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Synthesis, structures and properties of two complexes based on benzimidazole or benzothiazole ligand

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Abstract

Two complexes, Co(Hbim)2(NCS)2(Hbim=benzimidazole)(1) and [Cu(Hbzt)SCN] n (Hbzt=benzothiazole) (2) were synthesized by the same synthesis method and characterized by elemental analysis, infrared spectroscopy(IR), thermogravimetric analysis(TGA), X-ray powder diffraction(XRPD) and single-crystal X-ray diffraction. The results from the single-crystal X-ray diffraction indicate that complex 1 is zero-dimensional(0D) framework and complex 2 is 2-dimensional(2D) framework. In complex 2, the 3-dimensional(3D) supermolecular architecture was built up by means of π-π stacking interaction, and two helical chains existed in its structure. The luminescence properties and the magnetic properties of the two complexes were investigated.

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References

  1. Cheng J. W., Zheng S. T., Yang G. Y., Inorg. Chem., 2007, 46, 10261

    Article  CAS  Google Scholar 

  2. Gong Y., Tang W., Hou W. B., Zha Z. Y., Hu C. W., Inorg. Chem., 2006, 45, 4987

    Article  CAS  Google Scholar 

  3. Park K. S., Ni Z., Coté A. P., Choi J. Y., Huang R. D., Uribe-Romo F. J., Chae H. K., Keeffe M. O’., Yaghi O. M., PANS, 2006, 103, 10186

    Article  CAS  Google Scholar 

  4. Tu T., Assenmacher W., Peterlik H., Weisbarth R., Nieger M., Dötz K. H., Angew. Chem. Int. Ed., 2007, 46, 6368

    Article  CAS  Google Scholar 

  5. Chuprakov S., Hwang F. W., Gevorgyan V., Angew. Chem., 2007, 119, 4841

    Article  Google Scholar 

  6. Lu H. J., Li X. G., Wang S. R., Gao W. Z., Wang S. S., Chem. Res. Chinese Universities, 2012, 28(2), 313

    CAS  Google Scholar 

  7. Li C. J., Feng Z. J., Zhao X. J., Wang S. N., Dou J. M., Chem. Res. Chinese Universities, 2013, 29(2), 414

    Article  CAS  Google Scholar 

  8. Su C. Y., Goforth A. M., Smith M. D., Loye H. C., Inorg. Chem., 2003, 42, 5685

    Article  CAS  Google Scholar 

  9. Matthews C. J., Clegg W., Heath S. L., Martin N. C., Stuart H. M. N., Lockhart J. C., Inorg. Chem., 1998, 37, 199

    Article  CAS  Google Scholar 

  10. Rajesh, Mathur P., Polyhedron, 1998, 17, 2607

    Article  CAS  Google Scholar 

  11. Quintal S., Matos J., Fonseca I., Félix V., Drew M. G. B., Trindade N., Meireles M., Calhorda M. J., Inorg. Chem. Acta, 2008, 361, 1584

    Article  CAS  Google Scholar 

  12. Yang X. P., Jones R. A., Lai R. J., Waheed A., Oye M. M., Holmes A. L., Polyhedron, 2006, 25, 881

    Article  CAS  Google Scholar 

  13. González-Álvarez M., Alzuet G., Borrás J., Agudo L. C., García-Granda S., Montejo-Bernardo J. M., Inorg. Chem., 2005, 44, 9424

    Article  CAS  Google Scholar 

  14. Tzanopoulou S., Pirmettis I. C., Patsis G., Raptopoulou C., Terzis A., Papadopoulos M., Pelecanou M., Inorg. Chem., 2006, 45, 902

    Article  CAS  Google Scholar 

  15. Toth A., Floriani C., Chiesi-Villa A., Guastinil C., Inorg. Chem., 1987, 26, 3897

    Article  CAS  Google Scholar 

  16. Yen S. K., Koh L. L., Hahn F. E., Huynh H. V., Andy H. T. S., Organometallics, 2006, 25, 5105

    Article  CAS  Google Scholar 

  17. Huynh H. V., Meier N., Pape T., Ekkehardt H. F., Organometallics, 2006, 25, 3012

    Article  CAS  Google Scholar 

  18. Huang X. Y., Meng X. G., Zhang Y., Wang L., Liu C. L., Chem. J. Chinese Universities, 2012, 33(6), 1151

    CAS  Google Scholar 

  19. Chen Q., Chang Z., Song W. C., Song H., Song H. B., Hu T. L., Bu X. H., Angew. Chem. Int. Ed., 2013, 52, 11550

    Article  CAS  Google Scholar 

  20. Sielisch T., Cowie M., Organometallics, 1988, 7, 707

    Article  CAS  Google Scholar 

  21. Raper E. S., Coord. Chem. Rev., 1997, 165, 475

    Article  CAS  Google Scholar 

  22. Ballester L., Coronado E., Gutierrez A., Mange A., Perpifitin M. F., Pinilla E., Rico T., Inorg. Chem., 1992, 31, 2053

