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Microstructure and Corrosion Characteristics of In Situ Aluminum Diboride Metal Matrix Composites

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Abstract

The present work relates to the preparation of Al–AlB2 in situ composite and investigates the characteristics of corrosion of in situ composites in sodium chloride media. Composites containing matrix alloy, XAlB2 (X—1, 3, and 5 wt%), were prepared by an in situ technique involving the chemical reaction between base matrix and halide salt KBF4. To know about the uniform distribution of AlB2 dispersoid in the Al6061 base matrix, microstructural characterization was carried out using SEM. Potentiodynamic Tafel polarization curves have fetched some of the electrochemical parameters. Outcome of the research concludes that higher corrosion resistance was offered by composites compared to base matrix in the selected corrosion media.

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References

  1. Ghomashchi MR, Vikhrov A (2000) Squeeze casting: an overview. J Mater Process Technol 101:1–9

    Article  Google Scholar 

  2. Dayanand Samuel, Satish Babu B, Auradi V (2018) Experimental investigation on micro structural and dry sliding wear behavior of Al-AlB2 metal matrix composites. Material Today 5:22536–22542

    Google Scholar 

  3. Murthy BS, Kori SA, Venkateshvaralu K, Bhat RR, Charoborthy M (1999) Manufacture of Al-Ti-B master alloy by the reaction of complex halide salt with molten aluminium. J Mater Proces Technol 89:152–158

    Article  Google Scholar 

  4. Uju WA, Oguocha INA (2009) Thermal cycling behaviour of stir cast Al-Mg alloy reinforced with fly ash. Mater Sci Eng, A 526:100–105

    Article  Google Scholar 

  5. Seah KHW, Hemanth J, Sharma SC (2003) Mechanical properties of aluminum quartz particulate composites cast using metallic and non-metallic chills. Mater Des 24:1987–1993

    Article  Google Scholar 

  6. Ramesh CS, Anwar Khan AR, Ravikumar N, Savanprabhu P (2005) Prediction of wear coefficient of Al6061-TiO2 composites. Wear 259:602–608

    Article  CAS  Google Scholar 

  7. Ashok Kumar B, Murugan N (2012) Metallurgical and mechanical characterization of stir cast AA6061-T6-AlNp composite. Mater Des 40:52–58

    Article  CAS  Google Scholar 

  8. Ramesh CS, Keshavamurthy R (2011) Slurry erosive wear behavior of Ni-P coated Si3N4 reinforced Al6061 composites. Mater Des 32:1833–1843

    Article  CAS  Google Scholar 

  9. Gopalakrishnan S, Murugan N (2011) Prediction of tensile strength of friction stir welded aluminum matrix TiCp particulate reinforced composite. Mater Des 32:462–467

    Article  CAS  Google Scholar 

  10. Kalaiselvan K, Murugan N, Parameswaran S (2011) Production and characterization of AA6061-B4C stir cast composite. Mater Des 32:4004–4009

    Article  CAS  Google Scholar 

  11. Vijay SJ, Murugan N (2010) Influence of tool pin profile on the metallurgical and mechanical properties of friction stir welded Al–10 wt% TiB2 metal matrix composite. Mater Des 31:3585–3589

    Article  CAS  Google Scholar 

  12. Naveen Kumar G, Narayanasamy R, Natarajan S, Kumaresh Babu SP, Sivaprasad K, Sivasankaran S (2010) Dry sliding wear behaviour of AA 6351-ZrB2 in situ composite at room temperature. Mater Des 31:1526–1532

    Article  CAS  Google Scholar 

  13. Feng CF, Froyen L (2000) Microstructures of in situ Al/TiB2 MMCs prepared by a casting route. J Mater Sci 35:837–850

    Article  CAS  Google Scholar 

  14. Birol Yucel (2009) Production of Al-B alloy by heating Al/KBF4 powder blends. J Alloys Compds 481:195–198

    Article  CAS  Google Scholar 

  15. Boppanna S, Channakeshavalu K (2009) Preparation of Al-TiC metal matrix composites. J Miner Mater Charact Eng 8(6):563–568

    Google Scholar 

  16. Wang X (2005) The formation of AlB2 in an Al- B master alloy. J Alloys Compd. 403:283–287

    Article  CAS  Google Scholar 

  17. Kayikcia R, Savas O, Koksala S, Demira A (2014) The effect reinforcement ratio on the wear behaviour of AlB2 flake reinforced metal matrix composites. Acta phycica Polonic A 125(2)

    Article  Google Scholar 

  18. Draguţ DV, Uşurelu E (2011) Characterization of in situ AA 6060/AlB2 metal matrix composite. U.P.B. Sci Bull. Ser B 73

