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Preparation of activated carbons from bio-waste: effect of surface functional groups on methylene blue adsorption

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Abstract

Low-cost activated carbons were prepared by physical activation of bio-waste rice husk. Various physicochemical characterization techniques confirmed the high surface area and oxygen functional groups on the surface. It has been confirmed that activation under humidified carbon dioxide followed by ozonation resulted the highest number of surface functional groups on activated carbon. Nitrogen adsorption–desorption isotherms confirmed the highest surface area (417 m2/g), whereas elemental analysis ensured the increasing oxygen content after activation. Temperature-programmed decomposition quantified these surface oxygen functional groups, and it was concluded that ozonation increased both acidic and basic groups. The developed activated carbons were tested during the removal of a model dye methylene blue from aqueous medium in the concentration range 10–30 mg/L. Typical results indicated that adsorption studies are consistent with the Langmuir isotherm model with maximum monolayer adsorption capacity of 28.5 mg/g, and the dimensionless separation factor (R L) values between 0.006 and 0.030 confirmed a favorable adsorption. Methylene blue adsorption followed pseudo-second order kinetics indicating MB was adsorbed onto the surface via chemical interaction.

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References

  • Ahmad T, Danish M, Rafatullah M, Ghazali A, Sulaiman O, Hashim R, Ibrahim M (2012) The use of date palm as a potential adsorbent for wastewater treatment: a review. Environ Sci Pollut Res 19(5):1464–1484

    Article  CAS  Google Scholar 

  • Al-Degs Y, Khraisheh MAM, Allen SJ, Ahmad MN (2000) Effect of carbon surface chemistry on the removal of reactive dyes from textile effluent. Water Res 34(3):927–935

    Article  CAS  Google Scholar 

  • Attia AA, Girgis BS, Fathy NA (2008) Removal of methylene blue by carbons derived from peach stones by `H3PO4 activation: batch and column studies. Dyes Pigments 76:282–289

    Article  Google Scholar 

  • Ben Mansour H, Houas I, Montassar F, Ghedira K, Barillier D, Mosrati R, Chekir-Ghedira L (2012) Alteration of in vitro and acute in vivo toxicity of textile dyeing wastewater after chemical and biological remediation. Environ Sci Pollut Res 19(7):2634–2643

    Article  CAS  Google Scholar 

  • Benaddi H, Bandosz TJ, Jagiello J, Schwarz JA, Rouzaud JN, Legras D, Béguin F (2000) Surface functionality and porosity of activated carbons obtained from chemical activation of wood. Carbon 38(5):669–674

    Article  CAS  Google Scholar 

  • Chakraborty S, Basu JK, De S, DasGupta S (2006) Adsorption of reactive dyes from a textile effluent using sawdust as the adsorbent. Ind Eng Chem Res 45:7363

    Article  CAS  Google Scholar 

  • Chowdhury S, Mishra R, Saha P, Kushwaha P (2011) Adsorption thermodynamics, kinetics and isosteric heat of adsorption of malachite green onto chemically modified rice husk. Desalination 265:159–168

    Article  CAS  Google Scholar 

  • Figueiredo JL, Pereira MFR, Freitas MMA, Orfao JJM (1999) Modification of the surface chemistry of activated carbons. Carbon 37:1379–1389

    Article  CAS  Google Scholar 

  • Franca AS, Oliveira LS, Ferreira ME (2009) Kinetics and equilibrium studies of methylene blue adsorption by spent coffee grounds. Desalination 249:267–272

    Article  CAS  Google Scholar 

  • Geethakarthi A, Phanikumar BR (2011) Adsorption of reactive dyes from aqueous solutions by tannery sludge developed activated carbon: kinetic and equilibrium studies. Int J Environ Sci Technol 8(3):561–570

    Article  CAS  Google Scholar 

  • Ghezzar MR, Belhadj M, Abdelmalek F, Rais A, Addou A (2008) Non-thermal plasma degradation of wastewater in presence of titanium oxide by gliding arc discharge. Int J Environ Waste Manag 2:458–470

    Article  CAS  Google Scholar 

  • Gupta VK, Rastogi A (2009) Biosorption of hexavalent chromium by raw and acid-treated green alga Oedogonium hatei from aqueous solutions. J Hazard Mater 163(1):396–402

    Article  CAS  Google Scholar 

  • Gupta VK, Mohan D, Sharma S, Sharma M (2000) Removal of basic dyes (rhodamine B and methylene blue) from aqueous solutions using bagasse fly ash. Sep Sci Technol 35(13):2097–2113

    Article  CAS  Google Scholar 

  • Gupta VK, Mittal A, Gajbe V (2005) Adsorption and desorption studies of a water soluble dye, Quinoline Yellow, using waste materials. J Colloid Interface Sci 284(1):89–98

