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A novel Li-ion supercapattery by K-ion vacant ternary perovskite fluoride anode with pseudocapacitive conversion/insertion dual mechanisms

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Abstract

An innovative K+ vacant ternary perovskite fluoride (K0.89Ni0.02Co0.03Mn0.95F3.0, KNCMF-3#) anode was designed for advanced Li-ion supercapattery (i.e., Li-ion capacitors/batteries, LIC/Bs). Owing to the conversion/insertion dual mechanisms and fast pseudocapacitive control dynamics, the KNCMF-3# electrode exhibits superior electrochemical performance, especially the excellent cycle performance (467% (229 mAh·g−1)/1000 cycles/2 A·g−1). Moreover, the hybrid KNCMF-3#/reduced graphene oxide (rGO) electrode can further increase the electrochemical performance (217–97 mAh·g−1/0.1–3.2 A·g−1, 150% (197 mAh·g−1)/1000 cycles/2 A·g−1). Also, a novel capacitor/battery cathode, activated carbon (AC) + LiFePO4 + graphene (AC + LFP + G), exhibits impressive performance (128–82 mAh·g−1/0.1–3.2 A·g−1, 84%/1000 cycles/2 A·g−1). By the synergistic optimization of anode and cathode, the Li-ion supercapattery KNCMF-3#@rGO//AC + LFP + G demonstrates remarkable performance, for example, 111.9–23.8 Wh·kg−1/0.4–8.0 kW·kg−1/82%/2000 cycles/5 A·g−1/0–4 V, which is superior to KNCMF-3#//AC LICs, KNCMF-3#@rGO//AC LICs, KNCMF-3#//AC + LFP + G LIC/Bs. In all, the novel Li-ion supercapattery idea adds a promising perspective to develop advanced energy storage devices.

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摘要

设计了一种新型的钾离子空位三元钙钛矿氟化物 (K0.89Ni0.02Co0.03Mn0.95F3.0, KNCMF-3#) 负极用于先进的锂离子超级电容电池 (即锂离子电容器/电池, LIC/Bs)。由于转换/插入双重机制和快速赝电容控制动力学, KNCMF-3#电极表现出优异的电化学性能, 尤其是优异的循环性能 (467% (229 mAh·g−1)/1000次循环/2 A·g−1)。此外, KNCMF-3#/还原氧化石墨烯 (rGO) 复合电极可以进一步提高电化学性能 (217–97 mAh·g−1/0.1–3.2 A·g−1, 150% (197 mAh·g−1) /1000循环/2 A·g−1)。此外, 构筑了一种新型电容器/电池正极-活性炭 (AC) + LiFePO4 + 石墨烯 (AC + LFP + G), 该正极展现出优异的电化学性能 (128–82 mAh·g−1/0.1–3.2 A·g−1, 84%/1000循环 /2 A·g−1)。通过正负极协同优化, 锂离子超级电容电池KNCMF-3#@rGO//AC + LFP + G表现出卓越的性能, 例如111.9–23.8 Wh·kg−1/0.4–8.0 kW·kg−1/82%/2000循环/5 A·g−1/0–4 V, 优于KNCMF-3#//AC和KNCMF-3#@rGO//AC LICs以及KNCMF-3#//AC + LFP + G LIC/Bs。总之, 本文提出的新型锂离子超级电容电池理念为开发先进的储能设备增添了前景。

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Acknowledgements

This study was financially supported by the National Natural Science Foundation of China (No. 22078279).

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  1. Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, 411105, China

    Yong-Fa Huang, Rui Ding, Dan-Feng Ying, Yu-Xi Huang, Tong Yan, Cai-Ni Tan, Xiu-Juan Sun & En-Hui Liu

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Huang, YF., Ding, R., Ying, DF. et al. A novel Li-ion supercapattery by K-ion vacant ternary perovskite fluoride anode with pseudocapacitive conversion/insertion dual mechanisms. Rare Met. 41, 2491–2504 (2022). https://doi.org/10.1007/s12598-022-01979-2

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