  19. Orbán R, Cora I, Dódony I (2012) Preparation and characterization of an aluminum/aluminum diboride composite. In: ECCM15-15th European conference on composite materials, Venice, Italy, 24–28 June 2012

  20. Kubota M (2004) Properties of Al-AlB2 materials processed by mechanical alloying and spark plasma sintering proceedings. In: 9th international conference on aluminium alloys (2004) Edited by J.F. Nie, A.J. Morton and B.C. Muddle Institute of Materials Engineering Australasia Ltd

  21. Prasad KVS, Murthy BS, Pramanik P, Mukunda PG, Chakramurthy M (1996) Reaction fluorides salts with aluminuim. Mater Sci Technol 12:766–770

    Article  CAS  Google Scholar 

  22. Koksal S, Ficici F, Kayikci R, Savas O (2012) Experimental investigation of dry sliding wear behaviour of insitu AlB2/Al composite based on taguchi’s method. Mater Des 42:124–230

    Article  CAS  Google Scholar 

  23. Maldovan P, Dragut DV (2015) In-situ productions of Al/AlB2 composite by metal salt reaction, www.researchgate.net.publication. https://doi.org/10.13140/rg2.1.1339.5367. May 2015

  24. Huda MD, Hashmi MS, El-Baradie MA (1995) MMCs: materials, manufacturing and mechanical properties. In: Key engineering materials, vol 104. Trans Tech Publications, pp. 37–64)

  25. Sherif ESM, Almajid AA, Latif FH, Junaedi H (2011) Effects of graphite on the corrosion behavior of aluminum-graphite composite in sodium chloride solutions. Int J Electrochem Sci 6:1085–1099

    CAS  Google Scholar 

  26. Abdul-Jameel HP, Nagaswararpa P, Krupakara V, ShashiShekar TR (2009) Evaluation of corrosion rate of Al 6061-Zirconia metal matrix composites in sea water. Int J Ocean Oceanogr 3(1):37–42

    Google Scholar 

  27. Alaneme KK, Bodunrin MO (2011) Corrosion behavior of alumina reinforced metal matrix composites. JMMCE 10(12):1153–1165

    Article  Google Scholar 

  28. Achutha Kini U, Shetty Prakash, Divakara Shetty S, Arun Isloor M (2011) Corrosion inhibition of 6061 aluminum alloy/SiC composite in HCl acid medium using 3-Chloro-I-Benzothiophene-2-carbohydrazide. Indian J Chem Technol 18:439–445

    Google Scholar 

  29. Seah KHW, Krishna M, Vijayalakshmi VT, Uchil J (2002) Corrosion behavior of garnet particulate reinforced LM 13 alloy MMCs. Corros Sci 44:917–925

    Article  CAS  Google Scholar 

  30. Zuhair GM, Al-qutub AM (2002) Corrosion behavior of powder metallurgy aluminum alloy 6061/Al2O3 metal matrix composites. In: The 6th Saudi Engg conference, vol 5, pp 271–281

  31. Pruthviraj RD, Krupakara PV, Parashuram BS (2006) Effect of reinforcement content on the corrosion properties of aluminium 7075/SiC composites in equimolar solution of sodium hydroxide and sodium chloride solution. Bull Electrochem 22(6):281–284

    CAS  Google Scholar 

  32. Krupakara PV (2013) Corrosion characterization of Al6061/red mud metal matrix composites. Portugaliae Electro chimica Acta 31(3):157–164

    Article  Google Scholar 

  33. Auradi V, Kori SA (2008) Influence of reaction temperature for the manufacturing of Al-3Ti and Al-3B master alloys. J Alloys Compds 453:147–156

    Article  CAS  Google Scholar 

  34. Tjong SC, Wang GS, Geng L, Mai YW (2004) Cyclic deformation behaviour of insitu aluminium matrix composite of the system Al-Al3Ti-TiB2-Al2O3. Compos Sci Technol 64:1971–1980

    Article  CAS  Google Scholar 

  35. Karantzails AE, Lekatou A, Gerogties M, Poulas V, Mavros H (2011) Casting based production of Al-TiC-AlB2 composite material through the use of KBF4 salt. J Mater Eng Perform 20(2):198–202

    Article  Google Scholar 

  36. Ficici F, Koksal S, Kayikci R, Savas O (2011) Investigation of unlubricated sliding wear behaviours of in situ AlB2/Al metal matrix composite. Adv Compos Lett 20(4):096369351102000404

