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Use of Sacrificial Anodes as Protection of Galvanized Steel Exposed to Potassium Chloride and Urea Fertigation Solutions

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Abstract

Corrosion is one of the major causes of metallic pipes deterioration used in irrigation, such as galvanized steel. Its magnitude is directly linked to the quality of the water flowed by these pipes. Thus, the use of cathodic protection combined with pipe coating is used to achieve a greater protection. This study aimed to evaluate the effectiveness of using cathodic protection by the sacrificial anode method to reduce the mass loss, related to corrosion, in specimens of galvanized steel caused by fertigation solutions containing urea or potassium chloride, at 10 g L−1, using Zn, Al and Mg anodes, in addition to a control treatment, without protection. For this, immersion tests were conducted to obtain the mass loss per area, by simulating 10 years of operation. The results showed that with the use of sacrificial anodes it is possible to reduce the mass loss in galvanized steel caused by potassium chloride solutions for fertigation; however, this type of cathodic protection may not be effective in protecting urea-containing solutions from overall corrosion. The aluminum anode is the most suitable to use in solutions with high electrical conductivity, as it can reduce the mass loss caused by potassium chloride by up to 78% compared to the unprotected treatment.

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References

  1. LaRue, J.: A review of center pivot pipeline solutions for various water qualities. In: ASABE Meeting Presentation, Paper Number 072286. Minneapolis, Minnesota (2007)

  2. Della Rovere, C.A.; Silva, R.; Moretti, C.; Kuri, S.E.: Corrosion failure analysis of galvanized steel pipes in a water irrigation system. Eng. Fail. Anal. 33, 381–386 (2013). https://doi.org/10.1016/j.engfailanal.2013.06.024

    Article  Google Scholar 

  3. Nwoye, C.I.; Chinwuko, E.C.; Nwosu, I.E.; Onyia, W.C.; Amalu, N.I.; Nwosu, P.C.: Operational dependence of galvanized steel corrosion rate on its structural weight loss and immersion-point pH in sea water environment. Am. J. Min. Metall. 2(4), 81–87 (2014)

    Google Scholar 

  4. Oki, M.; Anawe, P.A.L.: A Review of corrosion in agricultural industries. Phys. Sci. Int. J. 5(4), 216–222 (2015). https://doi.org/10.9734/PSIJ/2015/14847

    Article  Google Scholar 

  5. Schweitzer, P.A.: Fundamentals of Corrosion: Mechanisms, Causes, and Preventative Methods. CRC Press (2010)

    Google Scholar 

  6. Koch, G.; Varney, J.; Thompson, N.; Moghissi, O.; Gould, M.; Payer, J.: International measures of prevention, application, and economics of corrosion technologies study. In: NACE International IMPACT. Houston, USA (2016)

  7. Tezdogan, T.; Demirel, Y.K.: An overview of marine corrosion protection with a focus on cathodic protection and coatings. Brodogradnja/Shipbuilding 65(2), 49–59 (2014)

    Google Scholar 

  8. Gurrapa, I.: Cathodic protection of cooling water systems and selection of appropriate materials. J. Mater. Process. Technol. 166, 256–267 (2005). https://doi.org/10.1016/j.jmatprotec.2004.09.074

    Article  Google Scholar 

  9. Gentil, V.: Corrosão, 6th edn. LTC, Rio de Janeiro (2011)

  10. Loto, C.A.; Loto, R.T.; Popoola, A.P.: Performance evaluation of zinc anodes for cathodic protection of mild steel corrosion in HCl. Chem. Data Collect. 24, 100280 (2019). https://doi.org/10.1016/j.cdc.2019.100280

    Article  Google Scholar 

  11. Delaunois, F.F.; Vitry, T.V.: Corrosion behaviour and biocorrosion of galvanized steel water distribution systems. Bioelectrochemistry 97, 110–119 (2014). https://doi.org/10.1016/j.bioelechem.2014.01.003

    Article  Google Scholar 

  12. Loto, C.A.; Popoola, A.P.I.: Effect of anode and size variations on the cathodic protection of mild steel in sea water and sulphuric acid. Int. J. Phys. Sci. 6(12), 2861–2868 (2011)

    Google Scholar 

  13. Refait, Ph.; Jeannin, M.; Sabot, R.; Antony, H.; Pineau, S.: Corrosion and cathodic protection of carbon steel in the tidal zone: Products, mechanisms and kinetics. Corr. Sci. 90, 375–382 (2015). https://doi.org/10.1016/j.corsci.2014.10.035

    Article  Google Scholar 

  14. Owoeye, F.T.; Adetunji, O.R.; Kuye, S.I.; Bada, B.S.: Cathodic protection of aluzinc coated, galvanized and stainless steels in Ijegun seawater using aluminum as sacrificial anode. United Int. J. Res. Technol. 2(2), 81–92 (2020)