    Article  CAS  Google Scholar 

  23. Colacio E., Kivekãs R., Lloret F., Sunberg M., Inorg. Chem., 2002, 41, 5141

    Article  CAS  Google Scholar 

  24. Chesnut D. J., Kusnetzow A., Birge R., Zubieta J., Inorg. Chem., 1999, 38, 5484

    Article  CAS  Google Scholar 

  25. Li C. X., Zhang G. H., Shih H. H., Jiang X. Q., Sun P., Pan Y., Cheng C. H., J. Organomet. Chem., 2009, 694, 2415

    Article  CAS  Google Scholar 

  26. Weaver J. A., Hxmbright P., Talbeizt P. T., Kaiyg E., Thorpe A. N., Inorg. Chem., 1970, 9, 268

    Article  CAS  Google Scholar 

  27. Tong Y. P., Zheng S. L., Chen X. M., Inorg. Chem., 2005, 44, 4270

    Article  CAS  Google Scholar 

  28. Shavaleev N. M., Scopelliti R., Gumy F., Bunzli J. C. G., Inorg. Chem., 2009, 48, 6178

    Article  CAS  Google Scholar 

  29. Payra P., Hung S. C., Kwok W. H., Johnston D., Gallucci J., Chan M. K., Inorg. Chem., 2001, 40, 4036

    Article  CAS  Google Scholar 

  30. Lescop C., Belorizky E., Luneau D., Rey P., Inorg. Chem., 2002, 41, 3375

    Article  CAS  Google Scholar 

  31. Casella L., Carugo O., Gullotti M., Garofani S., Zanello P., Inorg. Chem., 1993, 32, 2056

    Article  CAS  Google Scholar 

  32. Arjmand F., Mohani B., Ahmad S., Eur. J. Med. Chem., 2005, 40, 1103

    Article  CAS  Google Scholar 

  33. Mohapatra S. C., Tehlan S., Hundal M. S., Mathur P., Inorg. Chem. Acta, 2008, 361, 1897

    Article  CAS  Google Scholar 

  34. Tarte N. H., Woo S. I., Cui L. Q., Gong Y. D., Hwang Y. H., J. Organomet. Chem., 2008, 693, 729

    Article  CAS  Google Scholar 

  35. Li Y. W., Li J. R., Wang L. F., Zhou B. Y., Chen Q., Bu X. H., J. Mater. Chem. A, 2013, 1, 495

    Article  CAS  Google Scholar 

  36. Zhong C. F., Guo R. F., Wu Q., Zhang H. L., React. Funct. Polym., 2007, 67, 408

    Article  CAS  Google Scholar 

  37. Sheldrick G. M., SMART and SAINT Software Package, Siemens Analytical X-Ray Instruments Inc., Madison, WI, 1996

    Google Scholar 

  38. Sheldrick G. M., SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Göttingen, 1997

    Google Scholar 

  39. Wang X. L., Hu H. L., Tian A. X., Lin H. Y., Li J., Inorg. Chem., 2010, 49, 10299

    Article  CAS  Google Scholar 

  40. Mandal T. N., Roy S., Barik A. K., Gupta S., Butcher R. J., Kar S. K., Inorg. Chem. Acta, 2009, 362, 1315

    Article  CAS  Google Scholar 

  41. Gao H. L., Yi L., Zhao B., Zhao X. Q., Cheng P., Liao D. Z., Yan S. P., Inorg. Chem., 2006, 45, 5980

    Article  CAS  Google Scholar 

  42. Wang X. W., Chen F. P., Chen L., Chen J. Z., Jiang W. J., Cai T. J., Deng Q., J. Mol. Struct., 2007, 842, 75

    Article  CAS  Google Scholar 

  43. Xia C. K., Lu C. Z., Zhang Q. Z., He X., Zhang J. J., Wu D. M., Cryst. Growth Des., 2005, 5, 1569

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Key Laboratory of Cluster Science, Ministry of Education, School of Chemistry, Beijing Institute of Technology, Beijing, 100081, P. R. China

    Zhongqiang Zhang, Di Di, Qinlei Zhu, Yanqing Xu & Rudan Huang

  2. Department of Applied Chemistry, Hengshui University, Hengshui, 053000, P. R. China

    Zhongqiang Zhang, Jingshuo Zhai & Lili Wu

Authors
  1. Zhongqiang Zhang
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  2. Di Di
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  3. Jingshuo Zhai
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  4. Lili Wu
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  5. Qinlei Zhu
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  6. Yanqing Xu
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  7. Rudan Huang
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Corresponding author

Correspondence to Rudan Huang.

Additional information

Supported by the National Natural Science Foundation of China(Nos.20971014, 21271024), the Natural Science Foundation of Beijing City, China(No.2112037) and the Science and Technology Supported Planning Project of Hebei Province, China(No. 12215117D).

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Zhang, Z., Di, D., Zhai, J. et al. Synthesis, structures and properties of two complexes based on benzimidazole or benzothiazole ligand. Chem. Res. Chin. Univ. 30, 185–189 (2014). https://doi.org/10.1007/s40242-014-3434-2

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  • DOI: https://doi.org/10.1007/s40242-014-3434-2

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