Abstract
The Kali River is an intermittent river in western Uttar Pradesh (U.P), which receives a huge amount of untreated wastewater containing toxic heavy metals from industrial and urban discharge. The present study aims to assess the heavy metals (Fe, Cd, Zn, Cr, and Pb) contamination in Kali River using heavy metal pollution index (HPI) during pre- and post-monsoon periods in year 2014. The assessment also involves hierarchical cluster analysis (HCA) and principal component analysis (PCA) for identification of clusters of sampling locations of similar pollution characteristics, determination of regional water quality variables and their input sources. The result indicates that the overall water quality in Kali River is severely contaminated (i.e., mean HPI >1) with respect to heavy metals concentration and could pose a likely threat to flora and fauna. The outcome of HCA classified similar water quality stations into two clusters and PCA demonstrating up to 97 and 94% of both temporal and spatial changes during pre- and post-monsoon periods, respectively.




Similar content being viewed by others
References
Aktar MW, Paramasivam M, Ganguly M, Purkait S, Sengupta D (2010) Assessment and occurrence of various heavy metals in surface water of Ganga River around Kolkata: a study for toxicity and ecological impact. Environ Monit Assess 160(4):207–213
APHA (2002) Standard methods for the examination of water and wastewater, 20th edn. American Public and Health Association, Washington DC
Bao LJ, Maruya KA, Snyder SA, Zeng EY (2012) China’s water pollution by persistent organic pollutants. Environ Poll 163:100–108
Bhargava S, Saxena U, Bhragava AK (2009) Some microbiological studies of polluted Kali River water at Meerut. Biochem Cell Arch 9:155–156
Birth G (2003) A scheme for assessing human impacts on coastal aquatic environments using sediments. In: Woodcoffe CD, Furness RA (eds) Coastal GIS, Wollongong University Papers in Center for Maritime Policy, Australia
Chabukdhara M, Nema AK (2012) Assessment of heavy metal contamination in Hindon River sediments: a chemometric and geochemical approach. Chemosphere 87:945–953
Chatterjee SK, Bhattacharjee I, Chandra G (2010) Water quality assessment near an industrial site of Damodar River. India. Environ Monit Assess 161(4):177–189
CPCB (2011) Report on Status of Quality in India. Central Pollution Control Board, Monitoring of Indian National Aquatic Resources
Danielsson A, Cato I, Carman R, Rahm L (1999) Spatial clustering of metals in the sediments of Skagerrak/Kattegat. Appl Geochem 14:689–706
Dhakyanaika K, Kumara P (2010) Effects of pollution in River Krishni on hand pump water quality. J Engg Sci Tech Review 3(1):14–22
Facchinelli A, Sacchi E, Mallen L (2001) Multivariate statistical and GIS-based approach to identify heavy metal sources in soils. Environ Poll 114:313–324
Filgueiras AV, Lavilla I, Bendicho C (2004) Evaluation of distribution, mobility and binding behaviour of heavy metals in surficial sediments of Louro River (Galicia, Spain) using chemometric analysis: a case study. Sci Tot Environ 330:115–129
Gao H, Lv C, Song Y, Zhang Y, Zheng L, Wen Y, Peng J, Yu H (2015) Chemometrics data of water quality and environmental heterogeneity analysis in Pu River, China. Environ Earth Sci 73:5119–5129
Giri S, Singh AK (2014) Risk assessment, statistical source identification and seasonal fluctuation of dissolved metals in the Subarnarekha River, India. J Hazard Mat 265:305–314
Helena B, Pardo R, Vega M, Barrado E, Fernandez JM, Fernandez L (2000) Temporal evolution of groundwater composition in an alluvial aquifer (Pisuerga River, Spain) by principal component analysis. Water Res 34:807–816
Herojeet R, Rishi MS, Lata R, Sharma R (2015) Application of environmetrics statistical models and water quality index for groundwater quality characterization of alluvial aquifer of Nalagarh Valley. Sustainability Water Resources Management, Himachal Pradesh. doi:10.1007/s40899-015-0039-y
Huang W, Campredon R, Abrao JJ, Bernat M, Latouche C (1994) Variation of heavy metals in recent sediments from Piratininga Lagoon: interpretation of geochemical data with the aid of multivariate analysis. Environ Geo 23:241–247
Indian Standard Specification for Drinking Water, Bureau of Indian Standards, BIS: 10500 (1991) Bureau of Indian Standards Manak Bhawan, New Delhi
Jain CK, Sharma MK (2006) Heavy metal transport in the Hindon river basin, India. Environ Monit Assess 112(3):255–270
Jain CK, Bhatia KKS, Seth SM (1997) Assessment of point and non-point sources of pollution using a chemical mass balance approach. J Hydro Sci 43(3):379–390
Kalin M, Cao Y, Smith M, Olaveson M (2000) Development of phytoplankton community in a pit-lake in relation to water quality changes. Water Res 35(13):3215–3225
Kannel PR, Lee S, Kanel SR, Khan SP (2007) Chemometric application in classification and assessment of monitoring locations of an urban river system. Anal Chim Acta 582:390–399