    Article  CAS  Google Scholar 

  • Gupta VK, Mittal A, Jain R, Mathur M, Sikarwar S (2006) Adsorption of Safranin-T from wastewater using waste materials—activated carbon and activated rice husks. J Colloid Interface Sci 303(1):80–86

    Article  CAS  Google Scholar 

  • Gupta VK, Jain R, Mittal A, Saleh TA, Nayak A, Agarwal S, Sikarwar S (2012) Photo-catalytic degradation of toxic dye amaranth on TiO2/UV in aqueous suspensions. Mater Sci Eng C 32(1):12–17

    Article  CAS  Google Scholar 

  • Hameed BH, Ahmad AA (2009) Batch adsorption of methylene blue from aqueous solution by garlic peel, an agricultural waste biomass. J Hazard Mater 164(3):870–875

    Article  CAS  Google Scholar 

  • Hameed BH, Lee TW (2009) Degradation of malachite green in aqueous solution by Fenton process. J Hazard Mater 164(2–3):468–472

    Article  CAS  Google Scholar 

  • Jain AK, Gupta VK, Bhatnagar A, Suhas (2003) A comparative study of adsorbents prepared from industrial wastes for removal of dyes. Sep Sci Technol 38:120016585

    Article  Google Scholar 

  • Jain AK, Gupta VK, Jain S, Suhas (2004) Removal of chlorophenols using industrial wastes. Environ Sci Technol 38(4):1195–1200

    Article  CAS  Google Scholar 

  • Hayashi JI, Horikawa T, Takeda I, Muroyama K, Nasir AF (2002) Preparing activated carbon from various nutshells by chemical activation with K2CO3. Carbon 40:2381–2386

    Article  CAS  Google Scholar 

  • Juang RS, Wu FC, Tseng RL (1997) The ability of activated clay for the adsorption of dyes from aqueous solutions. Environ Technol 18:525–531

    Article  CAS  Google Scholar 

  • Kalderis D, Bethanis S, Paraskeva P, Diamadopoulos E (2008) Production of activated carbon from bagasse and rice husk by a single-stage chemical activation method at low retention times. Bioresour Technol 99(15):6809–6816

    Article  CAS  Google Scholar 

  • Kannan N, Sundaram MM (2001) Kinetics and mechanism of removal of methylene blue by adsorption on various carbons: a comparative study. Dyes Pigments 51:25–40

    Article  CAS  Google Scholar 

  • Karagöz S, Tay T, Ucar S, Erdem M (2008) Activated carbons from waste biomass by sulfuric acid activation and their use on methylene blue adsorption. Bioresour Technol 99:6214–6222

    Article  Google Scholar 

  • Karuppiah J, Linga Reddy E, Manoj Kumar Reddy P, Ramaraju B, Subrahmanyam C (2013) Catalytic nonthermal plasma reactor for the abatement of low concentrations of benzene. Int J Environ Sci Technol 1–8. doi:10.1007/s13762-013-0218-z

  • Khattri SD, Singh MK (2000) Colour removal from synthetic dye wastewater using a bioadsorbent. Water Air Soil Pollut 120:283–294

    Article  CAS  Google Scholar 

  • Liu Q-S, Zheng T, Li N, Wang P, Abulikemu G (2010) Modification of bamboo-based activated carbon using microwave radiation and its effects on the adsorption of methylene blue. Appl Surf Sci 256:3309–3315

    Article  CAS  Google Scholar 

  • Manoj Kumar Reddy P, Subrahmanyam C (2012) Green approach for wastewater treatment: degradation and mineralization of aqueous organic pollutants by discharge plasma. Ind Eng Chem Res 51(34):11097–11103

    Article  Google Scholar 

  • Manoj Kumar Reddy P, Mahammadunnisa S, Ramaraju B, Sreedhar B, Subrahmanyam C (2013a) Low-cost adsorbents from bio-waste for the removal of dyes from aqueous solution. Environ Sci Pollut Res 20(6):4111–4124

    Article  CAS  Google Scholar 

  • Manoj Kumar Reddy P, Rama Raju B, Karuppiah J, Linga Reddy E, Subrahmanyam C (2013b) Degradation and mineralization of methylene blue by dielectric barrier discharge non-thermal plasma reactor. Chem Eng J 217:41–47

    Article  CAS  Google Scholar 

  • Mittal A, Gupta VK, Malviya A, Mittal J (2008) Process development for the batch and bulk removal and recovery of a hazardous, water-soluble azo dye (Metanil Yellow) by adsorption over waste materials. J Hazard Mater 151(2–3):821–832

