Abstract
Glasses based on the basic composition of lithium disilicate (Li2O.2SiO2) together with derived samples containing increasing CeO2 replacing Li2O (0.1, 0.2, 0.5, 1 Mol %) were prepared by melting – annealing method, samples from the prepared parent glasses were thermally heat treated through two-step regime (450° C /10 h – followed by 650° C / 6 h) to convert them to their glass – ceramics derivatives. The main purpose of this study is to find out the main properties of the prepared glass – ceramics to be applied as dental candidates. The optical, FTIR, and thermal expansion properties of the parent glasses were examined to identify the main structural groups which are defined as tetrahedral stronger SiO2 building groups. The detailed separated crystalline phases within the prepared glass–ceramics were identified together with their textural features. The Vickers microhardness data for both the parent glasses and their glass -ceramics derivatives were evaluated. SEM and EDAX measurements indicate the ability of the prepared samples to form hydroxyapatite upon immersion in SBF solution.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles and news from researchers in related subjects, suggested using machine learning.Avoid common mistakes on your manuscript.
Data Availability
The authors stated and declared that all data exists and is available.
References
Höland W, Rheinbrger V, Apel E, Ritzbrger C, Rothbrust F, Kapput H, Krumeich F, Nesper R (2009) Future perspectives of biomaterials for dental restoration. J Eur Ceram Soc 29:1291–1297
ElBatal FH, Azooz MA, Hamdy YM (2009) Preparation and characterization of some multicomponent silicate glasses and their glass–ceramics derivatives for dental applications. Ceram Intern 35:1211–1218
Pollington S (2011) Novel Glass-Ceramics for Dental Restorations. J Contemp Dant Pract 12:60–67
Johnson A, Sinthuprasirt P, Fathi H, Pollington S (2013) Current glass – ceramics used in dentistry. In: Nandyala SH, Santen JD (eds) Current trends in glass and ceramic materials. Bentham Science Publishers Ud, UK, pp 49–72
Montazerian M, Zanotto ED (2016) Bioactive glass-ceramics: processing, properties and applications. J Biomed Mater Res Part A 104A:1231–1244
Montazerian M, Zanotta ED (2017) Bioactive and inert dental glass-ceramics. J. Biomed. Mater. Res. Part A 105A:619–639
Höland W, Beall GH (2020) Glass-ceramic Technology, 3rd edn. The American Ceramic Society, John Wiley, Sons New Jersey
Baino F, Tomaliao M, Tylyaganov D (eds) (2021) Ceramics, glass and glass-ceramics from early manufacturing steps towards modern frontiers. Springer Nature, Switzerland AG
Lohbauer U, Belli R (2022) Chemistry and microstructure. In: Dental Ceramics. Springer, Cham. https://doi.org/10.1007/978-3-030-94687-6_2
Montazerian M, Buino F, Fiume E, Migneco C, Alaghmandfard A, Sedighi O, DeCeanne AV, Wilkinson CJ, Mairo JC (2023) Glass-ceramics in dentistry: Fundamentals, technologies, experimental techniques, applications, and open issues. Prog Mater Sci 132:101023
Baino F, Novajra G, Miguez-Pacheco V, Boccaccini AR, Vitale- Brovarone C (2016) Bioactive glasses: Special applications outside the skeletal system. J. Non-Cryst. Solids 432:15–30
Gracis S, Thompson VP, Ferencz H, Silva NR, Bonfante EA (2015) A new classification system for all-ceramic and ceramic-like restorative Materials. Int J Prosthodont 28:227–235
Hassan SM, Gad NA (2017) Two-body wear and surface roughness of three different ceramic systems and their enamel antagonist: An invitro study. Al-Azhar Dental Journal 4(4):347–357
Al Hamad KQ, AlQuran FA, Aljalam SA, Baba NZ (2019) Comparison of the accuracy of fit of metal, zirconia, and lithium disilicate crowns made from different manufacturing techniques. J Prosthodont 28:497–503. https://doi.org/10.1111/jopr.13029
Wong J, Angell CA (1976) Glass Structure by vibrational spectroscopy. Marcel Dekker, NewYork
Efimov AM (1999) Vibrational spectra, related properties, and structure of inorganic glasses. J Non-Cryst Solids 235:95
Merzbacher CI, White WB (1991) The structure of alkaline earth aluminosilicate glasses as determined by vibrational spectroscopy. J Non-Cryst Solids 130:18
Srichumpong T, Pintasiri S, Heness G, Leonelli C, Meechoowas E, Thongpun N, Teanchai C, Suputtamongkol K, Chaysuwan D (2021) The influence of yttria-stabilised zirconia and cerium oxide on the microstructural morphology and properties of a mica glass-ceramic for restorative dental materials. Journal of Asian Ceramic Societies 9(3):926–933
Montazerian M, Zanotto ED (2017) Review Article. J. Biomed. Mater. Res. Part A 105A:619–639
Kokubo T, Kushitani H, Sakka S, Kitsugi T, Yamamuro T (1990) Solutions able to reproduce in vivo surface-structure changes in bioactive glass–ceramic A-W3. J Biomed Mater Res (A) 24:721–734
Marzouk MA, Elkashef IM, Elbatal HA (2019) Luminescent, semiconducting, thermal, and structural performance of Ho3+-doped lithium borate glasses with CaF2 or MgF2. Appl Phys A 125:97
Holloway DG (1973) the Physical properties of glass. Wykeham, London
Rawson H (1980) Properties and applications of glasses, Glass Science & Technology, vol 3. Elsevier, Amsterdam