Kaushik A, Kansal A, Meena S, Kumari S, Kaushik CP (2009) Heavy metal contamination of river Yamuna, Haryana, India: assessment by metal enrichment factor of the sediments. J Hazard Mat 164:265–270
Konhauser KO, Powell MA, Fyfe WS, Longstaffe FJ, Tripathy S (1997) Trace element chemistry of major rivers in Orissa State, India. Environ Geo 29(2):132–141
Kumar A, Mishra S, Kumar A, Singhal S (2017) Environmental quantification of soil elements in the catchment of hydroelectric reservoirs in India. Human Ecol Risk Assess Int J. doi:10.1080/10807039.2017.1309266
Loska K, Wiechula D (2003) Application of principal component analysis for the estimation of source heavy metal contamination in surface sediments from Rybnik Reservoir. Chemosphere 51:723–733
Mishra S, Kumar A, Shukla P (2015a) Study of water quality in Hindon River using pollution index and environmetrics, India. Desal Water Treat 56:1–10
Mishra S, Kumar A, Yadav S, Singhal MK (2015b) Assessment of heavy metal contamination in Kali river, Uttar Pradesh, India. J Appl Nat Sci 7(2):1016–1020
Moha SV, Nithila P, Reddy SJ (1996) Estimation of heavy metal in drinking water and development of heavy metal pollution index. J Environ Sci Health 31(2):283–289
Nayak BB, Panda UC, Panigrahy PK, Acharya BC (2001) Dynamics of heavy metals in Dhamara Estuary of Orissa state in India. Chem Environ Res 10(4):203–218
Ouyang Y (2005) Evaluation of river water quality monitoring stations by principal component analysis. Water Res 39:2621–2635
Prasad MBK, Ramanathan AL, Shrivastav SK, Anshumali Rajinder S (2006) Metal fractionation studies in surfacial and core sediments in the Achankovil river basin in India. Environ Monit Assess 121(1–3):77–102
Reza R, Singh G (2010) Heavy metal contamination and its indexing approach for river water. Int J Environ Sci Tech 7(4):785–792
Selle B, Schwientek M, Lischeid G (2013) Understanding processes governing water quality in catchments using principal component scores. J Hydrol 486:31–38
Senapati NK, Sahu KC (1996) Heavy metal distribution in Subarnarekha river east coast of India. Ind J Marine Sci 25(2):109–114
Sharma S (1996) Applied Multivariate Techniques. John Wiley and Sons, Inc., New York
Sharma MK, Jain CK, Singhal DC, Choubey VK (2009) Kinetics of sorption of lead on bed sediments of River Hindon, India. Environ Monit Assess 157:11–21
Singh KP, Malik A, Mohan D, Sinha S (2004) Multivariate statistical techniques for the evaluation of spatial and temporal variations in water quality of Gomti River (India)—a case study. Water Res 38:3980–3992
Singh KP, Malik A, Sinha S (2005) Water quality assessment and apportionment of pollution sources of Gomti River (India) using multivariate statistical techniques: a case study. Anal Chim Acta 538:355
Sundaray SK (2009) Application of multivariate statistical techniques in hydro-geochemical studies-a case study: Brahmani–Koel River (India). Environ Monit Assess 164(4):297–310
Ting H, Liangen Z, Chuanying ZYZ, Jing L (2012) Water quality comprehensive index method of Eltrix River in Xin Jiang Province using SPSS. Proc Earth Planet Sci 5:314–321
Vega M, Pardo R, Barrado E, Deban L (1998) Assessment of seasonal and polluting effects on the quality of river water by exploratory data analysis. Water Res 32(12):3581–3592
Vink R, Behrendt H, Salomons W (1999) Development of the heavy metal pollution trends in several European Rivers: an analysis of point and diffuse sources. Water Sci Tech 39(12):215–223
Wunderlin DA, Diaz M, Ame MMV, Pesce SF, Hued AC, Bistoni M (2001) Pattern recognition techniques for the evaluation of spatial and temporal variations in water quality. A case study: Suquia River basin (Cordoba-Argentina). Water Res 35:2881–2894
Yalcin MG, Narin I, Soylak M (2008) Multivariate analysis of heavy metal contents of sediments from Gumusler creek, Nigde, Turkey. Environ Geol 54:1155–1163
Yi Y, Yang Z, Zhang S (2011) Ecological risk assessment of heavy metals in sediment and human health risk assessment of heavy metals in fishes in the middle and lower reaches of the Yangtze River basin. Environ Poll 159:2575–2585
Zarei H, Bilondi MP (2013) Factor analysis of chemical composition in the Karoon River basin, southwest of Iran. Appl Water Sci 3:753–761
Zhao Y, Xia XH, Yang ZF, Wang F (2012) Assessment of water quality in Baiyangdian Lake using multivariate statistical techniques. Proc Environ Sci 13:1213–1226
Acknowledgements
The authors (SM and SY) are thankful to MHRD, Government of India for financial assistance in the form of academic scholarship during his Master of Technology programme in Environmental Management of Rivers and Lakes. The authors would like to deeply acknowledge the editor and reviewers for providing careful and useful suggestions to improve the quality of paper.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mishra, S., Kumar, A., Yadav, S. et al. Assessment of heavy metal contamination in water of Kali River using principle component and cluster analysis, India. Sustain. Water Resour. Manag. 4, 573–581 (2018). https://doi.org/10.1007/s40899-017-0141-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40899-017-0141-4