Article  Google Scholar 

  14. Meyer, K.: Characterisation of the structure of binary calcium ultraphosphate glasses by infrared and Raman spectroscopy. Phys. Chem. Glasses. 39, 108 (1998)

    CAS  Google Scholar 

  15. Navarro, M., Planell, J.A.: Bioactive composite based on calcium phosphate for bone regeneration. Key Eng. Mater. 441, 203–233 (2010)

    Article  CAS  Google Scholar 

  16. Prabhakar, R.L., Brocchini, S., Knowless, J.C.: Effect of glass composition on the degradation properties and ion release characteristics of phosphate glass polycaprolactone composites. Biomaterials. 26, 2209–2218 (2005)

    Article  CAS  Google Scholar 

  17. Kim, H.W., Lee, E.J., Jun, I.K., Kim, H.E., Knowles, J.C.: Degradation and drug release of phosphate glass/polycaprolactone biological composites for hard-tissue regeneration. J Biomed Mater Res B Appl Biomater. 75B, 34–41 (2005)

    Article  CAS  Google Scholar 

  18. Burnie, J., Gilchrist, T., Dutt, S.R.I., Drake, C.F., Harding, N.G.L., Malcolm, A.J.: Controlled release glasses (C.R.G.) for biomedical users. Biomaterilas. 2, 244 (1981)

    Article  CAS  Google Scholar 

  19. Ahmed, A.A., Ali, A.A., El-Fiqi, A.: Glass-forming compositions and physicochemical properties of degradable phosphate and silver-doped phosphate glasses in the P2O5-CaO-Na2O-Ag2O system. J Mater Res Technol. 8(1), 1003–1013 (2019)

    Article  CAS  Google Scholar 

  20. Sayyed, M.I., Tekin, H.O., Kılıcoglu, O., Agar, O., Zaid, M.H.M.: Shielding features of concrete types containing sepiolite mineral: comprehensive study on experimental, XCOM and MCNPX results. Results Phys. 11, 40–45 (2018). https://doi.org/10.1016/j.rinp.2018.08.029

    Article  Google Scholar 

  21. Rammah, Y.S., Sayyed, M.I., Ali, A.A., Tekin, H.O., ElMallawany, R.: Optical properties and gamma shielding features of bismuth borate glasses. Appl. Phys. A Mater. Sci. Process. 124(2018), 824–832 (2018)

    Google Scholar 

  22. Sayyed, M.I.: Investigations of gamma ray and fast neutron shielding properties of tellurite glasses with different oxide compositions. Can. J. Phys. 94(11), 1133–1137 (2016)

    Article  CAS  Google Scholar 

  23. Kavaz, E., Ekinci, N., Tekin, H.O., Sayyed, M.I., Aygün, B., Perişanoğlu, U.: Estimation of gamma radiation shielding qualification of newly developed glasses by using WinXCOM and MCNPX code. Prog. Nucl. Energy. 115, 12–20 (2019)

    Article  CAS  Google Scholar 

  24. Rammah, Y.S., Al-Buriahi, M.S., Abouhaswa, A.S.: B2O3–BaCO3–Li2O3 glass system doped with Co3O4: structure, optical, and radiation shielding properties. Phys. B Condens. Matter. 576, 411717 (2020)

    Article  CAS  Google Scholar 

  25. Rammah, Y.S., El-Agawany, F.I., Mahmoud, K.A., El-Mallawany, R., Ilik, E., Kilic, G.: FTIR, UV–Vis–NIR spectroscopy, and gamma rays shielding competence of novel ZnO-doped vanadium borophosphate glasses. J. Mater. Sci. Mater. Electron. (2020). https://doi.org/10.1007/s10854-020-03440-5

  26. Olarinoye, I.O., El-Agawany, F.I., El-Adawy, A., Yousef, E.-S., Rammah, Y.S.: Mechanical features, alpha particles, photon, proton, and neutron interaction parameters of TeO2–V2O3–MoO3 semiconductor glasses. Ceram. Int. (2020). https://doi.org/10.1016/j.ceramint.2020.06.093

  27. Rammah, Y.S., Olarinoye, I.O., El-Agawany, F.I., El-Adawy, A., Gamal, A.: El Sayed Yousef., Elastic moduli, photon, neutron, and proton shielding parameters of tellurite bismo-vanadate (TeO2–V2O5–Bi2O3) semiconductor glasses. Ceram. Int. https://doi.org/10.1016/j.ceramint.2020.07.014