Deshpande VK, Taikar RN (2010) Effect of cerium oxide addition on electrical and physical properties of alkali borosilicate glasses. Mater Sci Eng, B 172:6–8
Peuget S, Maugeri EA, Charpentier T, Mendoza C, Moskura M, Fares T, Bouty O, Jégou C (2013) Comparison of radiation and quenching rate effects on the structure of a sodium borosilicate glass. J Non-Cryst Solids 378:201–212
Eremyashev VE, Zherebtsov DA, Osipova LM, Brazhnikov MV (2018) Effect of calcium, barium, and strontium on the thermal properties of borosilicate glasses. Glass Ceram 74:345–348
Zhao X, Gao C, Li B (2020) Effect of CeO2 on sintering behavior, crystallization, and properties of CaO-Al2O3-SiO2 glass–ceramics for packages. J Mater Sci: Mater Electron 31:17718–17725
Hu AM, Liang KM, Zhou F, Wang GL, Peng F (2005) Phase transformations of Li2O–Al2O3–SiO2 glasses with CeO2 addition. Ceram Int 31:11–14
Lei Y, He Y, Chen FF, Xu J (2015) Effect of Mineralizers and Reaction Conditions on the Formation of Cristobalite. Interceram Int Ceram Rev 64:214–218
Marzouk MA, ElBatal HA (2014) In vitro bioactivity of soda lime borate glasses with substituted SrO in sodium phosphate solution. Processing and Application of Ceramics 8(3):167–177
Dunken H, Doremus RH (1987) Short time reactions of a Na2O-CaO-SiO2 glass with water and salt solutions. J Non-Cryst Solids 92:61
Husung RD, Doremus RH (1990) The infrared transmission spectra of four silicate glasses before and after exposure to water. J. Mater. Res. 5(10):2209
AboNaf SM, ElBatal FH, Azooz MA (2003) Characterization of some glasses in the system SiO2, Na2O·RO by infrared spectroscopy. Mater Chem Phys 77:846
ElBatal FH, Khalil EM, Hamdy YM, Zidan HM, Aziz MS, Abdelghany AM (2010) FTIR spectral analysis of corrosion mechanisms in soda lime silica glasses doped with transition metal oxides. SILICON 2:41–47
ElBatal HA, Azooz HA, Saad EA, EzzElDin FM, Amin MS (2018) Corrosion behavior mechanism of borosilicate glasses towards different leaching solutions evaluated by the grain method and FTIR spectral analysis before and after gamma irradiation. Silicon 10:1139–1149
Seuthe T, Grehn M, Mermillod-Blondin A, Eichler HJ, Bonse J, Eberstein M (2013) Structural modifications of binary lithium silicate glasses upon femtosecond laser pulse irradiation probed by micro-Raman spectroscopy. Optical Materials Express 3(6):755–764
Möncke D, Ehrt R, Palles D, Efthimiopoulos I, Kamitsos EI, Johannes M (2017) A multi technique study of a new lithium disilicate glass-ceramic spray-coated on ZrO2 substrate for dental restoration. Biomed Glasses 3:41–55
Duffy JA (1997) Charge transfer spectra of metal ions in glass. Phys Chem Glasses 38:289–294
Ehrt D, Ebeling P, Natura U, UV, (2000) Transmission and radiation-induced defects in phosphate and fluoride–phosphate glasses. J. Non-Cryst. Solids 263 264:240–250
Möncke D, Ehrt D (2004) Irradiation induced defects in glasses resulting in the photoionization of polyvalent dopants. Opt Mater 25:425–437
Marzouk MA, Ali IS, ElBatal HA (2018) Optical, FT infrared and photoluminescence spectra of CeO2 – doped Na2O –ZnO – B2O3 host glass and effects of gamma irradiation. J Non-Cryst Solids 485:14–23
Marzouk MA, ElBatal HA, Hamdy YM, Ezz-Eldin FM (2019) Collective Optical, FTIR, and Photoluminescence Spectra of CeO2 and/or Sm2O3-Doped Na2O–ZnO–P2O5 Glasses. Int J Opt 2019:1–11. https://doi.org/10.1155/2019/6527327
Ghoneim NA, El Batal HA, Nassar AMA (1983) Microhardness and softening point of some alumino-borate glasses as flow dependent properties. J Non-Cryst Solids 55:343–351
Ghoneim NA, EL Batal HA, Abbas ARF, Ammar MM, Halawa MM (1981) Microindentation Hardness of Silicate Glasses Containing BaO or ZnO. Bull Am Ceram Soc 60:1289–1292
Hamzawy EMA, El Batal HA, Azooz MA, El-Bassyouni GT, El Batal FH (2023) Glasses and Glass-Ceramics from Li2O-KF-TiO2-SiO2 System Doped with SiC. SILICON. https://doi.org/10.1007/s12633-023-02531-2
Acknowledgements
The authors of this study wish to thank the National Research Centre authority for the financial support with project No. 13020218.
Funding
Open access funding provided by The Science, Technology & Innovation Funding Authority (STDF) in cooperation with The Egyptian Knowledge Bank (EKB). The authors declare no Funds.
Author information
Authors and Affiliations
Contributions
M. A. Marzouk, H. A. Elbatal, F. H. Elbatal, M. A. Azooz, R. L. Elwan, A. M. Fayad, M. A. Ouis, A. K. Helmy, and Y. M. Hamdy contributed to executing data analysis, writing manuscript, drawing figures, and manuscript revision.
Corresponding author
Ethics declarations
Consent for Publication
All authors approved the version of the manuscript to be published.
Competing Interests
The authors declare no competing interests.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
Marzouk, M.A., Elbatal, H.A., Elbatal, F.H. et al. Preparation and Characterization of Nano Glass–ceramics from CeO2-doped Li2O-SiO2 System for Dental Applications. Silicon 16, 1881–1892 (2024). https://doi.org/10.1007/s12633-023-02819-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12633-023-02819-3