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Poly(vinylidene fluoride)/Plasma-Treated BaTiO3 Nanocomposites with Enhanced Electroactive Phase

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Abstract

Functional C=O and C-O groups are successfully fixated onto the surface of a high dielectric constant material barium titanate (BaTiO3) via non-thermal plasma. The strong dipole interaction exists between these functional groups and CH2 or CF2 groups of poly(vinylidene fluoride) (PVDF), resulting in the enhancement of the electroactive γ-phase of PVDF/BaTiO3 nanocomposites on one hand; on the other hand the dispersion of BaTiO3 is enhanced in the PVDF matrix, where the smaller spherulite size and better hydrophilic property are observed in the PVDF/plasmatreated BaTiO3 nanocomposite, comparing with the untreated ones. Therefore, the PVDF/plasma-treated BaTiO3 nanoparticles exhibited higher dielectric constant and lower dielectric loss than the PVDF/BaTiO3 nanoparticles.

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References

  1. Z. M. Dang, J. K. Yuan, J. W. Zha, T. Zhou, S. T. Li, and G. H. Hu, Prog. Mater. Sci., 57, 660 (2012).

    Article  CAS  Google Scholar 

  2. L. Xie, X. Huang, K. Yang, S. Li, and P. Jiang, J. Mater. Chem. A, 2, 5244 (2014).

    Article  CAS  Google Scholar 

  3. S. Ramesh, B. A. Shutzberg, C. Huang, and J. Gao, IEEE Trans. Adv. Packag., 26, 17 (2003).

    Article  CAS  Google Scholar 

  4. T. Sharma, S. S. Je, B. Gill, and J. X. J. Zhang, Sens. Actuators A: Phys., 177, 87 (2012).

    Article  CAS  Google Scholar 

  5. X. Huang, L. Xie, P. Jiang, G. Wang, and F. Liu, J. Phys. D Appl. Phys., 42, 245407 (2009).

    Article  CAS  Google Scholar 

  6. M. Sharma, G. Madras, and S. Bose, Macromolecules, 47, 1392 (2017).

    Article  CAS  Google Scholar 

  7. S. Wu, W. Li, M. Lin, Q. Burlingame, Q. Chen, A. Payzant, K. Xiao, and Q. M. Zhang, Adv. Mater., 25, 1734 (2013).

    Article  CAS  PubMed  Google Scholar 

  8. S. Cho, J. S. Lee, and J. Jang, ACS Appl. Mater. Interfaces, 7, 9668 (2015).

    Article  CAS  PubMed  Google Scholar 

  9. B. S. Lee, B. Park, H. S. Yang, J. W. Han, C. Choong, J. Bae, K. Lee, W. R. Yu, U. Jeong, and U. I. Chung, ACS Appl. Mater. Interfaces, 6, 3520 (2014).