    Article  Google Scholar 

  37. Savaş Omar, Koksal Sakip, Kayikci Ramazan (2012) Application of taguchi method to investigate the effect of some factors on in situ formed flake structures of Al/AlB2 composite. Adv Compos Lett 21(2):49

    Article  Google Scholar 

  38. Draught DV, Maldovan P, Butu M, Usurelu E (2011) Characterization of in situ AA6060/AlB2 metal matrix composite. UPB Sci Bull Ser B 73:4

    Google Scholar 

  39. Mirkovic D, Irkovic D, Grobner J, Schmid-Fetzer R, Fabrichnaya O, Lukas HL (2004) Experimental study and thermodynamic re-assessment of the Al-B system. J Alloys Compds 384:168–174

    Article  CAS  Google Scholar 

  40. Kayikcia R, Sava B, Koksala S, Demira A (2013) The effect of reinforcement ratio on the wear behaviour of AlB2 flake reinforced MMCS. In: Proceedings of the 3rd international congress apmas, April 24–28: Antalya, Turkey

  41. Jackson MJ, Graham ID (1994) Mechanical stirring of Al-B alloys. J Mater Sci Lett 13:754–756

    Article  CAS  Google Scholar 

  42. Tjong SC, Ma ZY (2000) Microstructural and mechanical characteristics of in situ metal matrix composites. Mater Sci Eng, R 29:49–113

    Article  Google Scholar 

  43. Xiao-ming W (2005) The formation of AlB2 in an Al-B master alloy. J Alloys Compds 403:283–287

    Article  Google Scholar 

  44. Wang QL, Zhao HS, Li ZG, Shen L, Zhao JZ (2013) Production of Al-B master alloys by mixing KBF4 salt into molten aluminum Trans. Nonferrous Met Soc China 23:294–300

    Article  CAS  Google Scholar 

  45. Elicicek H, Savas O, Ayadin Z, Ozdemir O K, Kayaki R (2016) Corrosion behavior of in situ AlB2/Al-Cu metal matrix composites. Acta Physica polonica A 129(4)

  46. Shanbhag VV, Yalamoori NN, Yalamoori S, Kartikeyan S, Ramanujam R (2014) Fabrication surface morphology and corrosion investigation of Al7075-Al2O3 matrix composites in sea water and industrial environment. Proceedia Eng 97:607–613

    Article  CAS  Google Scholar 

  47. Bienias J, Walczak M, Surowska B, Sobczak J (2003) Microstructure and corrosion behavior of aluminum fly ash composites. J Optoelectron Adv Mater 5(2):493–502

    CAS  Google Scholar 

  48. Anandmurthy HC, Singh SK (2015) Influence of TiC particulate reinforcement on the corrosion behavior of Al6061 metal matrix composites. Adv Mater Lett 6(7):633–640

    Article  Google Scholar 

  49. Abbass MK, Hassan KS, Alwan AS (2015) Study of corrosion resistance of aluminum alloy 6061/SiC composites in 35% NaCl solution. Int J Mater Mech Manuf 3(1):31–35

    CAS  Google Scholar 

  50. Chunlin HE, Changsheng LIU, Li Fengquin (2002) Corrosion behavior and protection efficiency of 2024 Al and SiCp/2024Al metal matrix composites. J Mater Sci Tecnol 18(4):351–353

    Google Scholar 

  51. Ashok SD, Mamatha GP, Venkatesh TV, Pruthvaraj RD (2015) Corrosion characterization of aluminum 7075/silicon carbide metal matrix composite. Int J Adv Res Chem Sci 2(1):24–29

    Google Scholar 

  52. Ramchandra M, Dilip Kumar G, Rashmi R (2016) Evaluation of corrosion property of aluminum zirconium dioxide (Al-ZrO2) nano composites. Int J Chem Mol Nucl Mater Metall Eng 10(10):1321–1326

    Google Scholar 

  53. Han YM, Chen X (2015) Electrochemical behavior of Al-B4C metal matrix composites in NaCl solution. Materials 8(9):6455–6470

    Article  CAS  Google Scholar 

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Acknowledgements

The authors wish to express their profound sense of gratitude to the East West Institute of Technology, Bengaluru for the support and facility provided to carry out the corrosion studies.

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Correspondence to Samuel Dayanand or Satish Babu Boppana.

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Dayanand, S., Boppana, S.B., Hemanth, J. et al. Microstructure and Corrosion Characteristics of In Situ Aluminum Diboride Metal Matrix Composites. J Bio Tribo Corros 5, 60 (2019). https://doi.org/10.1007/s40735-019-0250-8

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  • DOI: https://doi.org/10.1007/s40735-019-0250-8

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