    Article  CAS  Google Scholar 

  • Mittal A, Mittal J, Malviya A, Kaur D, Gupta VK (2010a) Adsorption of hazardous dye crystal violet from wastewater by waste materials. J Colloid Interface Sci 343(2):463–473

    Article  CAS  Google Scholar 

  • Mittal A, Mittal J, Malviya A, Kaur D, Gupta VK (2010b) Decoloration treatment of a hazardous triarylmethane dye, Light Green SF (Yellowish) by waste material adsorbents. J Colloid Interface Sci 342(2):518–527

    Article  CAS  Google Scholar 

  • Mohan D, Gupta VK, Srivastava SK, Chander S (2000) Kinetics of mercury adsorption from wastewater using activated carbon derived from fertilizer waste. Colloids Surf A 177(2–3):169–181

    Google Scholar 

  • Nath K, Panchani S, Bhakhar MS, Chatrola S (2013) Preparation of activated carbon from dried pods of Prosopis cineraria with zinc chloride activation for the removal of phenol. Environ Sci Pollut Res 20(6):4030–4045

    Article  CAS  Google Scholar 

  • Nethaji S, Sivasamy A, Kumar RV, Mandal AB (2013a) Preparation of char from lotus seed biomass and the exploration of its dye removal capacity through batch and column adsorption studies. Environ Sci Pollut Res 20(6):3670–3678

    Article  CAS  Google Scholar 

  • Nethaji S, Sivasamy A, Mandal AB (2013b) Adsorption isotherms, kinetics and mechanism for the adsorption of cationic and anionic dyes onto carbonaceous particles prepared from Juglans regia shell biomass. Int J Environ Sci Technol 10(2):231–242

    Article  CAS  Google Scholar 

  • Noh J, Schwarz JA (1990) Effect of HNO3 treatment on the surface acidity of activated carbons. Carbon 28:675–682

    Article  CAS  Google Scholar 

  • Ozdemir M, Bolgaz T, Saka C, Sahin O (2011) Preparation and characterization of activated carbon from cotton stalks in a two-stage process. J Anal Appl Pyrolysis 92:171–175

    Article  CAS  Google Scholar 

  • Pereira MFR, Soares SF, Órfão JJM, Figueiredo JL (2003) Adsorption of dyes on activated carbons: influence of surface chemical groups. Carbon 41(4):811–821

    Article  CAS  Google Scholar 

  • Ramaraju B, Manoj Kumar Reddy P, Subrahmanyam C (2013) Low cost adsorbents from agricultural waste for removal of dyes. Environ Prog Sustain Energy. doi:10.1002/ep.11742

    Google Scholar 

  • Ros A, Lillo-Ródenas MA, Fuente E, Montes-Morán MA, Martín MJ, Linares-Solano A (2006) High surface area materials prepared from sewage sludge-based precursors. Chemosphere 65(1):132–140

    Article  CAS  Google Scholar 

  • Tsai W-T, Chen HR (2013) Adsorption kinetics of herbicide paraquat in aqueous solution onto a low-cost adsorbent, swine-manure-derived biochar. Int J Environ Sci Technol 10(6):1349–1356

    Article  CAS  Google Scholar 

  • Valdés H, Sánchez-Polo M, Rivera-Utrilla J, Zaror CA (2002) Effect of ozone treatment on surface properties of activated carbon. Langmuir 18:2111–2116

    Article  Google Scholar 

  • Zhang J, Fu H, Lv X, Tang J, Xu X (2011) Removal of Cu(II) from aqueous solution using the rice husk carbons prepared by the physical activation process. Biomass Bioenergy 35:464–472

    Article  CAS  Google Scholar 

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Acknowledgments

The authors are grateful for the financial support provided by the Ministry of Environment and Forest (Ref: No. 19-37/2008-RE), India, for this research.

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Authors and Affiliations

  1. Energy and Environmental Research Laboratory, Department of Chemistry, Indian Institute of Technology (IIT) Hyderabad, Hyderabad, 502205, Andhra Pradesh, India

    P. Manoj Kumar Reddy, K. Krushnamurty, S. K. Mahammadunnisa, A. Dayamani & Ch. Subrahmanyam

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  1. P. Manoj Kumar Reddy
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  2. K. Krushnamurty
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  3. S. K. Mahammadunnisa
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  4. A. Dayamani
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  5. Ch. Subrahmanyam
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Correspondence to Ch. Subrahmanyam.

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Manoj Kumar Reddy, P., Krushnamurty, K., Mahammadunnisa, S.K. et al. Preparation of activated carbons from bio-waste: effect of surface functional groups on methylene blue adsorption. Int. J. Environ. Sci. Technol. 12, 1363–1372 (2015). https://doi.org/10.1007/s13762-014-0506-2

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