    Article  CAS  PubMed  Google Scholar 

  10. H. Tang, Y. Lin, and H. A. Sodano, Adv. Energy Mater., 3, 451 (2013).

    Article  CAS  Google Scholar 

  11. M. F. Lin and P. S. Lee, J. Mater. Chem. A, 1, 14455 (2013).

    Article  CAS  Google Scholar 

  12. E. A. Stefanescu, X. Tan, Z. Lin, N. Bowler, and M. R. Kessler, Polymer, 52, 2016 (2011).

    Article  CAS  Google Scholar 

  13. K. Ke, P. Pötschke, D. Jehnichen, D. Fischer, and B. Voit, Polymer, 55, 611 (2014).

    Article  CAS  Google Scholar 

  14. S. Fabiano, X. Crispin, and M. Berggren, ACS Appl. Mater. Interfaces, 6, 438 (2014).

    Article  CAS  PubMed  Google Scholar 

  15. V. Cauda, S. Stassi, K. Bejtka, G. Canavese, ACS Appl. Mater. Interfaces, 5, 6430 (2013).

    Article  CAS  Google Scholar 

  16. K. Yu, H. Wang, Y. Zhou, Y. Bai, and Y. Niu, J. Appl. Phys., 113, 2 (2013).

    Google Scholar 

  17. R. Krishnamoorti, MRS Bull., 32, 341 (2007).

    Article  CAS  Google Scholar 

  18. Y. Fan, G. Wang, X. Huang, J. Bu, X. Sun, and P. Jiang, Appl. Surface Sci., 364, 798 (2016).

    Article  CAS  Google Scholar 

  19. T. Zhou, J. W. Zha, R. Y. Cui, B. H. Fan, J. K. Yuan, and Z. M. Dang, ACS Appl. Mater. Interfaces, 3, 2184 (2011).

    Article  CAS  PubMed  Google Scholar 

  20. L. Xie, X. Huang, Y. Huang, K. Yang, and P. Jiang, ACS Appl. Mater. Interfaces, 5, 1747 (2013).

    Article  CAS  PubMed  Google Scholar 

  21. S. L. Jiang, Y. Yu, and Y. K. Zeng, Current Appl. Phys., 9, 956 (2009).

    Article  Google Scholar 

  22. Y. Zhao, X. L. Liu, X. L. Dou, and J. F. Chen, J. Adv. Phys., 4, 357 (2015).

    Article  Google Scholar 

  23. Y. Li, X. Huang, Z. Hu, P. Jiang, S. Li, and T. Tanaka, ACS Appl. Mater. Interfaces, 3, 4396 (2011).

    Article  CAS  PubMed  Google Scholar 

  24. Y. Shen, Y. Guan, Y. Hu, Y. Lei, Y. Song, Y. Lin, and C. W. Nan, Appl. Phys. Lett., 103, 1939 (2013).

    Google Scholar 

  25. K. Yang, X. Huang, Y. Huang, L. Xie, and P. Jiang, Chem. Mater., 25, 2327 (2013).

    Article  CAS  Google Scholar 

  26. L. Xie, X. Huang, C. Wu, and P. Jiang, J. Mater. Chem., 21, 5897 (2011).

    Article  CAS  Google Scholar 

  27. N. D. Geyter, R. Morent, C. Leys, L. Gengembre, E. Payen, S. V. Vlierberghe, and E. Schacht, Surf. Coat. Technol., 202, 3000 (2008).

    Article  CAS  Google Scholar 

  28. C. Zhang, Y. Zhou, T. Shao, Q. Xie, J. Xu, and W. Yang, Appl. Surf. Sci., 311, 468 (2014).

    Article  CAS  Google Scholar 

  29. F. Zhi, L. Hao, Y. Hao, X. Xie, Y. Qiu, and K. Edmund, IEEE Trans. Plasma Sci., 255, 7279 (2009).

    Google Scholar 

  30. R. Morent, N. D. Geyter, and C. Leys, Nucl. Instrum. Methods Phys. Res. B, 266, 3081 (2008).

    Article  CAS  Google Scholar 

  31. Z. Fang, Y. Liu, K. Liu, T. Shao, and C. Zhang, Vacuum, 86, 1305 (2012).

    Article  CAS  Google Scholar 

  32. Z. Fang, S. Ji, J. Pan, T. Shao, and C. Zhang, IEEE Trans. Plasma Sci., 40, 883 (2012).

    Article  CAS  Google Scholar 

  33. A. K. Jin, G. S. Dong, T. J. Kang, and J. R. Youn, Carbon, 44, 1898 (2006).

    Article  CAS  Google Scholar 

  34. T. M. Long, S. Prakash, M. A. Shannon, and J. S. Moore, Langmuir, 22, 4104 (2006).

    Article  CAS  PubMed  Google Scholar 

  35. T. Shao, C. Zhang, Y. Yu, Z. Fang, and P. Yan, Europhys. Lett., 97, 55005 (2012).

    Article  CAS  Google Scholar 

  36. H. Bubert, S. Haiber, W. Brandl, G. Marginean, M. Heintze, and V. Brüser, Diam. Relat. Mater., 12, 811 (2003).

    Article  CAS  Google Scholar 

  37. T. Shao, D. Zhang, Y. Yu, C. Zhang, J. Wang, P. Yan, and Y. Zhou, IEEE Trans. Plasma Sci., 38, 1651 (2010).

    Article  Google Scholar 

  38. M. Pérezmendoza, M. Domingogarcía, I. Fernándezmorales, and A. Martínezalonso, J. Phys. Chem. B, 110, 11327 (2006).

    Article  CAS  Google Scholar 

  39. Z. Fang, C. Ruan, T. Shao, C. Zhang, Plasma Sources Sci. Technol., 25, 01LT01 (2016).

    Article  CAS  Google Scholar 

  40. R. Wang, K. Zhang, Y. Shen, C. Zhang, W. Zhu, and T. Shao, Plasma Sources Sci. Technol., 25, 015020 (2016).

    Article  CAS  Google Scholar 

  41. Y. Song, Y. Shen, H. Liu, Y. Lin, M. Li, and C. W. Nan, J. Mater. Chem., 22, 8063 (2012).

    Article  CAS  Google Scholar 

  42. R. G. Acres, A. V. Ellis, J. Alvino, C. E. Lenahan, D. A. Khodakov, G. F. Metha, and G. G. Andersson, J. Phys. Chem. C, 116, 6289 (2012).