  28. Elkhoshkhany, N., Syala, E., Yousef, E.: Concentration dependence of the elastic moduli, thermal properties, and non-isothermal kinetic parameters of Yb3+ doped multicomponent tellurite glass system. Results Phys. 16, 102876 (2020)

    Article  Google Scholar 

  29. RSICC Computer Code Collection. MCNPX User’s Manual Version 2.4.0. Monte Carlo N-particle transport code system for multiple and high energy applications (2002)

  30. Mann, K.S., Mann, S.S.: Py-MLBUF: Development of an online-platform for gamma-ray shielding calculations and investigations. Ann. Nucl. Energy. 150, 107845 (2021). https://doi.org/10.1016/j.anucene.2020.107845

    Article  CAS  Google Scholar 

  31. Rammah, Y.S., Sayyed, M.I., Ali, A.A., Tekin, H.O., El-Mallawany, R.: Optical properties and gamma-shielding features of bismuth borate glasses. Appl. Phys. A Mater. Sci. Process. 124, 832 (2018)

    Article  Google Scholar 

  32. Abouhaswa, A.S., Zakaly, H.M.H., Issa, S.A.M., Rashad, M., Pyshkina, M., Tekin, H.O., El-Mallawany, R., Mostafa, M.Y.A.: Synthesis, physical, optical, mechanical, and radiation attenuation properties of TiO2–Na2O–Bi2O3–B2O3 glasses. Ceram. Int. (2020). https://doi.org/10.1016/j.ceramint.2020.08.122

  33. Al-Hadeethi, Y., Sayyed, M.I., Rammah, Y.S.: Investigations of the physical, structural, optical and gamma-rays shielding features of B2O3-Bi2O3-ZnO-CaO glasses. Ceram. Int. 45, 20724–20732 (2019)

    Article  CAS  Google Scholar 

  34. Ilik, E., Kilic, G., Issever, U.G.: Synthesis of novel AgO-doped vanadium–borophosphate semiconducting glasses and investigation of their optical, structural, and thermal properties. J. Mater. Sci. Mater. Electron. 31, 8986–8995 (2020). https://doi.org/10.1007/s10854-020-03432-5

    Article  CAS  Google Scholar 

  35. Kavaz, E., El-Agawany, F.I., Tekin, H.O., Perisanoglu, U., Rammah, Y.S.: Nuclear radiation shielding using barium borosilicate glass ceramics. J. Phys. Chem. Solids. 142, 109437 (2020)

    Article  CAS  Google Scholar 

  36. Kara, U., Susoy, G., Issa, S.A.M., Elshami, W., Yorgun, N.Y., Abuzaid, M.M., Kavaz, E., Tekin, H.O.: Iron (III) oxide doped lithium borate glasses: structural and charged particles/photon shielding properties. J. Non-Cryst. Solids. 546, 120281 (2020). https://doi.org/10.1016/j.jnoncrysol.2020.120281

    Article  CAS  Google Scholar 

  37. Kara, U., Susoy, G., Issa, S.A.M., Elshami, W., Yorgun, N.Y., Abuzaid, M.M., Kavaz, E., Tekin, H.O.: Scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectroscopy and nuclear radiation shielding properties of [α-Fe+3O(OH)]-doped lithium borate glasses. Applied Physics A. 126, 506 (2020). https://doi.org/10.1007/s00339-020-03683-3

    Article  CAS  Google Scholar 

  38. Kavaz, E., Tekin, H.O., Yildiz Yorgun, N., Ozdemir, O.F., Sayyed, M.I.: Structural and nuclear radiation shielding properties of bauxite ore doped lithium borate glasses: experimental and Monte Carlo study. Radiat. Phys. Chem. 162, 187–193 (2019). https://doi.org/10.1016/j.radphyschem.2019.05.019

    Article  CAS  Google Scholar 

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Taif University Researchers Supporting Project number (TURSP-2020/84), Taif University, Taif, Saudi Arabia.

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Correspondence to Y. S. Rammah.

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Rammah, Y.S., Ahmed, E.M., Elshami, W. et al. Mechanical properties and elastic moduli, as well as gamma-ray attenuation abilities: A wide-ranging investigation into calcium/sodium/phosphate glasses. J Aust Ceram Soc 57, 1309–1319 (2021). https://doi.org/10.1007/s41779-021-00628-8

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