    Google Scholar 

  15. ASTM G31-12a: Standard Guide for Laboratory Immersion Corrosion Testing of Metals. ASTM International, Philadelphia (2012). https://doi.org/10.1520/G0031-12A

  16. Ebert, W.L.; Gattu, V.K.: Metallic waste forms. Compr. Nucl. Mater. 5, 505–538 (2012). https://doi.org/10.1016/B978-0-12-803581-8.11776-X

    Article  Google Scholar 

  17. Pearson, P.; Cousins, A.: Assessment of corrosion in amine-based post-combustion capture of carbon dioxide systems. In: Absorption-Based Post-Combustion Capture of Carbon Dioxide, pp. 439–463 (2016). https://doi.org/10.1016/B978-0-08-100514-9.00018-4

  18. Tsujino, B.; Miyase, S.: On area ratio of anode to cathode for iron in neutral solution. Corrosion 37(9), 540–545 (1981). https://doi.org/10.5006/1.3580803

    Article  Google Scholar 

  19. Dong, C.F.; Xiao, K.; Li, X.G.; Cheng, Y.F.: Galvanic corrosion of a carbon steel-stainless steel couple in sulfide solutions. J. Mater. Eng. Perform. 20(9), 1631–1637 (2011). https://doi.org/10.1007/s11665-011-9839-x

    Article  Google Scholar 

  20. Pramanik, N.; Kumar, R.; Ray, A.; Chaudhary, V.K.; Ghosh, S.: Corrosion behavior of mild steel in the presence of urea, sodium chloride, potassium chloride, and glycine: a kinetic and potentiodynamic polarization study approach. J. Bio- Tribo-Corros. 8, 112 (2022). https://doi.org/10.1007/s40735-022-00713-w

    Article  Google Scholar 

  21. Barbosa, J.C.; Maldonado Júnior, W.: AgroEstat: Sistema para análises estatísticas de ensaios agronômicos. FCAV/UNESP, Jaboticabal (2015)

  22. Ferreira, D.F.: A computer analysis system to fixed effects split plot type designs. Rev. Bras. Biom. 37(4), 529–535 (2019). https://doi.org/10.28951/rbb.v37i4.450

    Article  Google Scholar 

  23. Lee, H.; Rasheed, U.; Kong, M.: A study on the comparison of corrosion in water supply pipes due to tap water (TW) and reclaimed water (RW). Water 10(496), 1–21 (2018). https://doi.org/10.3390/w10040496

    Article  Google Scholar 

  24. Amer, B.A.; Abdel-Aziz, M.H.; El-Ashtoukly, E.S.Z.; Amin, N.K.: Galvanic corrosion of steel in agitated vessels used in fertilizer industry. Theor. Found. Chem. Eng. 53(2), 280–291 (2019). https://doi.org/10.1134/S0040579519020015

    Article  Google Scholar 

  25. Rodrigues, K.V.; Lima, L.A.; Thebaldi, M.S.: Effects of fertigation on corrosion in galvanized steel used in center pivot systems. Water Supply 20(4), 1189–1194 (2020). https://doi.org/10.2166/ws.2020.029

    Article  Google Scholar 

  26. Haque, M.M.; Limon, S.A.; Moniruzzaman, M.D.; Bepari, M.D.M.A.: Corrosion comparison of galvanized steel and aluminum in aqueous environments. Int. J. Automot. Mech. Eng. 9, 1758–1767 (2014). https://doi.org/10.15282/ijame.9.2013.24.0146

    Article  Google Scholar 

  27. Kapps, V.; Simões, A.L.C.; Custódio, A.B.: Experimentos de baixo custo em corrosão e proteção de dutos de aço em meios ácidos. Rev. Eng. Univ. Catól. Petrópolis 7(2), 23–38 (2012)

    Google Scholar 

  28. Narozny, M.; Zakowski, K.; Darowicki, K.: Method of sacrificial anode transistor-driving in cathodic protection system. Corr. Sci. 88, 275–279 (2014). https://doi.org/10.1016/j.corsci.2014.07.041

    Article  Google Scholar 

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Acknowledgements

This work was supported by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES), grant number 001; and by the Department of Water Resources of the Universidade Federal de Lavras (DRH-UFLA).

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Correspondence to Karina Vilela Rodrigues.

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Rodrigues, K.V., Lima, L.A. & Thebaldi, M.S. Use of Sacrificial Anodes as Protection of Galvanized Steel Exposed to Potassium Chloride and Urea Fertigation Solutions. Arab J Sci Eng 49, 5379–5384 (2024). https://doi.org/10.1007/s13369-023-08412-5

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  • DOI: https://doi.org/10.1007/s13369-023-08412-5

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  1. Michael Silveira Thebaldi