    Article  CAS  Google Scholar 

  43. T. Shao, C. Zhang, K. H. Long, D. D. Zhang, J. Wang, P. Yan, Y. X. Zhou, Appl. Surf. Sci., 256, 3888 (2010).

    Article  CAS  Google Scholar 

  44. N. Grossiord, J. Loos, O. Regev, and C. E. Koning, Chem. Mater., 18, 1089 (2006).

    Article  CAS  Google Scholar 

  45. L. Gong, B. Yin, L. P. Li, and M. B. Yang, Compos. Part B: Eng., 73, 49 (2015).

    Article  CAS  Google Scholar 

  46. Y. Ahn, J. Y. Lim, S. M. Hong, J. Lee, J. Ha, H. J. Choi, and Y. Seo, J. Phys. Chem. C, 117, 11791 (2013).

    Article  CAS  Google Scholar 

  47. S. Manna, S. K. B. And, and A. K. Nandi, J. Phys. Chem. B, 110, 12318 (2006).

    Article  CAS  PubMed  Google Scholar 

  48. D. Wang, Y. Bao, J. W. Zha, J. Zhao, Z. M. Dang, G. H. Hu, ACS Appl. Mater. Interfaces, 4, 6273 (2012).

    Article  CAS  PubMed  Google Scholar 

  49. P. M. Balaji, V. Katari, A. Ehab, L. Gavin, G. Hemant, and A. K. T. Salunke, J. Phys. Chem. C, 118, 20819 (2014).

    Article  CAS  Google Scholar 

  50. X. J. Yang, J. Y. Li, and Y. P. Lei, Adv. Mater. Res., 668, 17 (2013).

    Article  CAS  Google Scholar 

  51. S. Theapsak, A. Watthanaphanit, and R. Rujiravanit, ACS Appl. Mater. Interfaces, 4, 2474 (2012).

    Article  CAS  PubMed  Google Scholar 

  52. C. Labay, C. Canal, and M. J. García-Celma, Plasma Chem. Plasma Processing, 30, 885 (2010).

    Article  CAS  Google Scholar 

  53. A. K. Riau, D. Mondal, G. H. F. Yam, M. Setiawan, B. Liedberg, S. S. Venkatraman, and J. S. Mehta, ACS Appl. Mater. Interfaces, 7, 21690 (2010).

    Article  CAS  Google Scholar 

  54. T. Bhimasankaram, S. V. Suryanarayana, and G. Prasad, Curr. Sci., 74, 967 (1998).

    CAS  Google Scholar 

  55. F. Mendes, C. M. Costa, C. Caparros, V. Sencadas, and S. L-Mendez, J. Mater. Sci., 47, 1378 (2012).

    Article  CAS  Google Scholar 

  56. Y. Li, X. Huang, Z. Hu, P. Jiang, S. Li, and T. Tanaka, ACS Appl. Mater. Interfaces, 3, 4396 (2011).

    Article  CAS  PubMed  Google Scholar 

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Authors and Affiliations

  1. Department of Environment and Chemical Engineering, Dalian University, Dalian, 116622, Liaoning, P. R. China

    Ran Ding, Lei Gong, Ming-ming Li, Shu-hua Chen, Shi-ping Zhan & Xu-dong Sun

  2. Liaoning Engineering Labortory for special optical functional crystals, Dalian University, Dalian, 116622, Liaoning, P. R. China

    Ran Ding, Lei Gong, Ming-ming Li, Shu-hua Chen, Shi-ping Zhan & Xu-dong Sun

  3. Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing, 100190, P. R. China

    Cheng Zhang & Tao Shao

  4. University of Chinese Academy of Sciences, Beijing, 100039, P. R. China

    Cheng Zhang & Tao Shao

Authors
  1. Ran Ding
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  2. Lei Gong
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  3. Ming-ming Li
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  4. Shu-hua Chen
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  7. Cheng Zhang
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  8. Tao Shao
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Corresponding author

Correspondence to Lei Gong.

Additional information

Acknowledgments: The authors gratefully acknowledge the financial support from the Opening Project of State Key Laboratory of Polymer Materials Engineering (Sichuan University) (Grant No. Sklpme2015-4-24) and the Provincial Department of Education Science General Foundation of Liaoning (Contract No. L2015017). Thanks to Prof. You-Fu Zhou and Prof. Ji-Quan Huang from Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, for the dielectric property measurements.

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Ding, R., Gong, L., Li, Mm. et al. Poly(vinylidene fluoride)/Plasma-Treated BaTiO3 Nanocomposites with Enhanced Electroactive Phase. Macromol. Res. 26, 965–972 (2018). https://doi.org/10.1007/s13233-018-6118-9

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  • DOI: https://doi.org/10.1007/s13233-018-6118-9

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